Microrespirometric assessment of the metal–organic framework [Co2(btec)(bipy)(DMF)2]n (“MOF-Co”) to prevent inhibition by arsenic in activated sludge

2020 ◽  
Vol 6 (4) ◽  
pp. 1153-1162
Author(s):  
Alberto Ordaz ◽  
Eva Gil ◽  
Gabriel R. Hernández-Martínez ◽  
Frédéric Thalasso ◽  
Susana Rincón ◽  
...  
Keyword(s):  
Activated Sludge ◽  
Metal Organic Framework ◽  
Biological Processes ◽  
Metal Organic ◽  
First Time ◽  
Organic Framework

This study, for the first time, presents the application of a microrespirometric method to evaluate the effect of MOF-Co and As(iii) on biological processes.

Solvent-Free Powder Synthesis and MOF-CVD Thin Films of the Mesoporous Metal-Organic Framework MAF-6

2019 ◽  
Author(s):  
Timothée Stassin ◽  
Ivo Stassen ◽  
Joao Marreiros ◽  
Alexander John Cruz ◽  
Rhea Verbeke ◽  
...  
Keyword(s):  
Vapor Phase ◽  
Metal Organic Framework ◽  
Chemical Vapor ◽  
Uptake Capacity ◽  
Powder Synthesis ◽  
Crystalline Films ◽  
Metal Organic ◽  
Mesoporous Metal ◽  
First Time ◽  
Organic Framework

A simple solvent- and catalyst-free method is presented for the synthesis of the mesoporous metal-organic framework (MOF) MAF-6 (RHO-Zn(eIm)2) based on the reaction of ZnO with 2-ethylimidazole vapor at temperatures ≤ 100 °C. By translating this method to a chemical vapor deposition (CVD) protocol, mesoporous crystalline films could be deposited for the first time entirely from the vapor phase. A combination of PALS and Kr physisorption measurements confirmed the porosity of these MOF-CVD films and the size of the MAF-6 supercages (diam. ~2 nm), in close agreement with powder data and calculations. MAF-6 powders and films were further characterized by XRD, TGA, SEM, FTIR, PDF and EXAFS. The exceptional uptake capacity of the mesoporous MAF-6 in comparison to the microporous ZIF-8 is demonstrated by vapor-phase loading of a molecule larger than the ZIF-8 windows.

Metal–organic frameworks: a universal strategy towards super-elastic hydrogels

2019 ◽  
Vol 10 (18) ◽  
pp. 2263-2272 ◽  
Author(s):  
Huaizhi Liu ◽  
Hao Peng ◽  
Yumeng Xin ◽  
Jiuyang Zhang
Keyword(s):  
Drug Delivery ◽  
Mechanical Performance ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
High Loading ◽  
Loading Capacity ◽  
Metal Organic ◽  
First Time ◽  
Organic Framework

We reported for the first time using metal–organic framework (MOF) nanoparticles as effective nanofillers to significantly enhance the mechanical performance of hydrogels. The MOF hydrogels have been developed for drug delivery materials with high loading capacity and much extended drug releasing profiles.

Nanoarchitectured metal–organic framework/polypyrrole hybrids for brackish water desalination using capacitive deionization

2019 ◽  
Vol 6 (7) ◽  
pp. 1433-1437 ◽  
Author(s):  
Ziming Wang ◽  
Xingtao Xu ◽  
Jeonghun Kim ◽  
Victor Malgras ◽  
Ran Mo ◽  
...  
Keyword(s):  
Brackish Water ◽  
Metal Organic Framework ◽  
Water Desalination ◽  
Capacitive Deionization ◽  
Metal Organic ◽  
First Time ◽  
Organic Framework

Metal–organic framework/polypyrrole hybrids are synthesized and directly used in capacitive deionization for the first time.

scholarly journals Direct evidence of charge separation in a metal–organic framework: efficient and selective photocatalytic oxidative coupling of amines via charge and energy transfer

2018 ◽  
Vol 9 (12) ◽  
pp. 3152-3158 ◽  
Author(s):  
Caiyun Xu ◽  
Hang Liu ◽  
Dandan Li ◽  
Ji-Hu Su ◽  
Hai-Long Jiang
Keyword(s):  
Energy Transfer ◽  
Charge Separation ◽  
Oxidative Coupling ◽  
Direct Evidence ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
First Time ◽  
Organic Framework

For the first time, the photoexcited charge separation in a metal–organic framework has been evidenced with clear ESR signals, based on efficient and selective photocatalytic oxidative coupling of amines.

scholarly journals Waste PET as a Reactant for Lanthanide MOF Synthesis and Application in Sensing of Picric Acid

Polymers ◽  
2019 ◽  
Vol 11 (12) ◽  
pp. 2015 ◽  
Author(s):  
Feng Zhang ◽  
Shuyi Chen ◽  
Shengqiang Nie ◽  
Jun Luo ◽  
Shaomin Lin ◽  
...  
Keyword(s):  
Terephthalic Acid ◽  
Limit Of Detection ◽  
Picric Acid ◽  
Metal Organic Framework ◽  
Pet Bottles ◽  
Metal Organic ◽  
Lanthanide Metal ◽  
Ft Ir ◽  
First Time ◽  
Organic Framework

In this study, a lanthanide metal organic framework based on the ligand of terephthalic acid derived from waste polyethylene terephthalate (PET) bottles was designed and synthesized. The structure and morphology of the Tb-BDC was investigated by X-ray diffractometry (XRD), Fourier transform infrared spectroscopy (FT-IR), and scanning electron microscopy (SEM). The Tb-BDC displays a high selectivity and sensitivity towards picric acid (TNP). The luminescence intensities exhibit a linear relation, with a concentration of TNP over the range of 1 × 10−5–1 × 10−4 M, with a limit of detection of 1 × 10−5 M. The sensing mechanism is also discussed. This is the first time that waste PET materials have been used as the starting precursor of terephthalic acid (BDC) for the fabrication of lanthanide MOF (metal organic framework), which is applied in sensing TNP.

