Exploring the reactive chemistry of FOX-7: synthesis of cyclic triazinane-based energetic materials featuring the FOX-7 backbone

2019 ◽  
Vol 43 (26) ◽  
pp. 10429-10433 ◽  
Author(s):  
Chao Yan ◽  
Guangbin Cheng ◽  
Kangcai Wang ◽  
Tianlin Liu ◽  
Yunhe Jin ◽  
...  
Keyword(s):  
Energetic Materials ◽  
Energetic Compounds ◽  
Derivatization Reaction

Unexpected derivatization reaction of FOX-7 affords three cyclic triazinane-based energetic compounds featuring the FOX-7 backbone, which enriches the exciting reactive chemistry of FOX-7.

Azasydnone – novel “green” building block for designing high energetic compounds

2018 ◽  
Vol 6 (38) ◽  
pp. 18669-18676 ◽  
Author(s):  
Igor L. Dalinger ◽  
Olga V. Serushkina ◽  
Nikita V. Muravyev ◽  
Dmitry B. Meerov ◽  
Evgeniy A. Miroshnichenko ◽  
...  
Keyword(s):  
Building Block ◽  
Energetic Materials ◽  
Green Building ◽  
Future Generations ◽  
Energetic Compounds

The azasydnone unit is a promising explosophoric block for future generations of highly thermostable and dense energetic materials.

Tetrazolyl and dinitromethyl groups with 1,2,3-triazole lead to polyazole energetic materials

2019 ◽  
Vol 48 (10) ◽  
pp. 3237-3242 ◽  
Author(s):  
Yingle Liu ◽  
Chunlin He ◽  
Yongxing Tang ◽  
Gregory H. Imler ◽  
Damon A. Parrish ◽  
...  
Keyword(s):  
Energetic Materials ◽  
Energetic Compounds

A class of polyazole energetic compounds (combination of tetrazolyl, dinitromethyl and triazole) was obtained from 4,5-dicyanotriazole.

Theoretical studies on the derivatives of tris([1,2,4]triazolo)[4,3-a:4′,3′-c:4′′,3′′-e][1,3,5]triazine as high energetic compounds

RSC Advances ◽  
2016 ◽  
Vol 6 (7) ◽  
pp. 5419-5427 ◽  
Author(s):  
Qun Zeng ◽  
Yanyang Qu ◽  
Jinshan Li ◽  
Hui Huang
Keyword(s):  
Energetic Materials ◽  
Theoretical Studies ◽  
Energetic Compounds ◽  
Derivatives Of ◽  
New Framework

Tris([1,2,4]triazolo)[4,3-a:4′,3′-c:4′′,3′′-e][1,3,5]triazine inherited from triazole and triazine is suggested theoretically as a new framework for insensitive and high-energetic materials.

Extensive theoretical studies on two new members of the FOX-7 family: 5-(dinitromethylene)-1,4-dinitramino-tetrazole and 1,1′-dinitro-4,4′-diamino-5,5′-bitetrazole as energetic compounds

2015 ◽  
Vol 17 (8) ◽  
pp. 5840-5848 ◽  
Author(s):  
Piao He ◽  
Jian-Guo Zhang ◽  
Kun Wang ◽  
Xin Yin ◽  
Xin Jin ◽  
...  
Keyword(s):  
Energetic Materials ◽  
Theoretical Studies ◽  
Energetic Compounds ◽  
New Members

A combination of the tetrazole with an insensitive fragment of FOX-7 makes two novel compounds DNAT and DNABT very promising energetic materials.

scholarly journals Recent Advances in Synthesis and Properties of Nitrated-Pyrazoles Based Energetic Compounds

Molecules ◽  
2020 ◽  
Vol 25 (15) ◽  
pp. 3475 ◽  
Author(s):  
Shijie Zhang ◽  
Zhenguo Gao ◽  
Di Lan ◽  
Qian Jia ◽  
Ning Liu ◽  
...  
Keyword(s):  
Energetic Materials ◽  
High Performance ◽  
High Efficiency ◽  
Low Cost ◽  
Rapid Development ◽  
Development Trend ◽  
High Heat ◽  
High Energy ◽  
Heat Of Formation ◽  
Energetic Compounds

