Improving photo-controlled living radical polymerization from trithiocarbonates through the use of continuous-flow techniques

2015 ◽  
Vol 51 (31) ◽  
pp. 6742-6745 ◽  
Author(s):  
Mao Chen ◽  
Jeremiah A. Johnson
Keyword(s):  
Radical Polymerization ◽  
Continuous Flow ◽  
Flow Reactor ◽  
Reaction Rates ◽  
Living Radical Polymerization ◽  
Controlled Living Radical Polymerization ◽  
Simple Flow ◽  
Flow Techniques

Herein, we report simple flow reactor designs that enable photo-controlled living radical polymerization (photo-CRP) from trithiocarbonates (TTCs) with significant enhancements in scalability and reaction rates compared to the analogous batch reactions.

The influence of mixing on chain extension by photo-controlled/living radical polymerization under continuous-flow conditions

2019 ◽  
Vol 10 (35) ◽  
pp. 4879-4886 ◽  
Author(s):  
Fuyao Zhong ◽  
Yang Zhou ◽  
Mao Chen
Keyword(s):  
Radical Polymerization ◽  
Continuous Flow ◽  
Flow Chemistry ◽  
Polymer Synthesis ◽  
Living Radical Polymerization ◽  
Chain Extension ◽  
Flow Conditions ◽  
Continuous Flow Chemistry ◽  
Controlled Living Radical Polymerization

Continuous-flow chemistry holds powerful potential for polymer synthesis, and has attracted increasing attention in recent years.

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