From n-butyl acrylate Arrhenius parameters for backbiting and tertiary propagation to β-scission via stepwise pulsed laser polymerization

A stepwise method to estimate the Arrhenius parameters for backbiting, tertiary propagation, and β-scission in acrylate radical polymerization.

Ab initio based kinetic Monte Carlo analysis to unravel the propagation kinetics in vinyl acetate pulsed laser polymerization

The radical propagation kinetics of vinyl acetate in pulsed laser polymerization (PLP) is studied by combining ab initio calculated rate coefficients with kinetic Monte Carlo modeling of PLP spectra.

Pulsed laser polymerisation studies of methyl methacrylate in the presence of AlCl3 and ZnCl2 – evidence of propagation catalysis

Pulsed laser polymerization experiments demonstrate that Lewis acids electrostatically catalyse the propagation step in radical polymerization of methyl methacrylate.

Investigating the propagation kinetics of a novel class of nitrogen-containing methacrylates via PLP-SEC

The Mark–Houwink–Kuhn–Sakurada parameters as well as Arrhenius parameters of the propagation rate coefficient for a new group of nitrogen-containing methacrylates were determined via triple detector SEC and pulsed laser polymerization–size exclusion chromatography, respectively.