Ligand controlled switchable selectivity in ruthenium catalyzed aerobic oxidation of primary amines

2017 ◽  
Vol 53 (28) ◽  
pp. 4006-4009 ◽  
Author(s):  
Ritwika Ray ◽  
Shubhadeep Chandra ◽  
Vishal Yadav ◽  
Prasenjit Mondal ◽  
Debabrata Maiti ◽  
...  
Keyword(s):  
Catalytic System ◽  
Aerobic Oxidation ◽  
Ruthenium Catalysts ◽  
Primary Amines

A ligand controlled catalytic system for the aerobic oxidation of 1° amines to nitriles and imines has been developed where the varying π-acidic feature of BIAN versus phen in the frameworks of ruthenium catalysts facilitates switchable selectivity.

A New Catalytic System for the Selective Aerobic Oxidation of Large Ring Cycloalkanes to Ketones

2003 ◽  
Vol 7 (3) ◽  
pp. 426-428 ◽  
Author(s):  
Xavier Baucherel ◽  
Isabel W. C. E. Arends ◽  
S. Ellwood ◽  
Roger A. Sheldon
Keyword(s):  
Catalytic System ◽  
Aerobic Oxidation ◽  
Large Ring ◽  
Selective Aerobic Oxidation

Aerobic Oxidation of Primary Amines to Amides Catalyzed by an Annulated Mesoionic Carbene (MIC) Stabilized Ru Complex

2021 ◽  
Author(s):  
Jitendra K Bera ◽  
Suman Yadav ◽  
Noor U Din Reshi ◽  
Saikat Pal
Keyword(s):  
Aerobic Oxidation ◽  
Primary Amines ◽  
Ru Complex

Catalytic aerobic oxidation of primary amines to the amides, using the precatalyst [Ru(COD)(L1)Br2] (1) bearing an annulated π−conjugated imidazo[1,2−a][1,8]naphthyridine-based mesoionic carbene ligand L1, is disclosed. This catalytic protocol is distinguished...

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