Pyrazolo[1,5-a]pyrimidine with similar “amino-nitro-amino” arrangement characteristics to TATB: A novel heat-resistant explosive with fused structure

CrystEngComm ◽  
2021 ◽  
Author(s):  
Feng Yang ◽  
Yuangang Xu ◽  
Pengcheng Wang ◽  
Qiuhan Lin ◽  
Fu-qiang Bi ◽  
...  
Keyword(s):  
Energetic Materials ◽  
Energetic Compounds ◽  
Heat Resistant ◽  
Fused Ring

Exploring heat-resistant explosives that are easy to synthesize is a major challenge in the research of energetic materials. In this study, two novel fused-ring energetic compounds 4 and 5 were...

Tunable Dimroth rearrangement of versatile 1,2,3-triazoles towards high-performance energetic materials

2021 ◽  
Author(s):  
Jean'ne M. Shreeve ◽  
Shangbiao Feng ◽  
Ping Yin ◽  
Chunlin He ◽  
Si-Ping Pang
Keyword(s):  
Energetic Materials ◽  
High Performance ◽  
Energetic Compounds ◽  
Dimroth Rearrangement ◽  
Efficient Strategy ◽  
Highly Efficient ◽  
Fused Ring ◽  
Different Types ◽  
Rearrangement Reactions

A highly efficient strategy of two different types of nitrogen-rich heterocyclic energetic compounds, featuring a single NH-bridge (-NH-) and a fused ring, was demonstrated by virtue of Dimroth rearrangement reactions...

scholarly journals Comparative thermal research on tetraazapentalene-derived heat-resistant energetic structures

2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Jing Zhou ◽  
Li Ding ◽  
Yong Zhu ◽  
Bozhou Wang ◽  
Xiangzhi Li ◽  
...  
Keyword(s):  
Differential Scanning Calorimetry ◽  
Thermal Decomposition ◽  
Fourier Transform ◽  
Energetic Materials ◽  
Great Influence ◽  
Fourier Transform Infrared ◽  
Thermal Decomposition Mechanism ◽  
Scanning Calorimetry ◽  
In Situ Ftir Spectroscopy ◽  
Heat Resistant

AbstractOrganic inner salt structures are ideal backbones for heat-resistant energetic materials and systematic studies towards the thermal properties of energetic organic inner salt structures are crucial to their applications. Herein, we report a comparative thermal research of two energetic organic inner salts with different tetraazapentalene backbones. Detailed thermal decomposition behaviors and kinetics were investigated through differential scanning calorimetry and thermogravimetric analysis (DSC-TG) methods, showing that the thermal stability of the inner salts is higher than most of the traditional heat-resistant energetic materials. Further studies towards the thermal decomposition mechanism were carried out through condensed-phase thermolysis/Fourier-transform infrared (in-situ FTIR) spectroscopy and the combination of differential scanning calorimetry-thermogravimetry-mass spectrometry-Fourier-transform infrared spectroscopy (DSC-TG-MS-FTIR) techniques. The experiment and calculation results prove that the arrangement of the inner salt backbones has great influence on the thermal decompositions of the corresponding energetic materials. The weak N4-N5 bond in “y-” pattern tetraazapentalene backbone lead to early decomposition process and the “z-” pattern tetraazapentalene backbone exhibits more concentrated decomposition behaviors.

Azasydnone – novel “green” building block for designing high energetic compounds

2018 ◽  
Vol 6 (38) ◽  
pp. 18669-18676 ◽  
Author(s):  
Igor L. Dalinger ◽  
Olga V. Serushkina ◽  
Nikita V. Muravyev ◽  
Dmitry B. Meerov ◽  
Evgeniy A. Miroshnichenko ◽  
...  
Keyword(s):  
Building Block ◽  
Energetic Materials ◽  
Green Building ◽  
Future Generations ◽  
Energetic Compounds

The azasydnone unit is a promising explosophoric block for future generations of highly thermostable and dense energetic materials.

