Modular chiral Eu(III) complexes for efficient circularly polarized OLEDs

Achieving both high dissymmetry factors and strong emission in circularly polarized (CP) luminescent materials and, at the same time, compatibility with manufacturing processes for organic electronic devices, is a crucial...

Halide-containing organic persistent luminescent materials for environmental sensing applications

This review presents a summary of the molecular design of halide-containing organic persistent luminescent materials, and their environmental sensing applications.

Unravelling the origin of dual photoluminescence in Au2Cu6 clusters by triplet sensitization and photon upconversion

Ligand-protected, noble-metal clusters are promising as luminescent materials and photosensitizers because of their diverse chemical compositions and structures, as well as their easily tunable electronic and photophysical properties with single-atom...

Negative Thermal Quenching of Photoluminescence from Liquid-Crystalline Molecules in Condensed Phases

The luminescence of materials in condensed phases is affected by not only their molecular structures but also their aggregated structures. In this study, we designed new liquid-crystalline luminescent materials based on biphenylacetylene with a bulky trimethylsilyl terminal group and a flexible alkoxy chain. The luminescence properties of the prepared materials were evaluated, with a particular focus on the effects of phase transitions, which cause changes in the aggregated structures. The length of the flexible chain had no effect on the luminescence in solution. However, in crystals, the luminescence spectral shape depended on the chain length because varying the chain length altered the crystal structure. Interestingly, negative thermal quenching of the luminescence from these materials was observed in condensed phases, with the isotropic phase obtained at high temperatures exhibiting a considerable increase in luminescence intensity. This thermal enhancement of the luminescence suggests that the less- or nonemissive aggregates formed in crystals are dissociated in the isotropic phase. These findings can contribute toward the development of new material design concepts for useful luminescent materials at high temperatures.