Co‐Catalyst‐Free Chemical Fixation of CO 2 into Cyclic Carbonates by using Metal‐Organic Frameworks as Efficient Heterogeneous Catalysts

2020 ◽  
Vol 15 (16) ◽  
pp. 2403-2427 ◽  
Author(s):  
Sandeep Singh Dhankhar ◽  
Bharat Ugale ◽  
C. M. Nagaraja
Keyword(s):  
Heterogeneous Catalysts ◽  
Metal Organic Frameworks ◽  
Chemical Fixation ◽  
Cyclic Carbonates ◽  
Co Catalyst ◽  
Catalyst Free ◽  
Metal Organic

Metal–organic frameworks for the energy-related conversion of CO2 into cyclic carbonates

2020 ◽  
Vol 49 (29) ◽  
pp. 9935-9947 ◽  
Author(s):  
Feng Guo ◽  
Xiuling Zhang
Keyword(s):  
Heterogeneous Catalysts ◽  
Metal Organic Frameworks ◽  
Chemical Fixation ◽  
Cyclic Carbonates ◽  
Metal Organic

MOFs are promising heterogeneous catalysts for chemical fixation of CO2 and epoxides into cyclic carbonates.

An imidazolium-functionalized mesoporous cationic metal–organic framework for cooperative CO2 fixation into cyclic carbonate

2018 ◽  
Vol 54 (4) ◽  
pp. 342-345 ◽  
Author(s):  
Jun Liang ◽  
Ya-Qiang Xie ◽  
Xu-Sheng Wang ◽  
Qiang Wang ◽  
Tao-Tao Liu ◽  
...  
Keyword(s):  
Co2 Fixation ◽  
Metal Organic Framework ◽  
Cyclic Carbonate ◽  
Chemical Fixation ◽  
Cyclic Carbonates ◽  
Co Catalyst ◽  
Mild Conditions ◽  
Catalyst Free ◽  
Metal Organic ◽  
Organic Framework

A mesoporous cationic Cr-based metal–organic framework (MOF), FJI-C10, has been obtained and exhibited excellent performances in chemical fixation of CO2 into cyclic carbonates under co-catalyst free and mild conditions.

In-situ cleavage and rearrangement synthesis of an easy-obtained and high stable Cu(II)-based MOF for efficient heterogeneous catalysis of carbon dioxide conversion

CrystEngComm ◽  
2021 ◽  
Author(s):  
Lan Qin ◽  
Yu Pan ◽  
Lei Yu ◽  
Ranran Huai ◽  
Lu Yang ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Heterogeneous Catalysis ◽  
Metal Organic Frameworks ◽  
Chemical Fixation ◽  
Cyclic Carbonates ◽  
Carbon Dioxide Conversion ◽  
Metal Organic ◽  
Carbon Dioxide Co2

Cycloaddition into cyclic carbonates has been attracted substantial attentions for metal-organic frameworks based catalysis of carbon dioxide (CO2) chemical fixation, not only due to the contributions that solving the environmental...

Adenine-Based Zn(II)/Cd(II) Metal–Organic Frameworks as Efficient Heterogeneous Catalysts for Facile CO2Fixation into Cyclic Carbonates: A DFT-Supported Study of the Reaction Mechanism

2019 ◽  
Vol 58 (17) ◽  
pp. 11389-11403 ◽  
Author(s):  
Yadagiri Rachuri ◽  
Jintu Francis Kurisingal ◽  
Ramesh Kumar Chitumalla ◽  
Srimai Vuppala ◽  
Yunjang Gu ◽  
...  
Keyword(s):  
Reaction Mechanism ◽  
Heterogeneous Catalysts ◽  
Metal Organic Frameworks ◽  
Cyclic Carbonates ◽  
Metal Organic

Environment-friendly, co-catalyst- and solvent-free fixation of CO2 using an ionic zinc(ii)–porphyrin complex immobilized in porous metal–organic frameworks

2019 ◽  
Vol 3 (11) ◽  
pp. 2977-2982 ◽  
Author(s):  
Nayuesh Sharma ◽  
Sandeep Singh Dhankhar ◽  
C. M. Nagaraja
Keyword(s):  
Heterogeneous Catalyst ◽  
Metal Organic Frameworks ◽  
Porous Metal ◽  
Solvent Free ◽  
Environment Friendly ◽  
Co Catalyst ◽  
Porphyrin Complex ◽  
Catalyst Free ◽  
Metal Organic

Development of a heterogeneous catalyst composed of a [Zn(ii)NMeTPyP]4+[I−]4 complex immobilized in PCN-224 for environment-friendly, co-catalyst-free fixation of CO2 is reported.

An Overview of Metal-organic Frameworks-based Acid/Base Catalysts for Biofuel Synthesis

2020 ◽  
Vol 24 (16) ◽  
pp. 1876-1891
Author(s):  
Qiuyun Zhang ◽  
Yutao Zhang ◽  
Jingsong Cheng ◽  
Hu Li ◽  
Peihua Ma
Keyword(s):  
Alternative Fuels ◽  
Heterogeneous Catalysts ◽  
Supported Catalysts ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Flexible Structures ◽  
Biodiesel Production ◽  
Biodiesel Synthesis ◽  
Metal Organic ◽  
Organic Framework

Biofuel synthesis is of great significance for producing alternative fuels. Among the developed catalytic materials, the metal-organic framework-based hybrids used as acidic, basic, or supported catalysts play major roles in the biodiesel production. This paper presents a timely and comprehensive review of recent developments on the design and preparation of metal-organic frameworks-based catalysts used for biodiesel synthesis from various oil feedstocks, including MILs-based catalysts, ZIFs-based catalysts, UiO-based catalysts, Cu-BTC-based catalysts, and MOFs-derived porous catalysts. Due to their unique and flexible structures, excellent thermal and hydrothermal stability, and tunable host-guest interactions, as compared with other heterogeneous catalysts, metal-organic framework-based catalysts have good opportunities for application in the production of biodiesel at industrial scale.

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