Aerobic Oxidation of Primary Amines to Amides Catalyzed by an Annulated Mesoionic Carbene (MIC) Stabilized Ru Complex

Author(s):  
Jitendra K Bera ◽  
Suman Yadav ◽  
Noor U Din Reshi ◽  
Saikat Pal

Catalytic aerobic oxidation of primary amines to the amides, using the precatalyst [Ru(COD)(L1)Br2] (1) bearing an annulated π−conjugated imidazo[1,2−a][1,8]naphthyridine-based mesoionic carbene ligand L1, is disclosed. This catalytic protocol is distinguished...

2008 ◽  
Vol 47 (11) ◽  
pp. 2079-2081 ◽  
Author(s):  
Ken Suzuki ◽  
Tomonari Watanabe ◽  
Shun-Ichi Murahashi

2019 ◽  
Vol 9 (6) ◽  
pp. 1511-1517 ◽  
Author(s):  
Yusuke Isaka ◽  
Yoshifumi Kondo ◽  
Yasutaka Kuwahara ◽  
Kohsuke Mori ◽  
Hiromi Yamashita

Encapsulation of [Ru(bpy)3]2+ in the cavity of a metal–organic framework was found to enhance its activity in the photocatalytic aerobic oxidation of benzyl alcohol.


2018 ◽  
Vol 24 (59) ◽  
pp. 15766-15771 ◽  
Author(s):  
Susanta Hazra ◽  
Priti Pilania ◽  
Mayukh Deb ◽  
Ajay Kishor Kushawaha ◽  
Anil J. Elias

2017 ◽  
Vol 53 (28) ◽  
pp. 4006-4009 ◽  
Author(s):  
Ritwika Ray ◽  
Shubhadeep Chandra ◽  
Vishal Yadav ◽  
Prasenjit Mondal ◽  
Debabrata Maiti ◽  
...  

A ligand controlled catalytic system for the aerobic oxidation of 1° amines to nitriles and imines has been developed where the varying π-acidic feature of BIAN versus phen in the frameworks of ruthenium catalysts facilitates switchable selectivity.


2015 ◽  
Vol 51 (48) ◽  
pp. 9880-9883 ◽  
Author(s):  
Xiao Yu ◽  
Seth M. Cohen

A photocatalytic Ru complex was incorporated into a Zr(iv)-based MOF via postsynthetic methods, to give an efficient and recyclable catalytic material for the aerobic oxidation of arylboronic acids under light irradiation.


2012 ◽  
Vol 14 (11) ◽  
pp. 2850-2853 ◽  
Author(s):  
Alison E. Wendlandt ◽  
Shannon S. Stahl

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