Precision Polymer Synthesis by Degenerative Transfer Controlled/Living Radical Polymerization Using Organotellurium, Organostibine, and Organobismuthine Chain-Transfer Agents

2009 ◽  
Vol 109 (11) ◽  
pp. 5051-5068 ◽  
Author(s):  
Shigeru Yamago
Keyword(s):  
Radical Polymerization ◽  
Chain Transfer ◽  
Polymer Synthesis ◽  
Living Radical Polymerization ◽  
Controlled Living Radical Polymerization ◽  
Transfer Agents

Living Radical Polymerization with Reversible Addition−Fragmentation Chain Transfer (RAFT Polymerization) Using Dithiocarbamates as Chain Transfer Agents

1999 ◽  
Vol 32 (21) ◽  
pp. 6977-6980 ◽  
Author(s):  
Roshan T. A. Mayadunne ◽  
Ezio Rizzardo ◽  
John Chiefari ◽  
Yen Kwong Chong ◽  
Graeme Moad ◽  
...  
Keyword(s):  
Radical Polymerization ◽  
Chain Transfer ◽  
Raft Polymerization ◽  
Living Radical Polymerization ◽  
Reversible Addition ◽  
Transfer Agents

Controlled/Living Radical Polymerization of Semifluorinated (Meth)acrylates

Synlett ◽  
2018 ◽  
Vol 29 (12) ◽  
pp. 1543-1551 ◽  
Author(s):  
Mao Chen ◽  
Honghong Gong ◽  
Yu Gu
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Chain Transfer ◽  
Raft Polymerization ◽  
Living Radical Polymerization ◽  
Atom Transfer ◽  
Reversible Addition ◽  
Controlled Living Radical Polymerization ◽  
Chain Transfer Polymerization ◽  
Semifluorinated Polymers

Fluorinated polymers are important materials for applications in many areas. This article summarizes the development of controlled/living radical polymerization (CRP) of semifluorinated (meth)acrylates, and briefly introduces their reaction mechanisms. While the classical CRP such as atom transfer radical polymerization (ATRP), reversible addition-fragmentation chain transfer (RAFT) polymerization and nitroxide-mediated radical polymerization (NMP) have promoted the preparation of semifluorinated polymers with tailor-designed architectures, recent development of photo-CRP has led to unprecedented accuracy and monomer scope. We expect that synthetic advances will facilitate the engineering of advanced fluorinated materials with unique properties.1 Introduction2 Atom Transfer Radical Polymerization3 Reversible Addition-Fragmentation Chain Transfer Polymerization4 Nitroxide-Mediated Radical Polymerization5 Photo-CRP Mediated with Metal Complexes6 Metal-free Photo-CRP7 Conclusion

The influence of mixing on chain extension by photo-controlled/living radical polymerization under continuous-flow conditions

2019 ◽  
Vol 10 (35) ◽  
pp. 4879-4886 ◽  
Author(s):  
Fuyao Zhong ◽  
Yang Zhou ◽  
Mao Chen
Keyword(s):  
Radical Polymerization ◽  
Continuous Flow ◽  
Flow Chemistry ◽  
Polymer Synthesis ◽  
Living Radical Polymerization ◽  
Chain Extension ◽  
Flow Conditions ◽  
Continuous Flow Chemistry ◽  
Controlled Living Radical Polymerization

Continuous-flow chemistry holds powerful potential for polymer synthesis, and has attracted increasing attention in recent years.

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