Dye-functionalized Metal-Organic Frameworks with the Uniform Dispersion of MnO2 Nanosheets for Visualized Fluorescence Detection of Alanine Aminotransferase

Nanoscale ◽  
2021 ◽  
Author(s):  
Haifeng Sha ◽  
Bing Yan

The wide applications of metal-organic frameworks (MOFs) luminescent materials in the field of optics have attracted the general attention of researchers. Therefore, the development of simple and multifunctional MOFs light-emitting...

2015 ◽  
Vol 44 (20) ◽  
pp. 9588-9595 ◽  
Author(s):  
Shanghua Xing ◽  
Guang Zeng ◽  
Xiaomin Liu ◽  
Fen Yang ◽  
Zhiqiang Hao ◽  
...  

Multifunctional luminescent materials of six Ln-MOFs have been designed and synthesized by the co-doping strategy. Thus a wide range of light emitting spectra and different temperature-dependent luminescence behavior were displayed.


Author(s):  
Qiufen Liu ◽  
Shouqin Tian ◽  
Xiujian Zhao ◽  
Gopinathan Sankar

Metal organic frameworks (MOFs) constructed by metal ions/clusters and organic linkers become new porous luminescent materials and thus have attracted much attention. But their photoluminescence quantum yield (PLQY) is not...


Molecules ◽  
2020 ◽  
Vol 25 (18) ◽  
pp. 4230
Author(s):  
Andreas Windischbacher ◽  
Luca Steiner ◽  
Ritesh Haldar ◽  
Christof Wöll ◽  
Egbert Zojer ◽  
...  

In recent years, the photophysical properties of crystalline metal-organic frameworks (MOFs) have become increasingly relevant for their potential application in light-emitting devices, photovoltaics, nonlinear optics and sensing. The availability of high-quality experimental data for such systems makes them ideally suited for a validation of quantum mechanical simulations, aiming at an in-depth atomistic understanding of photophysical phenomena. Here we present a computational DFT study of the absorption and emission characteristics of a Zn-based surface-anchored metal-organic framework (Zn-SURMOF-2) containing anthracenedibenzoic acid (ADB) as linker. Combining band-structure and cluster-based simulations on ADB chromophores in various conformations and aggregation states, we are able to provide a detailed explanation of the experimentally observed photophysical properties of Zn-ADB SURMOF-2: The unexpected (weak) red-shift of the absorption maxima upon incorporating ADB chromophores into SURMOF-2 can be explained by a combination of excitonic coupling effects with conformational changes of the chromophores already in their ground state. As far as the unusually large red-shift of the emission of Zn-ADB SURMOF-2 is concerned, based on our simulations, we attribute it to a modification of the exciton coupling compared to conventional H-aggregates, which results from a relative slip of the centers of neighboring chromophores upon incorporation in Zn-ADB SURMOF-2.


RSC Advances ◽  
2017 ◽  
Vol 7 (17) ◽  
pp. 10415-10423 ◽  
Author(s):  
Yu Wu ◽  
Jian Wu ◽  
Zhidong Luo ◽  
Jun Wang ◽  
Yulong Li ◽  
...  

Two new MOFs show 3D 2-fold interpenetrating 4-connected networks and could be a prospective candidate for developing the luminescence sensors and the photocatalysis due to their highly stabilities.


2021 ◽  
Vol 50 (14) ◽  
pp. 4757-4764
Author(s):  
Yan Yan Li ◽  
Dong Luo ◽  
Kun Wu ◽  
Xiao-Ping Zhou

This review article summarizes the assembly, structures, and topologies of gyroidal metal–organic frameworks. Their applications in gas adsorption, catalysis, sensors, and luminescent materials are also discussed in detail.


2019 ◽  
Vol 58 (23) ◽  
pp. 7818-7822 ◽  
Author(s):  
Chengdong Peng ◽  
Xueling Song ◽  
Jinlin Yin ◽  
Guiyang Zhang ◽  
Honghan Fei

2021 ◽  
Author(s):  
Hsinhan Tsai ◽  
Shreetu Shrestha ◽  
Rafael A. Vilá ◽  
Wenxiao Huang ◽  
Cunming Liu ◽  
...  

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