Pulsed-laser polymerization-gel permeation chromatographic determination of the propagation-rate coefficient for the methyl acrylate dimer: A sterically hindered monomer

2001 ◽  
Vol 39 (22) ◽  
pp. 3902-3915 ◽  
Author(s):  
Kenta Tanaka ◽  
Bunichiro Yamada ◽  
Christopher M. Fellows ◽  
Robert G. Gilbert ◽  
Thomas P. Davis ◽  
...  
Keyword(s):  
Methyl Acrylate ◽  
Rate Coefficient ◽  
Pulsed Laser ◽  
Chromatographic Determination ◽  
Propagation Rate ◽  
Gel Permeation ◽  
Sterically Hindered ◽  
Propagation Rate Coefficient ◽  
Pulsed Laser Polymerization

Investigating the propagation kinetics of a novel class of nitrogen-containing methacrylates via PLP-SEC

2016 ◽  
Vol 7 (26) ◽  
pp. 4342-4351 ◽  
Author(s):  
Katrin B. Kockler ◽  
Friederike Fleischhaker ◽  
Christopher Barner-Kowollik
Keyword(s):  
Size Exclusion Chromatography ◽  
Rate Coefficient ◽  
Pulsed Laser ◽  
Propagation Rate ◽  
Size Exclusion ◽  
Arrhenius Parameters ◽  
Exclusion Chromatography ◽  
Kinetics Of ◽  
Propagation Rate Coefficient ◽  
Pulsed Laser Polymerization

The Mark–Houwink–Kuhn–Sakurada parameters as well as Arrhenius parameters of the propagation rate coefficient for a new group of nitrogen-containing methacrylates were determined via triple detector SEC and pulsed laser polymerization–size exclusion chromatography, respectively.

Pulsed-Laser Polymerization Measurements of the Propagation Rate Coefficient for Butyl Acrylate

1996 ◽  
Vol 29 (6) ◽  
pp. 1918-1927 ◽  
Author(s):  
Robert A. Lyons ◽  
Jelica Hutovic ◽  
Mark C. Piton ◽  
David I. Christie ◽  
Paul A. Clay ◽  
...  
Keyword(s):  
Butyl Acrylate ◽  
Rate Coefficient ◽  
Pulsed Laser ◽  
Propagation Rate ◽  
Propagation Rate Coefficient ◽  
Pulsed Laser Polymerization

Propagation Rate Coefficient of Vinylneo-Decanoate by Pulsed Laser Polymerization

1997 ◽  
Vol 30 (13) ◽  
pp. 3775-3780 ◽  
Author(s):  
Robert Balic ◽  
Robert G. Gilbert ◽  
Michael D. Zammit ◽  
Thomas P. Davis ◽  
Christopher M. Miller
Keyword(s):  
Rate Coefficient ◽  
Pulsed Laser ◽  
Propagation Rate ◽  
Propagation Rate Coefficient ◽  
Pulsed Laser Polymerization

Determination of vinyl acetate propagation rate coefficients via high frequency pulsed laser polymerization

e-Polymers ◽  
2009 ◽  
Vol 9 (1) ◽  
Author(s):  
Thomas Junkers ◽  
Dominik Voll ◽  
Christopher Barner-Kowollik
Keyword(s):  
Vinyl Acetate ◽  
Pulsed Laser ◽  
Propagation Rate ◽  
Size Exclusion ◽  
Rate Coefficients ◽  
Exclusion Chromatography ◽  
Propagation Rate Coefficient ◽  
Good Agreement ◽  
Pulsed Laser Polymerization

AbstractNew data on the propagation rate coefficient, kp, of vinyl acetate (VAc) are obtained via the IUPAC recommended method of pulsed laser polymerization - size exclusion chromatography (PLP-SEC) operated at 500 Hz laser repetition rate. An apparent dependency of the experiment’s outcome on the laser pulsing rate is identified with kp being about 25 % larger at 500 Hz compared to 100 Hz. The temperature dependence of kp was determined to fit ln kp = 17.12 - 2621 K/T; data is in generally good agreement with literature values when the previous underestimation of kp by 100 Hz laser pulsing experiments is taken into account.

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