scholarly journals Photocatalytic metal–organic frameworks for the aerobic oxidation of arylboronic acids

2015 ◽  
Vol 51 (48) ◽  
pp. 9880-9883 ◽  
Author(s):  
Xiao Yu ◽  
Seth M. Cohen
Keyword(s):  
Aerobic Oxidation ◽  
Metal Organic Frameworks ◽  
Light Irradiation ◽  
Arylboronic Acids ◽  
Ru Complex ◽  
Catalytic Material ◽  
Metal Organic

A photocatalytic Ru complex was incorporated into a Zr(iv)-based MOF via postsynthetic methods, to give an efficient and recyclable catalytic material for the aerobic oxidation of arylboronic acids under light irradiation.

Bimetallic FexMny catalysts derived from metal organic frameworks for efficient photocatalytic removal of quinolones without oxidant

2021 ◽  
Author(s):  
Xin Li ◽  
Zhiyu Yang ◽  
Di Hu ◽  
Anqi Wang ◽  
Yuwen Chen ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Light Irradiation ◽  
Impregnation Method ◽  
Photocatalytic Removal ◽  
Metal Organic

Bimetallic magnetic FeMn catalysts have been successfully prepared by a facile impregnation method, and they exhibit efficient photocatalytic removal of a series of quinolones without oxidant under simulated light irradiation.

scholarly journals Cobalt-Based Metal Organic Frameworks as Solids Catalysts for Oxidation Reactions

Catalysts ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 95
Author(s):  
Amarajothi Dhakshinamoorthy ◽  
Eva Montero Lanzuela ◽  
Sergio Navalon ◽  
Hermenegildo Garcia
Keyword(s):  
Aerobic Oxidation ◽  
High Surface ◽  
Metal Organic Frameworks ◽  
High Surface Area ◽  
Acid Sites ◽  
Crystalline Lattice ◽  
Oxidation Reactions ◽  
Solid Catalysts ◽  
Long Term Stability ◽  
Metal Organic

Metal organic frameworks (MOFs) are porous crystalline solids whose frameworks are constituted by metal ions/nodes with rigid organic linkers leading to the formation of materials having high surface area and pore volume. One of the unique features of MOFs is the presence of coordinatively unsaturated metal sites in their crystalline lattice that can act as Lewis acid sites promoting organic transformations, including aerobic oxidation reactions of various substrates such as hydrocarbons, alcohols, and sulfides. This review article summarizes the existing Co-based MOFs for oxidation reactions organized according to the nature of substrates like hydrocarbon, alcohol, olefin, and water. Both aerobic conditions and peroxide oxidants are discussed. Emphasis is placed on comparing the advantages of using MOFs as solid catalysts with respect to homogeneous salts in terms of product selectivity and long-term stability. The final section provides our view on future developments in this field.

Aerobic oxidation of thiols to disulfides using iron metal–organic frameworks as solid redox catalysts

2010 ◽  
Vol 46 (35) ◽  
pp. 6476 ◽  
Author(s):  
Amarajothi Dhakshinamoorthy ◽  
Mercedes Alvaro ◽  
Hermenegildo Garcia
Keyword(s):  
Aerobic Oxidation ◽  
Metal Organic Frameworks ◽  
Iron Metal ◽  
Redox Catalysts ◽  
Metal Organic

scholarly journals Diagnosing surface versus bulk reactivity for molecular catalysis within metal–organic frameworks using a quantitative kinetic model

2020 ◽  
Vol 11 (28) ◽  
pp. 7468-7478
Author(s):  
Ben A. Johnson ◽  
Sascha Ott
Keyword(s):  
Kinetic Model ◽  
Charge Transport ◽  
Reaction Rate ◽  
Metal Organic Frameworks ◽  
Material Design ◽  
Surface Versus ◽  
Catalytic Material ◽  
Metal Organic ◽  
Intrinsic Reaction Rate ◽  
Molecular Catalysis

This report presents diagnostic criteria for determining the limiting processes of MOF-based catalysis: either mass/charge transport or the intrinsic reaction rate. This will facilitate future catalytic material design.

Cerium‐Based Metal–Organic Frameworks with UiO Architecture for Visible Light‐Induced Aerobic Oxidation of Benzyl Alcohol

Solar RRL ◽  
2019 ◽  
Vol 4 (8) ◽  
pp. 1900449 ◽  
Author(s):  
Xueying Qiu ◽  
Yanfei Zhu ◽  
Xiaofei Zhang ◽  
Yin Zhang ◽  
Leta Takele Menisa ◽  
...  
Keyword(s):  
Visible Light ◽  
Benzyl Alcohol ◽  
Aerobic Oxidation ◽  
Metal Organic Frameworks ◽  
Oxidation Of Benzyl Alcohol ◽  
Metal Organic

Aerobic homocoupling of arylboronic acids catalysed by copper terephthalate metal–organic frameworks

2014 ◽  
Vol 16 (5) ◽  
pp. 2865 ◽  
Author(s):  
Pillaiyar Puthiaraj ◽  
Palaniswamy Suresh ◽  
Kasi Pitchumani
Keyword(s):  
Metal Organic Frameworks ◽  
Arylboronic Acids ◽  
Metal Organic

scholarly journals Ce-Doped Graphitic Carbon Nitride Derived from Metal Organic Frameworks as a Visible Light-Responsive Photocatalyst for H2 Production

Nanomaterials ◽  
2019 ◽  
Vol 9 (11) ◽  
pp. 1539 ◽  
Author(s):  
Liangjing Zhang ◽  
Zhengyuan Jin ◽  
Shaolong Huang ◽  
Yiyue Zhang ◽  
Mei Zhang ◽  
...  
Keyword(s):  
Photocatalytic Activity ◽  
Visible Light ◽  
Visible Light Irradiation ◽  
Carbon Nitride ◽  
Metal Organic Frameworks ◽  
Graphitic Carbon ◽  
Light Irradiation ◽  
Graphitic Carbon Nitride ◽  
Enhanced Absorption ◽  
Metal Organic

Novel fibrous graphitic carbon nitride (g-C3N4) derivatives prepared from metal organic frameworks (MOFs) were doped with Ce3+ (Ce-C3N4) as photocatalytic materials. Ce-C3N4 was characterized using various techniques, revealing its high specific surface area, excellent photocatalytic activity, and stability for H2 evolution under visible light irradiation. The fluorine modified samples show superior photocatalytic activity under visible light irradiation, which is due to the presence of more active sites and enhanced absorption of solar energy. This work provides a new synthetic route for MOF-derived g-C3N4 that can be doped with different metal ions. The fluorine modified Ce-C3N4 is an efficient photocatalyst with potential for many applications related to energy and the environment.

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