scholarly journals 16-Electron pentadienyl- and cyclopentadienyl-ruthenium half-sandwich complexes with bis(imidazol-2-imine) ligands and their use in catalytic transfer hydrogenation

2015 ◽  
Vol 44 (26) ◽  
pp. 11717-11724 ◽  
Author(s):  
Thomas Glöge ◽  
Kristof Jess ◽  
Thomas Bannenberg ◽  
Peter G. Jones ◽  
Nadine Langenscheidt-Dabringhausen ◽  
...  
Keyword(s):  
Ligand Exchange ◽  
Transfer Hydrogenation ◽  
Catalytic Transfer Hydrogenation ◽  
Sandwich Complexes ◽  
Hydrogenation Catalysts ◽  
Catalytic Transfer ◽  
Imine Ligands ◽  
Half Sandwich ◽  
Efficient Transfer

Ligand exchange from “protonated open ruthenocene” afforded 16-electron ruthenium half-sandwich complexes as efficient transfer hydrogenation catalysts.

scholarly journals Chelating N-heterocyclic carbene–carboranes offer flexible ligand coordination to IrIII, RhIII and RuII: effect of ligand cyclometallation in catalytic transfer hydrogenation

2016 ◽  
Vol 45 (40) ◽  
pp. 15818-15827 ◽  
Author(s):  
Jordan Holmes ◽  
Christopher M. Pask ◽  
Charlotte E. Willans
Keyword(s):  
Boron Atom ◽  
Transfer Hydrogenation ◽  
Catalytic Transfer Hydrogenation ◽  
Hydrogenation Catalysts ◽  
Flexible Ligand ◽  
Ligand Coordination ◽  
Catalytic Transfer ◽  
Effective Transfer

NHC–carborane ligands, with flexible coordination through either the carbon or the boron atom of the carborane, provide effective transfer hydrogenation catalysts.

Quinine-Derived Imidazolidin-2-imine Ligands: Synthesis, Coordination Chemistry, and Application in Catalytic Transfer Hydrogenation

2010 ◽  
Vol 636 (5) ◽  
pp. 691-699 ◽  
Author(s):  
Sabina-Alexandra Filimon ◽  
Cristian G. Hrib ◽  
Sören Randoll ◽  
Ion Neda ◽  
Peter G. Jones ◽  
...  
Keyword(s):  
Coordination Chemistry ◽  
Transfer Hydrogenation ◽  
Catalytic Transfer Hydrogenation ◽  
Catalytic Transfer ◽  
Imine Ligands

Half-Sandwich Complexes of Osmium(II) withl-α-Amino Carboxylate Ligands as Asymmetric Transfer Hydrogenation Catalysts. On the Origin of the Enantioselectivity

2012 ◽  
Vol 31 (8) ◽  
pp. 3333-3345 ◽  
Author(s):  
Daniel Carmona ◽  
Fernando J. Lahoz ◽  
Pilar García-Orduña ◽  
Luis A. Oro ◽  
M. Pilar Lamata ◽  
...  
Keyword(s):  
Transfer Hydrogenation ◽  
Asymmetric Transfer Hydrogenation ◽  
Sandwich Complexes ◽  
Carboxylate Ligands ◽  
Hydrogenation Catalysts ◽  
Half Sandwich

Enantioselective hydrogenation of cyclic imines catalysed by Noyori–Ikariya half-sandwich complexes and their analogues

2016 ◽  
Vol 52 (2) ◽  
pp. 362-365 ◽  
Author(s):  
B. Vilhanová ◽  
J. Václavík ◽  
P. Šot ◽  
J. Pecháček ◽  
J. Zápal ◽  
...  
Keyword(s):  
Trifluoroacetic Acid ◽  
Asymmetric Hydrogenation ◽  
Enantioselective Hydrogenation ◽  
Transfer Hydrogenation ◽  
Sandwich Complexes ◽  
Hydrogenation Catalysts ◽  
Half Sandwich

Trifluoroacetic acid activates cyclic imines in a new non-air sensitive asymmetric hydrogenation method. New transfer hydrogenation catalysts are demonstrated.

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