Integration of metalloporphyrin into cationic covalent triazine frameworks for the synergistically enhanced chemical fixation of CO2

2020 ◽  
Vol 10 (23) ◽  
pp. 8026-8033
Author(s):  
Qiu-Jin Wu ◽  
Min-Jie Mao ◽  
Jian-Xin Chen ◽  
Yuan-Biao Huang ◽  
Rong Cao

Cobalt porphyrin as a Lewis acidic site was integrated into imidazolium-functionalized porous cationic covalent triazine frameworks for the cooperatively enhanced catalysis CO2 cycloaddition to produce cyclic carbonates.

Materials ◽  
2017 ◽  
Vol 10 (7) ◽  
pp. 759 ◽  
Author(s):  
Sara García-Argüelles ◽  
Maria Ferrer ◽  
Marta Iglesias ◽  
Francisco Del Monte ◽  
María Gutiérrez

2018 ◽  
Vol 6 (4) ◽  
pp. 5322-5332 ◽  
Author(s):  
Felipe de la Cruz-Martínez ◽  
Javier Martínez ◽  
Miguel A. Gaona ◽  
Juan Fernández-Baeza ◽  
Luis F. Sánchez-Barba ◽  
...  

APL Materials ◽  
2019 ◽  
Vol 7 (11) ◽  
pp. 111102 ◽  
Author(s):  
Mousumi Garai ◽  
Vepa Rozyyev ◽  
Zakir Ullah ◽  
Aqil Jamal ◽  
Cafer T. Yavuz

2020 ◽  
Vol 56 (73) ◽  
pp. 10678-10681
Author(s):  
Suguru Motokucho ◽  
Hiroshi Morikawa

We have developed a synthetic methodology using poly(hydroxyurethane) as an organocatalyst for the chemical fixation of CO2 into epoxides, leading to the formation of five-membered cyclic carbonates with remarkably high selectivity and yields.


2020 ◽  
Vol 49 (29) ◽  
pp. 9935-9947 ◽  
Author(s):  
Feng Guo ◽  
Xiuling Zhang

MOFs are promising heterogeneous catalysts for chemical fixation of CO2 and epoxides into cyclic carbonates.


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