New nitrogen-rich heterocyclic compounds to build 3D energetic metal complexes

CrystEngComm ◽  
2020 ◽  
Vol 22 (27) ◽  
pp. 4573-4579
Author(s):  
Xiaoming Yang ◽  
Yanna Wang ◽  
Weijing Zhang ◽  
Yanli Yin ◽  
Zhimin Li ◽  
...  
Keyword(s):  
Metal Complexes ◽  
Energetic Materials ◽  
Heterocyclic Compounds ◽  
Three Dimensional ◽  
Potassium Salts ◽  
Heat Resistant ◽  
Sodium And Potassium

By introducing hydroxymethyl into nitrogen-rich heterocyclic compounds, we designed and synthesized a new ligand. The three dimensional (3D) energetic metal complexes sodium and potassium salts of new ligand were investigated for heat-resistant energetic materials.

Hydrated metal complexes of N-(6-amino-3,4-dihydro-3-methyl-5-nitroso-4-oxopyrimidin-2-yl)glycinate: interplay of molecular, molecular–electronic and supramolecular structures

2001 ◽  
Vol 57 (3) ◽  
pp. 317-328 ◽  
Author(s):  
John N. Low ◽  
Jose M. Moreno Sánchez ◽  
Paloma Arranz Mascarós ◽  
M. Luz Godino Salido ◽  
Rafael López Garzon ◽  
...  
Keyword(s):  
Metal Complexes ◽  
Three Dimensional ◽  
Organic Ligands ◽  
Water Molecules ◽  
Molecular Aggregates ◽  
Nitroso Group ◽  
Interatomic Distances ◽  
Vertex Sharing ◽  
Sodium And Potassium ◽  
Continuous Chain

The title anion, (C7H8N5O4)−, L −, forms hydrated metal complexes with a range of metal ions M + and M 2+. Lithium and manganese(II) form finite molecular aggregates [Li(L)(H2O)3] (1) and [Mn(L)2(H2O)4].6H2O (4) in which the molecular aggregates are linked into three-dimensional frameworks by extensive hydrogen bonding. The sodium and potassium derivatives, [Na2(L)2(H2O)3] (2) and [K(L)(H2O)] (3) both form organic–inorganic hybrid sheets in which metal–oxygen ribbons are linked by strips containing only organic ligands: these sheets are linked by hydrogen bonds into three-dimensional frameworks. In (2) the metal–oxygen ribbon is built from pairs of edge-shared trigonal bipyramids linked by water molecules, while in (3) it consists of a continuous chain of vertex-sharing octahedra. The nitroso group in the anion acts as an η1 ligand towards Na+ and as an η2 ligand towards K+. In all cases the anion L − shows the same unusual pattern of interatomic distances as the neutral parent LH.

Sodium and Potassium 3,5-Dinitro-4-hydropyrazolate: Three-Dimensional Metal–Organic Frameworks as Promising Super-heat-resistant Explosives

2019 ◽  
Vol 2 (10) ◽  
pp. 7628-7634 ◽  
Author(s):  
Jichuan Zhang ◽  
Jiaheng Zhang ◽  
Gregory H. Imler ◽  
Damon A. Parrish ◽  
Jean’ne M. Shreeve
Keyword(s):  
Metal Organic Frameworks ◽  
Three Dimensional ◽  
Heat Resistant ◽  
Metal Organic ◽  
Sodium And Potassium

Contributions to the chemistry of anionic water-soluble tetraarylporphyrins and their metal complexes

2004 ◽  
Vol 08 (01) ◽  
pp. 43-66 ◽  
Author(s):  
Johann W. Buchler
Keyword(s):  
Crystal Structure ◽  
Coordination Chemistry ◽  
Metal Complexes ◽  
Potassium Salt ◽  
Water Soluble ◽  
Potassium Salts ◽  
Sodium Potassium ◽  
Structure Determinations ◽  
Complex Salts ◽  
Sodium And Potassium

Recent contributions to the coordination chemistry of tetraanionic water-soluble tetraarylporphyrins, namely 5,10,15,20-tetrakis(4-carboxyphenyl)porphyrin, [1]4−, 5,10,15,20-tetrakis(4-sulfonatophenyl)porphyrin, [2]4−, and 5,10,15,20-tetrakis(4-hydroxidophosphorylmethylphenyl)porphyrin, [ H 43]4−, are reported. Problems with the isolation of sodium and potassium salts of [2]4− are discussed. The tetraphosphonoporphyrin H 8[3] is precipitated as a dihydrochloride H 8[3]·2 HCl , its metal complexes H 8[3-M] as such. The synthesis of salts containing Ce and Os complexes of [1]4−, Al , Ga , In , Ge , Sn , As , Sb , Mn , Mo , W , Re , Os , and Pt complexes of [2]4−, and Ni , Cu , Zn , Pt and Os complexes of [ H 43]4− as documented in publications and doctoral theses from the Darmstadt laboratory are reviewed. Some properties of the new complex salts are reported. The results of crystal structure determinations of the potassium salt of tetrakis(4-sulfonatophenyl)porphyrinatoplatinate(II), K 8[2-Pt]2·10 DMSO ·6 H 2O· C 7 H 8, and the mixed sodium-potassium salt of tetrakis(4-sulfonatophenyl)porphyrinatoaluminate, K 2 Na [ Al ( DMSO )2( tpps 4)]·8( DMSO )·2 H 2 O , are shown.