New nitrogen-rich heterocyclic compounds to build 3D energetic metal complexes

CrystEngComm ◽  
2020 ◽  
Vol 22 (27) ◽  
pp. 4573-4579
Author(s):  
Xiaoming Yang ◽  
Yanna Wang ◽  
Weijing Zhang ◽  
Yanli Yin ◽  
Zhimin Li ◽  
...  
Keyword(s):  
Metal Complexes ◽  
Energetic Materials ◽  
Heterocyclic Compounds ◽  
Three Dimensional ◽  
Potassium Salts ◽  
Heat Resistant ◽  
Sodium And Potassium

By introducing hydroxymethyl into nitrogen-rich heterocyclic compounds, we designed and synthesized a new ligand. The three dimensional (3D) energetic metal complexes sodium and potassium salts of new ligand were investigated for heat-resistant energetic materials.

Multipurpose [1,2,4]triazolo[4,3-b][1,2,4,5] tetrazine-based energetic materials

2019 ◽  
Vol 7 (13) ◽  
pp. 7875-7884 ◽  
Author(s):  
Yingle Liu ◽  
Gang Zhao ◽  
Yongxing Tang ◽  
Jichuan Zhang ◽  
Lu Hu ◽  
...  
Keyword(s):  
Energetic Materials ◽  
Next Generation ◽  
Mechanical Sensitivity ◽  
Fused Ring

Next-generation fused ring energetic materials for different applications were designed by regulating mechanical sensitivity.

Tetrazolyl and dinitromethyl groups with 1,2,3-triazole lead to polyazole energetic materials

2019 ◽  
Vol 48 (10) ◽  
pp. 3237-3242 ◽  
Author(s):  
Yingle Liu ◽  
Chunlin He ◽  
Yongxing Tang ◽  
Gregory H. Imler ◽  
Damon A. Parrish ◽  
...  
Keyword(s):  
Energetic Materials ◽  
Energetic Compounds

A class of polyazole energetic compounds (combination of tetrazolyl, dinitromethyl and triazole) was obtained from 4,5-dicyanotriazole.

Exploring the reactive chemistry of FOX-7: synthesis of cyclic triazinane-based energetic materials featuring the FOX-7 backbone

2019 ◽  
Vol 43 (26) ◽  
pp. 10429-10433 ◽  
Author(s):  
Chao Yan ◽  
Guangbin Cheng ◽  
Kangcai Wang ◽  
Tianlin Liu ◽  
Yunhe Jin ◽  
...  
Keyword(s):  
Energetic Materials ◽  
Energetic Compounds ◽  
Derivatization Reaction

Unexpected derivatization reaction of FOX-7 affords three cyclic triazinane-based energetic compounds featuring the FOX-7 backbone, which enriches the exciting reactive chemistry of FOX-7.

Theoretical studies on the derivatives of tris([1,2,4]triazolo)[4,3-a:4′,3′-c:4′′,3′′-e][1,3,5]triazine as high energetic compounds

RSC Advances ◽  
2016 ◽  
Vol 6 (7) ◽  
pp. 5419-5427 ◽  
Author(s):  
Qun Zeng ◽  
Yanyang Qu ◽  
Jinshan Li ◽  
Hui Huang
Keyword(s):  
Energetic Materials ◽  
Theoretical Studies ◽  
Energetic Compounds ◽  
Derivatives Of ◽  
New Framework

Tris([1,2,4]triazolo)[4,3-a:4′,3′-c:4′′,3′′-e][1,3,5]triazine inherited from triazole and triazine is suggested theoretically as a new framework for insensitive and high-energetic materials.

Extensive theoretical studies on two new members of the FOX-7 family: 5-(dinitromethylene)-1,4-dinitramino-tetrazole and 1,1′-dinitro-4,4′-diamino-5,5′-bitetrazole as energetic compounds

2015 ◽  
Vol 17 (8) ◽  
pp. 5840-5848 ◽  
Author(s):  
Piao He ◽  
Jian-Guo Zhang ◽  
Kun Wang ◽  
Xin Yin ◽  
Xin Jin ◽  
...  
Keyword(s):  
Energetic Materials ◽  
Theoretical Studies ◽  
Energetic Compounds ◽  
New Members

A combination of the tetrazole with an insensitive fragment of FOX-7 makes two novel compounds DNAT and DNABT very promising energetic materials.

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