A highly permeable zinc-based MOF/polyphenylsulfone composite membrane with elevated antifouling properties

2020 ◽  
Vol 56 (39) ◽  
pp. 5231-5234
Author(s):  
Arun Kumar Shukla ◽  
Javed Alam ◽  
Fekri Abdulraqeb Ahmed Ali ◽  
Mansour Alhoshan
Keyword(s):  
Composite Membrane ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
First Time ◽  
Organic Framework

In this study, for the first time, a highly permeable composite membrane was constructed by incorporating a zinc-based metal–organic framework (Zn-MOF) in a polyphenylsulfone matrix for the elevation of antifouling properties.

Ground to conduct: mechanochemical synthesis of a metal–organic framework with high proton conductivity

2015 ◽  
Vol 51 (36) ◽  
pp. 7637-7640 ◽  
Author(s):  
Dariusz Matoga ◽  
Marcin Oszajca ◽  
Marcin Molenda
Keyword(s):  
Proton Conductivity ◽  
Mechanochemical Synthesis ◽  
Metal Organic Framework ◽  
Environmentally Friendly ◽  
High Proton Conductivity ◽  
Proton Conducting ◽  
High Proton ◽  
Metal Organic ◽  
First Time ◽  
Organic Framework

A high proton-conducting metal–organic framework (PCMOF) is prepared for the first time by economical and environmentally-friendly mechanochemistry.

Exceptional high selectivity of hydrogen/methane separation on a phosphonate-based MOF membrane with exclusion of methane molecules

2017 ◽  
Vol 53 (70) ◽  
pp. 9797-9800 ◽  
Author(s):  
Qipeng Yang ◽  
Liangjun Li ◽  
Weiqiang Tan ◽  
Yingjie Sun ◽  
Huanli Wang ◽  
...  
Keyword(s):  
High Selectivity ◽  
Metal Organic Framework ◽  
Anodic Alumina ◽  
Porous Anodic Alumina ◽  
Anodic Alumina Membrane ◽  
Alumina Membrane ◽  
Metal Organic ◽  
First Time ◽  
Organic Framework

A phosphonate-based metal–organic framework membrane was constructed on a porous anodic alumina membrane (PAAM) substrate for H2/CH4 separation for the first time.

A Novel, Interpenetrating Metal–Organic Framework: Synthesis, Structure, and Luminescence Detection of Nitrobenzene

2017 ◽  
Vol 70 (7) ◽  
pp. 792 ◽  
Author(s):  
Peng-Fei Shi ◽  
Li-Xian Wang ◽  
Zhao-Peng Yu
Keyword(s):  
Metal Organic Framework ◽  
X Ray Diffraction ◽  
X Ray ◽  
Solvent Stability ◽  
Qualitative Detection ◽  
Highly Sensitive ◽  
Metal Organic ◽  
First Time ◽  
Ppm Level ◽  
Organic Framework

A 3D heterometal–organic framework {[TbZn(BPDC)2(HCOO)(H2O)3]·2H2O}n (1) was constructed from Tb3+ and Zn2+ as metal ions and 4,4′-dicarboxylate-2,2′-dipyridine (H2BPDC) as the ligand using a solvothermal method. Single-crystal X-ray diffraction analysis revealed that compound 1 is 2-fold interpenetrating. Thermogravimetric and solvent stability analyses demonstrated that compound 1 displayed good thermal and solvent stabilities. The luminescent explorations revealed that compound 1 exhibited highly sensitive and qualitative detection of nitrobenzene at the ppm level. To our knowledge, the present study reports for the first time the use of an interpenetrating heterometallic metal–organic framework as a luminescent probe for nitrobenzene.

Enhancing the colorimetric detection of H2O2 and ascorbic acid on polypyrrole coated fluconazole-functionalized POMOFs

The Analyst ◽  
2019 ◽  
Vol 144 (10) ◽  
pp. 3347-3356 ◽  
Author(s):  
Xiao Li ◽  
Longjiang Sun ◽  
Xiya Yang ◽  
Kunfeng Zhou ◽  
Gongguo Zhang ◽  
...  
Keyword(s):  
Ascorbic Acid ◽  
Metal Organic Framework ◽  
Colorimetric Detection ◽  
Metal Organic ◽  
First Time ◽  
Colorimetric Biosensing ◽  
Organic Framework

For the first time, a bifunctional colorimetric biosensing platform has been developed, based on a polypyrrole coated fluconazole-functionalized polyoxometalate-based metal–organic framework with ultrahigh stability for the enhanced detection of H2O2 and ascorbic acid.

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