Synthesis of Sulfoquinovose and Sulfoquinovosyl Diacylglycerides, and a Fluorogenic Substrate for Sulfoquinovosidases

2019 ◽  
Author(s):  
Yunyang Zhang ◽  
Janice Mui ◽  
Thimali Arumaperuma ◽  
James P. Lingford ◽  
ETHAN GODDARD-BORGER ◽  
...  
Keyword(s):  
Crystal Structures ◽  
Fluorogenic Substrate ◽  
Potassium Salts ◽  
X Ray ◽  
Sulfoquinovosyl Diacylglycerol ◽  
Sodium And Potassium

<p>The sulfolipid sulfoquinovosyl diacylglycerol (SQDG) and its headgroup, the sulfosugar sulfoquinovose (SQ), are estimated to harbour up to half of all organosulfur in the biosphere. SQ is liberated from SQDG and related glycosides by the action of sulfoquinovosidases (SQases). We report a 10-step synthesis of SQDG that we apply to the preparation of saturated and unsaturated lipoforms. We also report an expeditious synthesis of SQ and (<sup>13</sup>C<sub>6</sub>)SQ, and X-ray crystal structures of sodium and potassium salts of SQ. Finally, we report the synthesis of a fluorogenic SQase substrate, methylumbelliferyl a-D-sulfoquinovoside, and examination of its cleavage kinetics by two recombinant SQases.</p>

Heats of Solution of Some Sodium and Potassium Salts in Water and in Water-Methanol Mixtures

1992 ◽  
Vol 57 (11) ◽  
pp. 2227-2234 ◽  
Author(s):  
Ján Benko ◽  
Oľga Vollárová
Keyword(s):  
Transfer Functions ◽  
Enthalpies Of Solution ◽  
Potassium Salts ◽  
Solvent Interactions ◽  
Heats Of Solution ◽  
Solvent Molecules ◽  
Sodium And Potassium

The enthalpies of solution ∆Hs0 were determined for NaSCN, KSCN, NaBrO3, KBrO3, NaClO3, KClO3, NaIO4, KMnO4, KNO2 and NaNO2 in water-methanol mixtures. The transfer functions ∆Ht0 of the salts and anions were calculated based on the extrathermodynamic TPTB assumption. The ∆Ht0 values of the anion obtained from the sodium and potassium salts were compared. The differences observed, particularly at higher concentrations of the cosolvent, are discussed with respect to the interactions between the solvent molecules and the solute-solvent interactions.

scholarly journals Comparative thermal research on tetraazapentalene-derived heat-resistant energetic structures

2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Jing Zhou ◽  
Li Ding ◽  
Yong Zhu ◽  
Bozhou Wang ◽  
Xiangzhi Li ◽  
...  
Keyword(s):  
Differential Scanning Calorimetry ◽  
Thermal Decomposition ◽  
Fourier Transform ◽  
Energetic Materials ◽  
Great Influence ◽  
Fourier Transform Infrared ◽  
Thermal Decomposition Mechanism ◽  
Scanning Calorimetry ◽  
In Situ Ftir Spectroscopy ◽  
Heat Resistant

AbstractOrganic inner salt structures are ideal backbones for heat-resistant energetic materials and systematic studies towards the thermal properties of energetic organic inner salt structures are crucial to their applications. Herein, we report a comparative thermal research of two energetic organic inner salts with different tetraazapentalene backbones. Detailed thermal decomposition behaviors and kinetics were investigated through differential scanning calorimetry and thermogravimetric analysis (DSC-TG) methods, showing that the thermal stability of the inner salts is higher than most of the traditional heat-resistant energetic materials. Further studies towards the thermal decomposition mechanism were carried out through condensed-phase thermolysis/Fourier-transform infrared (in-situ FTIR) spectroscopy and the combination of differential scanning calorimetry-thermogravimetry-mass spectrometry-Fourier-transform infrared spectroscopy (DSC-TG-MS-FTIR) techniques. The experiment and calculation results prove that the arrangement of the inner salt backbones has great influence on the thermal decompositions of the corresponding energetic materials. The weak N4-N5 bond in “y-” pattern tetraazapentalene backbone lead to early decomposition process and the “z-” pattern tetraazapentalene backbone exhibits more concentrated decomposition behaviors.

ChemInform Abstract: CHEMISTRY OF HETEROCYCLIC COMPOUNDS. 18. TRANSITION METAL COMPLEXES OF SELECTED 2-PYRIDYLACETYLENES

1976 ◽  
Vol 7 (11) ◽  
pp. no-no
Author(s):  
G. R. NEWKOME ◽  
G. L. MCCLURE ◽  
S. F. WATKINS ◽  
B. GAYLE ◽  
R. E. TAYLOR ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Heterocyclic Compounds

Self-assembly of sodium and potassium betulinates into hydro- and organo-gels: entrapment and removal studies of fluorophores and synthesis of gel–gold nanoparticle hybrid materials

RSC Advances ◽  
2016 ◽  
Vol 6 (21) ◽  
pp. 17290-17296 ◽  
Author(s):  
Braja Gopal Bag ◽  
Shib Shankar Dash
Keyword(s):  
Gold Nanoparticle ◽  
Hybrid Materials ◽  
Betulinic Acid ◽  
Self Assembly ◽  
Solvent Mixtures ◽  
Potassium Salts ◽  
Aqueous Solvent Mixtures ◽  
Aqueous Solvent ◽  
Removal Studies ◽  
Sodium And Potassium

Sodium and potassium salts of a renewable nano-sized triterpenoid betulinic acid have been prepared and their self-assembly properties in water and aqueous solvent mixtures have been studied.

Sign in / Sign up

Export Citation Format

Share Document