Propagation Rate Coefficient and Fraction of Mid-Chain Radicals for Acrylic Acid Polymerization in Aqueous Solution

2007 ◽  
Vol 28 (21) ◽  
pp. 2049-2054 ◽  
Author(s):  
Michael Buback ◽  
Pascal Hesse ◽  
Igor Lacík
Keyword(s):  
Aqueous Solution ◽  
Acrylic Acid ◽  
Rate Coefficient ◽  
Propagation Rate ◽  
Propagation Rate Coefficient

Propagation Rate Coefficient for Radical Polymerization ofN-Vinyl Pyrrolidone in Aqueous Solution Obtained by PLP−SEC

2008 ◽  
Vol 41 (14) ◽  
pp. 5174-5185 ◽  
Author(s):  
Marek Stach ◽  
Igor Lacík ◽  
Dušan Chorvát ◽  
Michael Buback ◽  
Pascal Hesse ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Radical Polymerization ◽  
Rate Coefficient ◽  
Propagation Rate ◽  
Vinyl Pyrrolidone ◽  
Propagation Rate Coefficient

Propagation Rate Coefficient of Free-Radical Polymerization of Partially and Fully Ionized Methacrylic Acid in Aqueous Solution

2009 ◽  
Vol 42 (20) ◽  
pp. 7753-7761 ◽  
Author(s):  
Igor Lacík ◽  
Lucia Učňová ◽  
Silvia Kukučková ◽  
Michael Buback ◽  
Pascal Hesse ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Free Radical ◽  
Radical Polymerization ◽  
Methacrylic Acid ◽  
Rate Coefficient ◽  
Free Radical Polymerization ◽  
Propagation Rate ◽  
Propagation Rate Coefficient

Propagation rate coefficient for acrylic acid polymerization in bulk and in propionic acid by the PLP–SEC method: experiment and 3D simulation

2019 ◽  
Vol 10 (43) ◽  
pp. 5870-5878 ◽  
Author(s):  
Eva Dušička ◽  
Anatoly N. Nikitin ◽  
Igor Lacík
Keyword(s):  
Acrylic Acid ◽  
Propionic Acid ◽  
Rate Coefficient ◽  
Laser Pulses ◽  
Propagation Rate ◽  
3D Simulation ◽  
Propagation Rate Coefficient

The kp values for acrylic acid polymerization in bulk and in propionic acid are found to depend on the number of laser pulses used in PLP experiment and decrease from bulk value upon dilution with propionic acid.

PLP-SEC Studies into the Propagation Rate Coefficient of Acrylamide Radical Polymerization in Aqueous Solution

2016 ◽  
Vol 49 (9) ◽  
pp. 3244-3253 ◽  
Author(s):  
Igor Lacík ◽  
Anna Chovancová ◽  
Lucia Uhelská ◽  
Calista Preusser ◽  
Robin A. Hutchinson ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Radical Polymerization ◽  
Rate Coefficient ◽  
Propagation Rate ◽  
Propagation Rate Coefficient
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