Fluorescent Molecular Glass Based on Hexadehydrotribenzo[12]annulene

2021 ◽  
Author(s):  
Yotaro Kasahara ◽  
Ichiro Hisaki ◽  
Tomoyuki Akutagawa ◽  
Takashi Takeda

We prepared octylbenzoate-substituted [12]DBA (C8[12]DBA) as an organic molecular glass material. Even with a central large, planar π unit of [12]DBA, which is generally advantageous for the formation of a...

2012 ◽  
Vol 22 (40) ◽  
pp. 21502 ◽  
Author(s):  
Shanfeng Xue ◽  
Liang Yao ◽  
Suijun Liu ◽  
Cheng Gu ◽  
Fangzhong Shen ◽  
...  

1997 ◽  
Vol 7 (11) ◽  
pp. 1635-1650 ◽  
Author(s):  
A. Faivre ◽  
L. David ◽  
J. Perez

2017 ◽  
Vol 24 (1) ◽  
pp. 73-79
Author(s):  
Md. Moinul Islam ◽  
Mohammad Tariqul Islam ◽  
Mohammad Rashed Iqbal Faruque ◽  
Rabah W. Aldhaheri ◽  
Md. Samsuzzaman

AbstractA compact ultra-wideband (UWB) antenna is presented in this paper with a partial ground plane on epoxy woven glass material. The study is discussed to comprehend the effects of various design parameters with explicit parametric analyses. The overall antenna dimension is 0.22×0.26×0.016 λ. A prototype is made on epoxide woven glass fabric dielectric material of 1.6 mm thickness. The measured results point out that the reported antenna belongs to a wide bandwidth comprehending from 3 GHz to more than 11 GHz with VSWR<2. It has a peak gain of 5.52 dBi, where 3.98 dBi is the average gain. Nearly omnidirectional radiation patterns are observed within the operating frequency bands. A good term exists between simulation and measurement results, which lead the reported antenna to be an appropriate candidate for UWB applications.


Langmuir ◽  
2017 ◽  
Vol 33 (40) ◽  
pp. 10645-10654 ◽  
Author(s):  
Chungen Hsu ◽  
Yi Du ◽  
Xiaogong Wang
Keyword(s):  

2012 ◽  
Vol 22 (1) ◽  
pp. 123-129 ◽  
Author(s):  
Illhun Cho ◽  
Se Hun Kim ◽  
Jong H. Kim ◽  
Sanghyuk Park ◽  
Soo Young Park

2006 ◽  
Vol 52 (4) ◽  
pp. 540-544 ◽  
Author(s):  
Ryoji Nakazawa ◽  
Hisashi Tomemori ◽  
Atsuko Hirano ◽  
Hidetoshi Mochizuki ◽  
Ping An ◽  
...  

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Michela Romanini ◽  
Roberto Macovez ◽  
Maria Barrio ◽  
Josep Lluís Tamarit

AbstractWe employ temperature- and pressure-dependent dielectric spectroscopy, as well as differential scanning calorimetry, to characterize benzophenone and the singly-substituted ortho-bromobenzophenone derivative in the liquid and glass states, and analyze the results in terms of the molecular conformations reported for these molecules. Despite the significantly higher mass of the brominated derivative, its dynamic and calorimetric glass transition temperatures are only ten degrees higher than those of benzophenone. The kinetic fragility index of the halogenated molecule is lower than that of the parent compound, and is found to decrease with increasing pressure. By a detailed analysis of the dielectric loss spectra, we provide evidence for the existence of a Johari–Goldstein (JG) relaxation in both compounds, thus settling the controversy concerning the possible lack of a JG process in benzophenone and confirming the universality of this dielectric loss feature in molecular glass-formers. Both compounds also display an intramolecular relaxation, whose characteristic timescale appears to be correlated with that of the cooperative structural relaxation associated with the glass transition. The limited molecular flexibility of ortho-bromobenzophenone allows identifying the intramolecular relaxation as the inter-enantiomeric conversion between two isoenergetic conformers of opposite chirality, which only differ in the sign of the angle between the brominated aryl ring and the coplanar phenyl-ketone subunit. The observation by dielectric spectroscopy of a similar relaxation also in liquid benzophenone indicates that the inter-enantiomer conversion between the two isoenergetic helicoidal ground-state conformers of opposite chirality occurs via a transition state characterized by a coplanar phenyl-ketone moiety.


Author(s):  
F. E. Vilkov ◽  
A. A. Lozovan ◽  
A. V. Bazhanov ◽  
A. N. Kasitsyn ◽  
O. E. Schekoturova ◽  
...  

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