An enhanced fluorescent ZIF-8 film by capturing guest molecules for light-emitting applications

Author(s):  
Qiufen Liu ◽  
Shouqin Tian ◽  
Xiujian Zhao ◽  
Gopinathan Sankar

Metal organic frameworks (MOFs) constructed by metal ions/clusters and organic linkers become new porous luminescent materials and thus have attracted much attention. But their photoluminescence quantum yield (PLQY) is not...

Nanoscale ◽  
2021 ◽  
Author(s):  
Haifeng Sha ◽  
Bing Yan

The wide applications of metal-organic frameworks (MOFs) luminescent materials in the field of optics have attracted the general attention of researchers. Therefore, the development of simple and multifunctional MOFs light-emitting...


2015 ◽  
Vol 44 (20) ◽  
pp. 9588-9595 ◽  
Author(s):  
Shanghua Xing ◽  
Guang Zeng ◽  
Xiaomin Liu ◽  
Fen Yang ◽  
Zhiqiang Hao ◽  
...  

Multifunctional luminescent materials of six Ln-MOFs have been designed and synthesized by the co-doping strategy. Thus a wide range of light emitting spectra and different temperature-dependent luminescence behavior were displayed.


2018 ◽  
Vol 20 (17) ◽  
pp. 11564-11576 ◽  
Author(s):  
M. Oldenburg ◽  
A. Turshatov ◽  
D. Busko ◽  
M. Jakoby ◽  
R. Haldar ◽  
...  

Photoluminescence quantum yield enhancement based on energy transfer in surface-anchored metal–organic frameworks.


Molecules ◽  
2020 ◽  
Vol 25 (18) ◽  
pp. 4230
Author(s):  
Andreas Windischbacher ◽  
Luca Steiner ◽  
Ritesh Haldar ◽  
Christof Wöll ◽  
Egbert Zojer ◽  
...  

In recent years, the photophysical properties of crystalline metal-organic frameworks (MOFs) have become increasingly relevant for their potential application in light-emitting devices, photovoltaics, nonlinear optics and sensing. The availability of high-quality experimental data for such systems makes them ideally suited for a validation of quantum mechanical simulations, aiming at an in-depth atomistic understanding of photophysical phenomena. Here we present a computational DFT study of the absorption and emission characteristics of a Zn-based surface-anchored metal-organic framework (Zn-SURMOF-2) containing anthracenedibenzoic acid (ADB) as linker. Combining band-structure and cluster-based simulations on ADB chromophores in various conformations and aggregation states, we are able to provide a detailed explanation of the experimentally observed photophysical properties of Zn-ADB SURMOF-2: The unexpected (weak) red-shift of the absorption maxima upon incorporating ADB chromophores into SURMOF-2 can be explained by a combination of excitonic coupling effects with conformational changes of the chromophores already in their ground state. As far as the unusually large red-shift of the emission of Zn-ADB SURMOF-2 is concerned, based on our simulations, we attribute it to a modification of the exciton coupling compared to conventional H-aggregates, which results from a relative slip of the centers of neighboring chromophores upon incorporation in Zn-ADB SURMOF-2.


Nanoscale ◽  
2021 ◽  
Author(s):  
Dongdong Yan ◽  
Qionghua Mo ◽  
Shuangyi Zhao ◽  
Wensi Cai ◽  
Zhigang Zang

With a high photoluminescence quantum yield (PLQY) being able to exceed 90% for those prepared by hot injection method, CsPbBr3 quantum dots (QDs) have attracted intensive attentions for white light-emitting...


2021 ◽  
Author(s):  
Yingxue Tu ◽  
Caifen Lei ◽  
Fei Deng ◽  
Yiang Chen ◽  
Ying Wang ◽  
...  

Metal organic frameworks (MOFs) have the potential to boost the undervalued biomedical applications of metal ions. Such endeavor has been hindered by the challenge of how to avoid the (cyto)toxicity...


RSC Advances ◽  
2021 ◽  
Vol 11 (42) ◽  
pp. 26415-26420
Author(s):  
Yue Yao ◽  
Si-Wei Zhang ◽  
Zijian Liu ◽  
Chun-Yun Wang ◽  
Ping Liu ◽  
...  

A Bi3+-doped Cs2SnCl6 exhibits photoluminescence at around 456 nm and a photoluminescence quantum yield of 31%. The blue LED based on the Bi3+-doped Cs2SnCl6 phosphor exhibits a long life of 120 hours and a CIE color coordinates of (0.14, 0.11).


2016 ◽  
Vol 52 (14) ◽  
pp. 3003-3006 ◽  
Author(s):  
Linyi Bai ◽  
Binbin Tu ◽  
Yi Qi ◽  
Qiang Gao ◽  
Dong Liu ◽  
...  

Incorporating supramolecular recognition units, crown ether rings, into metal–organic frameworks enables the docking of metal ions through complexation for enhanced performance.


2021 ◽  
Vol 50 (14) ◽  
pp. 4757-4764
Author(s):  
Yan Yan Li ◽  
Dong Luo ◽  
Kun Wu ◽  
Xiao-Ping Zhou

This review article summarizes the assembly, structures, and topologies of gyroidal metal–organic frameworks. Their applications in gas adsorption, catalysis, sensors, and luminescent materials are also discussed in detail.


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