Enantioselective hydrogenation of cyclic imines catalysed by Noyori–Ikariya half-sandwich complexes and their analogues

2016 ◽  
Vol 52 (2) ◽  
pp. 362-365 ◽  
Author(s):  
B. Vilhanová ◽  
J. Václavík ◽  
P. Šot ◽  
J. Pecháček ◽  
J. Zápal ◽  
...  
Keyword(s):  
Trifluoroacetic Acid ◽  
Asymmetric Hydrogenation ◽  
Enantioselective Hydrogenation ◽  
Transfer Hydrogenation ◽  
Sandwich Complexes ◽  
Hydrogenation Catalysts ◽  
Half Sandwich

Trifluoroacetic acid activates cyclic imines in a new non-air sensitive asymmetric hydrogenation method. New transfer hydrogenation catalysts are demonstrated.

scholarly journals 16-Electron pentadienyl- and cyclopentadienyl-ruthenium half-sandwich complexes with bis(imidazol-2-imine) ligands and their use in catalytic transfer hydrogenation

2015 ◽  
Vol 44 (26) ◽  
pp. 11717-11724 ◽  
Author(s):  
Thomas Glöge ◽  
Kristof Jess ◽  
Thomas Bannenberg ◽  
Peter G. Jones ◽  
Nadine Langenscheidt-Dabringhausen ◽  
...  
Keyword(s):  
Ligand Exchange ◽  
Transfer Hydrogenation ◽  
Catalytic Transfer Hydrogenation ◽  
Sandwich Complexes ◽  
Hydrogenation Catalysts ◽  
Catalytic Transfer ◽  
Imine Ligands ◽  
Half Sandwich ◽  
Efficient Transfer

Ligand exchange from “protonated open ruthenocene” afforded 16-electron ruthenium half-sandwich complexes as efficient transfer hydrogenation catalysts.

Half-Sandwich Complexes of Osmium(II) withl-α-Amino Carboxylate Ligands as Asymmetric Transfer Hydrogenation Catalysts. On the Origin of the Enantioselectivity

2012 ◽  
Vol 31 (8) ◽  
pp. 3333-3345 ◽  
Author(s):  
Daniel Carmona ◽  
Fernando J. Lahoz ◽  
Pilar García-Orduña ◽  
Luis A. Oro ◽  
M. Pilar Lamata ◽  
...  
Keyword(s):  
Transfer Hydrogenation ◽  
Asymmetric Transfer Hydrogenation ◽  
Sandwich Complexes ◽  
Carboxylate Ligands ◽  
Hydrogenation Catalysts ◽  
Half Sandwich

scholarly journals Quinone Reduction by Organo-Osmium Half-Sandwich Transfer Hydrogenation Catalysts

2021 ◽  
Vol 40 (17) ◽  
pp. 3012-3023
Author(s):  
Elizabeth M. Bolitho ◽  
Nathan G. Worby ◽  
James P. C. Coverdale ◽  
Juliusz A. Wolny ◽  
Volker Schünemann ◽  
...  
Keyword(s):  
Transfer Hydrogenation ◽  
Hydrogenation Catalysts ◽  
Quinone Reduction ◽  
Half Sandwich

scholarly journals Practical Aspects and Mechanism of Asymmetric Hydrogenation with Chiral Half-Sandwich Complexes

Molecules ◽  
2013 ◽  
Vol 18 (6) ◽  
pp. 6804-6828 ◽  
Author(s):  
Jiří Václavík ◽  
Petr Šot ◽  
Beáta Vilhanová ◽  
Jan Pecháček ◽  
Marek Kuzma ◽  
...  
Keyword(s):  
Asymmetric Hydrogenation ◽  
Sandwich Complexes ◽  
Half Sandwich

N,O-Chelating quinoline-based half-sandwich organorhodium and -iridium complexes: synthesis, antiplasmodial activity and preliminary evaluation as transfer hydrogenation catalysts for the reduction of NAD+

2019 ◽  
Vol 48 (35) ◽  
pp. 13143-13148 ◽  
Author(s):  
Tameryn Stringer ◽  
Diana R. Melis ◽  
Gregory S. Smith
Keyword(s):  
Plasmodium Falciparum ◽  
Transfer Hydrogenation ◽  
Antiplasmodial Activity ◽  
Preliminary Evaluation ◽  
Iridium Complexes ◽  
Drug Resistant ◽  
Hydrogenation Catalysts ◽  
Half Sandwich

Two Rh(iii) and Ir(iii) half-sandwich quinoline-based complexes were evaluated for theirin vitroantiplasmodial activity against the chloroquine-sensitive NF54 and multi-drug resistant K1 strains of the parasite,Plasmodium falciparum.

scholarly journals Quinoline-triazole half-sandwich iridium(iii) complexes: synthesis, antiplasmodial activity and preliminary transfer hydrogenation studies

2020 ◽  
Vol 49 (33) ◽  
pp. 11543-11555
Author(s):  
Diana R. Melis ◽  
Christopher B. Barnett ◽  
Lubbe Wiesner ◽  
Ebbe Nordlander ◽  
Gregory S. Smith
Keyword(s):  
Plasmodium Falciparum ◽  
Malaria Parasite ◽  
Transfer Hydrogenation ◽  
Antiplasmodial Activity ◽  
Sandwich Complexes ◽  
Inhibitory Activities ◽  
Hybrid Ligands ◽  
Half Sandwich

Iridium(iii) half-sandwich complexes containing 7-chloroquinoline-1,2,3-triazole hybrid ligands were synthesised and their inhibitory activities evaluated against the Plasmodium falciparum malaria parasite.

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