Construction of a series of metal–organic frameworks based on novel flexible ligand 4-carboxy-1-(3,5-dicarboxy-benzyl)-pyridinium chloride and selective d-block metal ions: crystal structures and photoluminescence

CrystEngComm ◽  
2015 ◽  
Vol 17 (33) ◽  
pp. 6297-6307 ◽  
Author(s):  
Hai-Yang Li ◽  
Li-Hui Cao ◽  
Yong-Li Wei ◽  
Hong Xu ◽  
Shuang-Quan Zang
Keyword(s):  
Metal Ions ◽  
Crystal Structures ◽  
Metal Organic Frameworks ◽  
Pyridinium Chloride ◽  
Flexible Ligand ◽  
Metal Organic

scholarly journals Selective CO2 adsorption in water-stable alkaline-earth based metal–organic frameworks

2018 ◽  
Vol 5 (3) ◽  
pp. 541-549 ◽  
Author(s):  
Yiwen Tang ◽  
Andreas Kourtellaris ◽  
Anastasios J. Tasiopoulos ◽  
Simon J. Teat ◽  
David Dubbeldam ◽  
...  
Keyword(s):  
Metal Ions ◽  
High Stability ◽  
Alkaline Earth ◽  
Co2 Adsorption ◽  
Metal Organic Frameworks ◽  
Earth Metal ◽  
Alkaline Earth Metal ◽  
Flexible Ligand ◽  
Alkaline Earth Metal Ions ◽  
Metal Organic

Four novel metal–organic frameworks (MOFs) built from alkaline-earth metal ions and the flexible ligand tetrakis[4-(carboxyphenyl)oxamethyl]methane acid (H4L) were synthesized. Among them, Ca-based MOFs have high stability under humidity conditions and show good CO2 uptake.

Negative linear compressibility in nanoporous metal-organic frameworks rationalized by the empty channel structural mechanism

2021 ◽  
Author(s):  
Francisco Colmenero
Keyword(s):  
Crystal Structures ◽  
Metal Organic Frameworks ◽  
Structural Mechanism ◽  
Nanoporous Metal ◽  
Metal Organic ◽  
Linear Compressibility

Cobalt squarate hydroxide (Co3(C4O4)2(OH)2), zinc squarate tetrahydrate (ZnC4O4·4 H2O) and titanium oxalate trioxide dihydrate (Ti2(C2O4)O3·2 H2O) are nanoporous metal-organic frameworks possessing empty channels in their crystal structures. The crystal structures...

scholarly journals Experimental investigations on the irregular synthesis of the iron(III) terephthalate metal-organic frameworks MOF-235 and MIL-101

2021 ◽  
Author(s):  
Isabelle Simonsson ◽  
Philip Gärdhagen ◽  
Moira Andrén ◽  
Pui Lam Tam ◽  
Zareen Abbas
Keyword(s):  
Crystal Structures ◽  
Metal Organic Frameworks ◽  
Experimental Investigations ◽  
Surface Areas ◽  
Metal Organic

(Fe)-MOF-235 and (Fe)-MIL-101 are two well-studied iron(III) terephthalate metal-organic frameworks (MOFs) with dissimilar crystal structures and topologies. Previously reported syntheses of the former show greatly varying surface areas, indicating a...

Core-shell ZIF-8@polydopamine nanoparticles obtained by mitigating polydopamine coating induced self-etching of MOFs: prototypical metal ion reservoirs for sticking to and killing bacteria

2021 ◽  
Author(s):  
Yingxue Tu ◽  
Caifen Lei ◽  
Fei Deng ◽  
Yiang Chen ◽  
Ying Wang ◽  
...  
Keyword(s):  
Metal Ions ◽  
Metal Ion ◽  
Biomedical Applications ◽  
Metal Organic Frameworks ◽  
Core Shell ◽  
Metal Organic

Metal organic frameworks (MOFs) have the potential to boost the undervalued biomedical applications of metal ions. Such endeavor has been hindered by the challenge of how to avoid the (cyto)toxicity...

Enhanced performance in gas adsorption and Li ion batteries by docking Li+ in a crown ether-based metal–organic framework

2016 ◽  
Vol 52 (14) ◽  
pp. 3003-3006 ◽  
Author(s):  
Linyi Bai ◽  
Binbin Tu ◽  
Yi Qi ◽  
Qiang Gao ◽  
Dong Liu ◽  
...  
Keyword(s):  
Crown Ether ◽  
Metal Ions ◽  
Gas Adsorption ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Li Ion Batteries ◽  
Metal Organic ◽  
Li Ion ◽  
Organic Framework

Incorporating supramolecular recognition units, crown ether rings, into metal–organic frameworks enables the docking of metal ions through complexation for enhanced performance.

Microporous lanthanide metal-organic frameworks

2012 ◽  
Vol 32 (2-4) ◽  
pp. 81-100 ◽  
Author(s):  
Yao Chen ◽  
Shengqian Ma
Keyword(s):  
Optical Properties ◽  
Metal Ions ◽  
Porous Materials ◽  
Chemical Sensing ◽  
Metal Organic Frameworks ◽  
Current Status ◽  
Multifunctional Materials ◽  
Metal Organic ◽  
Lanthanide Metal ◽  
Solvent Adsorption

AbstractMicroporous metal-organic frameworks (MOFs) based on lanthanide metal ions or clusters represent a group of porous materials, featuring interesting coordination, electronic, and optical properties. These attractive properties in combination with the porosity make microporous lanthanide MOFs (Ln-MOFs) hold the promise for various applications. This review is to provide an overview of the current status of the research in microporous Ln-MOFs, and highlight their potential as types of multifunctional materials for applications in gas/solvent adsorption and separation, luminescence and chemical sensing and catalysis.

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