Propagation rate coefficient for acrylic acid polymerization in bulk and in propionic acid by the PLP–SEC method: experiment and 3D simulation

2019 ◽  
Vol 10 (43) ◽  
pp. 5870-5878 ◽  
Author(s):  
Eva Dušička ◽  
Anatoly N. Nikitin ◽  
Igor Lacík
Keyword(s):  
Acrylic Acid ◽  
Propionic Acid ◽  
Rate Coefficient ◽  
Laser Pulses ◽  
Propagation Rate ◽  
3D Simulation ◽  
Propagation Rate Coefficient

The kp values for acrylic acid polymerization in bulk and in propionic acid are found to depend on the number of laser pulses used in PLP experiment and decrease from bulk value upon dilution with propionic acid.

scholarly journals Re-evaluation of Propagation Rate Coefficient of Free-Radical Polymerization of N-Vinylcarbazole by the Rotating-Sector Technique

2004 ◽  
Vol 36 (12) ◽  
pp. 953-958
Author(s):  
Masataka Ohoka ◽  
Sadahito Misumi ◽  
Hideo Ohkita ◽  
Shinzaburo Ito ◽  
Masahide Yamamoto
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Rate Coefficient ◽  
Free Radical Polymerization ◽  
Propagation Rate ◽  
Propagation Rate Coefficient

Investigating the propagation kinetics of a novel class of nitrogen-containing methacrylates via PLP-SEC

2016 ◽  
Vol 7 (26) ◽  
pp. 4342-4351 ◽  
Author(s):  
Katrin B. Kockler ◽  
Friederike Fleischhaker ◽  
Christopher Barner-Kowollik
Keyword(s):  
Size Exclusion Chromatography ◽  
Rate Coefficient ◽  
Pulsed Laser ◽  
Propagation Rate ◽  
Size Exclusion ◽  
Arrhenius Parameters ◽  
Exclusion Chromatography ◽  
Kinetics Of ◽  
Propagation Rate Coefficient ◽  
Pulsed Laser Polymerization

The Mark–Houwink–Kuhn–Sakurada parameters as well as Arrhenius parameters of the propagation rate coefficient for a new group of nitrogen-containing methacrylates were determined via triple detector SEC and pulsed laser polymerization–size exclusion chromatography, respectively.

Pulsed-Laser Polymerization Measurements of the Propagation Rate Coefficient for Butyl Acrylate

1996 ◽  
Vol 29 (6) ◽  
pp. 1918-1927 ◽  
Author(s):  
Robert A. Lyons ◽  
Jelica Hutovic ◽  
Mark C. Piton ◽  
David I. Christie ◽  
Paul A. Clay ◽  
...  
Keyword(s):  
Butyl Acrylate ◽  
Rate Coefficient ◽  
Pulsed Laser ◽  
Propagation Rate ◽  
Propagation Rate Coefficient ◽  
Pulsed Laser Polymerization

E.s.r. measurements of the propagation rate coefficient for styrene free radical polymerisation

Polymer ◽  
1998 ◽  
Vol 39 (11) ◽  
pp. 2305-2313 ◽  
Author(s):  
Matthew P. Tonge ◽  
Atsushi Kajiwara ◽  
Mikiharu Kamachi ◽  
Robert G. Gilbert
Keyword(s):  
Free Radical ◽  
Rate Coefficient ◽  
Propagation Rate ◽  
Radical Polymerisation ◽  
Propagation Rate Coefficient

Solvent effects on the propagation rate coefficient for free radical polymerization

1993 ◽  
Vol 26 (16) ◽  
pp. 4368-4372 ◽  
Author(s):  
Bradley R. Morrison ◽  
Mark C. Piton ◽  
Mitchell A. Winnik ◽  
Robert G. Gilbert ◽  
Donald H. Napper
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Solvent Effects ◽  
Rate Coefficient ◽  
Free Radical Polymerization ◽  
Propagation Rate ◽  
Propagation Rate Coefficient
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