Catalysis of a hydroxyapatite-bound Ru complex: efficient heterogeneous oxidation of primary amines to nitriles in the presence of molecular oxygen

2001 ◽  
pp. 461-462 ◽  
Author(s):  
Kohsuke Mori ◽  
Kazuya Yamaguchi ◽  
Tomoo Mizugaki ◽  
Kohki Ebitani ◽  
Kiyotomi Kaneda
Keyword(s):  
Molecular Oxygen ◽  
Primary Amines ◽  
Heterogeneous Oxidation ◽  
Ru Complex

ChemInform Abstract: Catalysis of a Hydroxyapatite-Bound Ru Complex: Efficient Heterogeneous Oxidation of Primary Amines to Nitriles in the Presence of Molecular Oxygen.

ChemInform ◽  
2010 ◽  
Vol 32 (24) ◽  
pp. no-no
Author(s):  
Kohsuke Mori ◽  
Kazuya Yamaguchi ◽  
Tomoo Mizugaki ◽  
Kohki Ebitani ◽  
Kiyotomi Kaneda
Keyword(s):  
Molecular Oxygen ◽  
Primary Amines ◽  
Heterogeneous Oxidation ◽  
Ru Complex

Efficient heterogeneous oxidation of organosilanes to silanols catalysed by a hydroxyapatite-bound Ru complex in the presence of water and molecular oxygen

2002 ◽  
Vol 26 (11) ◽  
pp. 1536-1538 ◽  
Author(s):  
Kohsuke Mori ◽  
Makoto Tano ◽  
Tomoo Mizugaki ◽  
Kohki Ebitani ◽  
Kiyotomi Kaneda
Keyword(s):  
Molecular Oxygen ◽  
Heterogeneous Oxidation ◽  
Ru Complex

Aerobic Oxidation of Primary Amines to Amides Catalyzed by an Annulated Mesoionic Carbene (MIC) Stabilized Ru Complex

2021 ◽  
Author(s):  
Jitendra K Bera ◽  
Suman Yadav ◽  
Noor U Din Reshi ◽  
Saikat Pal
Keyword(s):  
Aerobic Oxidation ◽  
Primary Amines ◽  
Ru Complex

Catalytic aerobic oxidation of primary amines to the amides, using the precatalyst [Ru(COD)(L1)Br2] (1) bearing an annulated π−conjugated imidazo[1,2−a][1,8]naphthyridine-based mesoionic carbene ligand L1, is disclosed. This catalytic protocol is distinguished...

Oxidation of Primary Amines to Oximes with Molecular Oxygen using 1,1-Diphenyl-2-picrylhydrazyl and WO3/Al2O3 as Catalysts

2013 ◽  
Vol 78 (6) ◽  
pp. 2301-2310 ◽  
Author(s):  
Ken Suzuki ◽  
Tomonari Watanabe ◽  
Shun-Ichi Murahashi
Keyword(s):  
Molecular Oxygen ◽  
Primary Amines

Efficient Heterogeneous Oxidation of Allylarenes with Molecular Oxygen.

ChemInform ◽  
2005 ◽  
Vol 36 (4) ◽  
Author(s):  
Keigo Kamata ◽  
Jun Kasai ◽  
Kazuya Yamaguchi ◽  
Noritaka Mizuno
Keyword(s):  
Molecular Oxygen ◽  
Heterogeneous Oxidation

Palladium in Heterogeneous Oxidation Catalysis

2016 ◽  
pp. 53-81
Author(s):  
Andreas Martin ◽  
Venkata Narayana Kalevaru ◽  
Jörg Radnik
Keyword(s):  
Benzyl Alcohol ◽  
Molecular Oxygen ◽  
Palladium Catalysts ◽  
Deep Understanding ◽  
Oxidation Catalysis ◽  
Benzyl Acetate ◽  
Heterogeneous Oxidation ◽  
Hydrogenation Reactions ◽  
Gas Phase Oxidation ◽  
Common Application

Palladium is one of the precious group metals mainly used in automobile catalytic converters. Besides, it has an importance in various catalytic processes. Although it is well known for hydrogenation reactions, various oxidations can also be catalyzed by palladium. This chapter gives an overview on the most common application of palladium catalysts in heterogeneously catalyzed acetoxylation, i.e. the acetoxylation of ethylene to vinyl acetate. Derived from this knowledge, the authors summarize in detail recently accumulated research results in acetoxylation of toluene to benzyl acetate that can be easily converted to benzyl alcohol. The chapter includes a detailed description of catalyst syntheses, gas phase oxidation runs, comprehensive characterizations and a deep understanding in catalyst-feed interaction. This development can turn away the manufacture of important petrochemicals from chlorine chemistry to oxidations using molecular oxygen.

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