Selective 5-Hydroxymethylfurfural Hydrogenolysis to 2,5-Dimethylfuran over Bimetallic Pt-FeOx/AC Catalysts

The selective hydrogenolysis of 5-hydroxymethylfurfural (HMF) platform molecule to 2,5-dimethylfuran (DMF) has attracted increasing attention due to its broad range of applications. However, HMF, with multiple functional groups, produces various byproducts, hindering its use on an industrial scale. Herein, a bimetallic Pt-FeOx/AC catalyst with low Pt and FeOx loadings for selective HMF hydrogenolysis to DMF was prepared by incipient wetness impregnation. The structures and properties of different catalysts were characterized by XRD, XPS, TEM, ICP-OES and Py-FTIR techniques. The addition of FeOx enhanced Pt dispersion and the Lewis acidic site density of the catalysts, and was found to be able to inhibit C=C hydrogenation, thereby im-proving DMF yield. Moreover, the presence of Pt promoted the reduction of iron oxide, creating a strong interaction between Pt and FeOx. This synergistic effect originated from the activation of the C–O bond over FeOx species followed by hydrogenolysis over the adjacent Pt, and played a critical role in hydrogenolysis of HMF to DMF, achieving a yield of 91% under optimal reaction conditions. However, the leaching of Fe species caused a metal–acid imbalance, which led to an increase in ring hydrogenation products.

Hydrogenation of pentenal over supported Pt nanoparticles: influence of Lewis-acid sites in the conversion pathway

The superb TOF and high selectivity of Pt/CeAl are associated with the surface properties (e.g. medium Lewis acidic site). The unsaturated Ce4+/Al3+ cations pairs act as the acid sites and electron acceptors to polarize the CO bonds.

Integration of metalloporphyrin into cationic covalent triazine frameworks for the synergistically enhanced chemical fixation of CO2

Cobalt porphyrin as a Lewis acidic site was integrated into imidazolium-functionalized porous cationic covalent triazine frameworks for the cooperatively enhanced catalysis CO2 cycloaddition to produce cyclic carbonates.

CS2activation at uranium(iii) siloxide ate complexes: the effect of a Lewis acidic site

Multimetallic cooperativity plays an important role in U(iii) mediated CS2reduction: the reductive dimerization of CS2occurs preferentially at a heterodimetallic U, K complex while the reductive disproportionation pathway is favoured by the “ate” complex [K(18c6)][U(OSi(OtBu)3)4].