The influence of mixing on chain extension by photo-controlled/living radical polymerization under continuous-flow conditions

2019 ◽  
Vol 10 (35) ◽  
pp. 4879-4886 ◽  
Author(s):  
Fuyao Zhong ◽  
Yang Zhou ◽  
Mao Chen
Keyword(s):  
Radical Polymerization ◽  
Continuous Flow ◽  
Flow Chemistry ◽  
Polymer Synthesis ◽  
Living Radical Polymerization ◽  
Chain Extension ◽  
Flow Conditions ◽  
Continuous Flow Chemistry ◽  
Controlled Living Radical Polymerization

Continuous-flow chemistry holds powerful potential for polymer synthesis, and has attracted increasing attention in recent years.

Recent Applications of Continuous Flow in Homogeneous Palladium Catalysis

Synthesis ◽  
2020 ◽  
Vol 52 (23) ◽  
pp. 3511-3529 ◽  
Author(s):  
Peter Koóš ◽  
Martin Markovič ◽  
Pavol Lopatka ◽  
Tibor Gracza
Keyword(s):  
Organic Synthesis ◽  
Continuous Flow ◽  
Palladium Catalysis ◽  
Flow Chemistry ◽  
Cross Coupling ◽  
Coupling Reactions ◽  
Flow Conditions ◽  
Cross Coupling Reactions ◽  
Continuous Flow Chemistry ◽  
Oxidative Transformations

Considerable advances have been made using continuous flow chemistry as an enabling tool in organic synthesis. Consequently, the number of articles reporting continuous flow methods has increased significantly in recent years. This review covers the progress achieved in homogeneous palladium catalysis using continuous flow conditions over the last five years, including C–C/C–N cross-coupling reactions, carbonylations and reductive/oxidative transformations.1 Introduction2 C–C Cross-Coupling Reactions3 C–N Coupling Reactions4 Carbonylation Reactions5 Miscellaneous Reactions6 Key to Schematic Symbols7 Conclusion

Synthesis of ketones via organolithium addition to acid chlorides using continuous flow chemistry

RSC Advances ◽  
2015 ◽  
Vol 5 (97) ◽  
pp. 79385-79390 ◽  
Author(s):  
Soo-Yeon Moon ◽  
Seo-Hee Jung ◽  
U. Bin Kim ◽  
Won-Suk Kim
Keyword(s):  
Efficient Method ◽  
Continuous Flow ◽  
Flow Chemistry ◽  
Acid Chlorides ◽  
Flow Conditions ◽  
Continuous Flow Chemistry

An efficient method for the synthesis of ketones using organolithium and acid chlorides under continuous flow conditions has been developed.

Improving photo-controlled living radical polymerization from trithiocarbonates through the use of continuous-flow techniques

2015 ◽  
Vol 51 (31) ◽  
pp. 6742-6745 ◽  
Author(s):  
Mao Chen ◽  
Jeremiah A. Johnson
Keyword(s):  
Radical Polymerization ◽  
Continuous Flow ◽  
Flow Reactor ◽  
Reaction Rates ◽  
Living Radical Polymerization ◽  
Controlled Living Radical Polymerization ◽  
Simple Flow ◽  
Flow Techniques

Herein, we report simple flow reactor designs that enable photo-controlled living radical polymerization (photo-CRP) from trithiocarbonates (TTCs) with significant enhancements in scalability and reaction rates compared to the analogous batch reactions.

A metal-free synthesis of 1,1-diphenylvinylsulfides with thiols via thioetherification under continuous-flow conditions

2020 ◽  
Vol 7 (12) ◽  
pp. 1490-1494 ◽  
Author(s):  
Jiawei Zhang ◽  
Erfei Wang ◽  
Yang Zhou ◽  
Lu Zhang ◽  
Mao Chen ◽  
...  
Keyword(s):  
Continuous Flow ◽  
Flow Chemistry ◽  
Flow Conditions ◽  
Aggregation Induced Emission ◽  
Metal Free ◽  
Mild Conditions ◽  
Continuous Flow Chemistry ◽  
Efficient Access

A continuous-flow chemistry facilitated protocol that allows efficient access to a novel aggregation-induced emission (AIE) luminogen 1,1-diphenylvinylsulfides utilizing thiols under metal-free and mild conditions.

scholarly journals Application of Reactor Engineering Concepts in Continuous Flow Chemistry: A Review

2021 ◽  
Author(s):  
Nicole Candice Neyt ◽  
Darren Lyall Riley
Keyword(s):  
Rapid Growth ◽  
Continuous Flow ◽  
Flow Chemistry ◽  
The Past ◽  
Continuous Flow Chemistry

The adoption of flow technology for the manufacture of chemical entities, and in particular pharmaceuticals, has seen rapid growth over the past two decades with the technology now blurring the...

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