scholarly journals Osmium(II) Tethered Half-Sandwich Complexes: pH-dependent Aqueous Speciation and Transfer Hydrogenation in Cells

2021 ◽  
Author(s):  
Sonia Infante-Tadeo ◽  
Vanessa Rodriguez ◽  
Abraha Habtemariam ◽  
Ana M. Pizarro
Keyword(s):  
Transfer Hydrogenation ◽  
Sandwich Complexes ◽  
Hemilabile Ligands ◽  
New Family ◽  
Ph Dependent ◽  
Half Sandwich ◽  
In Cells

Aquation is often acknowledged as a necessary step for metallodrug activity inside the cell. Hemilabile ligands can be used for reversible metallodrug activation. We report a new family of osmium(II)...

scholarly journals 16-Electron pentadienyl- and cyclopentadienyl-ruthenium half-sandwich complexes with bis(imidazol-2-imine) ligands and their use in catalytic transfer hydrogenation

2015 ◽  
Vol 44 (26) ◽  
pp. 11717-11724 ◽  
Author(s):  
Thomas Glöge ◽  
Kristof Jess ◽  
Thomas Bannenberg ◽  
Peter G. Jones ◽  
Nadine Langenscheidt-Dabringhausen ◽  
...  
Keyword(s):  
Ligand Exchange ◽  
Transfer Hydrogenation ◽  
Catalytic Transfer Hydrogenation ◽  
Sandwich Complexes ◽  
Hydrogenation Catalysts ◽  
Catalytic Transfer ◽  
Imine Ligands ◽  
Half Sandwich ◽  
Efficient Transfer

Ligand exchange from “protonated open ruthenocene” afforded 16-electron ruthenium half-sandwich complexes as efficient transfer hydrogenation catalysts.

scholarly journals Quinoline-triazole half-sandwich iridium(iii) complexes: synthesis, antiplasmodial activity and preliminary transfer hydrogenation studies

2020 ◽  
Vol 49 (33) ◽  
pp. 11543-11555
Author(s):  
Diana R. Melis ◽  
Christopher B. Barnett ◽  
Lubbe Wiesner ◽  
Ebbe Nordlander ◽  
Gregory S. Smith
Keyword(s):  
Plasmodium Falciparum ◽  
Malaria Parasite ◽  
Transfer Hydrogenation ◽  
Antiplasmodial Activity ◽  
Sandwich Complexes ◽  
Inhibitory Activities ◽  
Hybrid Ligands ◽  
Half Sandwich

Iridium(iii) half-sandwich complexes containing 7-chloroquinoline-1,2,3-triazole hybrid ligands were synthesised and their inhibitory activities evaluated against the Plasmodium falciparum malaria parasite.

Half-Sandwich Complexes of Osmium(II) withl-α-Amino Carboxylate Ligands as Asymmetric Transfer Hydrogenation Catalysts. On the Origin of the Enantioselectivity

2012 ◽  
Vol 31 (8) ◽  
pp. 3333-3345 ◽  
Author(s):  
Daniel Carmona ◽  
Fernando J. Lahoz ◽  
Pilar García-Orduña ◽  
Luis A. Oro ◽  
M. Pilar Lamata ◽  
...  
Keyword(s):  
Transfer Hydrogenation ◽  
Asymmetric Transfer Hydrogenation ◽  
Sandwich Complexes ◽  
Carboxylate Ligands ◽  
Hydrogenation Catalysts ◽  
Half Sandwich

Role of the sulfonamide moiety of Ru(II) half-sandwich complexes in the asymmetric transfer hydrogenation of 3,4-dihydroisoquinolines

2016 ◽  
Vol 118 (1) ◽  
pp. 215-222 ◽  
Author(s):  
Ondřej Matuška ◽  
Jakub Zápal ◽  
Radka Hrdličková ◽  
Miloš Mikoška ◽  
Jan Pecháček ◽  
...  
Keyword(s):  
Transfer Hydrogenation ◽  
Asymmetric Transfer Hydrogenation ◽  
Sandwich Complexes ◽  
Half Sandwich

Enantioselective hydrogenation of cyclic imines catalysed by Noyori–Ikariya half-sandwich complexes and their analogues

2016 ◽  
Vol 52 (2) ◽  
pp. 362-365 ◽  
Author(s):  
B. Vilhanová ◽  
J. Václavík ◽  
P. Šot ◽  
J. Pecháček ◽  
J. Zápal ◽  
...  
Keyword(s):  
Trifluoroacetic Acid ◽  
Asymmetric Hydrogenation ◽  
Enantioselective Hydrogenation ◽  
Transfer Hydrogenation ◽  
Sandwich Complexes ◽  
Hydrogenation Catalysts ◽  
Half Sandwich

Trifluoroacetic acid activates cyclic imines in a new non-air sensitive asymmetric hydrogenation method. New transfer hydrogenation catalysts are demonstrated.

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