Nitrated-pyrazole-based energetic compounds have attracted wide publicity in the field of energetic materials (EMs) due to their high heat of formation, high density, tailored thermal stability, and detonation performance. Many nitrated-pyrazole-based energetic compounds have been developed to meet the increasing demands of high power, low sensitivity, and eco-friendly environment, and they have good applications in explosives, propellants, and pyrotechnics. Continuous and growing efforts have been committed to promote the rapid development of nitrated-pyrazole-based EMs in the last decade, especially through large amounts of Chinese research. Some of the ultimate aims of nitrated-pyrazole-based materials are to develop potential candidates of castable explosives, explore novel insensitive high energy materials, search for low cost synthesis strategies, high efficiency, and green environmental protection, and further widen the applications of EMs. This review article aims to present the recent processes in the synthesis and physical and explosive performances of the nitrated-pyrazole-based Ems, including monopyrazoles with nitro, bispyrazoles with nitro, nitropyrazolo[4,3-c]pyrazoles, and their derivatives, and to comb the development trend of these compounds. This review intends to prompt fresh concepts for designing prominent high-performance nitropyrazole-based EMs.

Carbonyl-bridged energetic materials: biomimetic synthesis, organic catalytic synthesis, and energetic performances

2016 ◽  
Vol 45 (43) ◽  
pp. 17117-17122 ◽  
Author(s):  
Yong-an Feng ◽  
Hao Qiu ◽  
Sa-sha Yang ◽  
Jiang Du ◽  
Tong-lai Zhang
Keyword(s):  
Energetic Materials ◽  
Catalytic Synthesis ◽  
Biomimetic Synthesis ◽  
Carbonyl Groups ◽  
Energetic Compounds ◽  
Bridging Groups ◽  
Organic Catalyst

Carbonyl groups (CO) have been newly introduced as sole bridging groups in the field of energetic materials. Moreover, the biomimetic synthesis and energetic organic catalyst were used to synthesize new energetic compounds.

Silver(i)-based energetic coordination polymers: synthesis, structure and energy performance

2015 ◽  
Vol 39 (10) ◽  
pp. 7849-7857 ◽  
Author(s):  
Xiaoni Qu ◽  
Sheng Zhang ◽  
Qi Yang ◽  
Zhiyong Su ◽  
Qing Wei ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Energetic Materials ◽  
Substituent Effect ◽  
Energy Performance ◽  
Energetic Compounds

Two energetic compounds were reported to illustrate the substituent effect of nitrogen-rich heterocycles on the energy performance of energetic materials.

Asymmetric nitrogen-rich energetic materials resulting from the combination of tetrazolyl, dinitromethyl and (1,2,4-oxadiazol-5-yl)nitroamino groups with furoxan

2018 ◽  
Vol 47 (46) ◽  
pp. 16558-16566 ◽  
Author(s):  
Yingle Liu ◽  
Chunlin He ◽  
Yongxing Tang ◽  
Gregory H. Imler ◽  
Damon A. Parrish ◽  
...  
Keyword(s):  
Energetic Materials ◽  
Energetic Compounds ◽  
Asymmetric Nitrogen

Three classes of nitrogen-rich energetic compounds were obtained from 3,4-dicyano-furoxan.

scholarly journals Preparation, Characterization and Application of Nano-Graphene-Based Energetic Materials

Nanomaterials ◽  
2021 ◽  
Vol 11 (9) ◽  
pp. 2374
Author(s):  
Xiaolong Fu ◽  
Yonghu Zhu ◽  
Jizhen Li ◽  
Liping Jiang ◽  
Xitong Zhao ◽  
...  
Keyword(s):  
Thermal Decomposition ◽  
Future Development ◽  
Energetic Materials ◽  
Energetic Compounds ◽  
Combustion Behavior ◽  
Existing Problems ◽  
Combustion Catalyst ◽  
New Type ◽  
Nano Graphene

Nano-graphene-based energetic materials, as a new type of composite energetic materials such as desensitizer and combustion catalyst, have attracted extensive attention from energetic researchers. In this paper, the preparation of nano-graphene-based energetic materials, the desensitization effect of nano-graphene-based on energetic compounds, the thermal decomposition and combustion behavior of the materials are reviewed. Meanwhile, the existing problems and future development of nano-graphene-based energetic compounds are discussed.

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