Ground to conduct: mechanochemical synthesis of a metal–organic framework with high proton conductivity

2015 ◽  
Vol 51 (36) ◽  
pp. 7637-7640 ◽  
Author(s):  
Dariusz Matoga ◽  
Marcin Oszajca ◽  
Marcin Molenda
Keyword(s):  
Proton Conductivity ◽  
Mechanochemical Synthesis ◽  
Metal Organic Framework ◽  
Environmentally Friendly ◽  
High Proton Conductivity ◽  
Proton Conducting ◽  
High Proton ◽  
Metal Organic ◽  
First Time ◽  
Organic Framework

A high proton-conducting metal–organic framework (PCMOF) is prepared for the first time by economical and environmentally-friendly mechanochemistry.

High Proton Conductivity and Spectroscopic Investigations of Metal–Organic Framework Materials Impregnated by Strong Acids

2014 ◽  
Vol 6 (7) ◽  
pp. 5161-5167 ◽  
Author(s):  
Danil N. Dybtsev ◽  
Valentina G. Ponomareva ◽  
Sokhrab B. Aliev ◽  
Alexei P. Chupakhin ◽  
Marsel R. Gallyamov ◽  
...  
Keyword(s):  
Proton Conductivity ◽  
Metal Organic Framework ◽  
High Proton Conductivity ◽  
Framework Materials ◽  
Spectroscopic Investigations ◽  
High Proton ◽  
Metal Organic ◽  
Strong Acids ◽  
Organic Framework

Selective CO2 Capture and High Proton Conductivity of a Functional Star-of-David Catenane Metal-Organic Framework

2017 ◽  
Vol 29 (42) ◽  
pp. 1703301 ◽  
Author(s):  
You-Gui Huang ◽  
Shu-Qi Wu ◽  
Wei-Hua Deng ◽  
Gang Xu ◽  
Fa-Lu Hu ◽  
...  
Keyword(s):  
Proton Conductivity ◽  
Co2 Capture ◽  
Metal Organic Framework ◽  
High Proton Conductivity ◽  
High Proton ◽  
Metal Organic ◽  
Organic Framework

Proton Conductivity, Stability and Potential for Polymorphism in Metal-Organic Framework Minerals

2018 ◽  
Author(s):  
Igor Huskić ◽  
Novendra Novendra ◽  
Dae-Woo Lim ◽  
Filip Topic ◽  
Hatem M. Titi ◽  
...  
Keyword(s):  
Proton Conductivity ◽  
Metal Organic Framework ◽  
Rare Metal ◽  
Framework Structure ◽  
High Proton Conductivity ◽  
High Proton ◽  
High Thermodynamic Stability ◽  
Metal Organic ◽  
Complex Organic ◽  
Organic Framework

We demonstrate that rare metal-organic framework (MOF) minerals stepanovite and zhemchuzhnikovite can exhibit properties comparable to known oxalate MOFs, including high proton conductivity at 25 <sup>o</sup>C, and retention of the framework structure upon thermal dehydration. They also have high thermodynamic stability, with a pronounced stabilizing effect of substituting aluminium for iron, illustrating a simple design to access stable, highly proton-conductive MOFs without using complex organic ligands. <br>

Proton Conductivity, Stability and Potential for Polymorphism in Metal-Organic Framework Minerals

2018 ◽  
Author(s):  
Igor Huskić ◽  
Novendra Novendra ◽  
Dae-Woo Lim ◽  
Filip Topic ◽  
Hatem M. Titi ◽  
...  
Keyword(s):  
Proton Conductivity ◽  
Metal Organic Framework ◽  
Rare Metal ◽  
Framework Structure ◽  
High Proton Conductivity ◽  
High Proton ◽  
High Thermodynamic Stability ◽  
Metal Organic ◽  
Complex Organic ◽  
Organic Framework

We demonstrate that rare metal-organic framework (MOF) minerals stepanovite and zhemchuzhnikovite can exhibit properties comparable to known oxalate MOFs, including high proton conductivity at 25 <sup>o</sup>C, and retention of the framework structure upon thermal dehydration. They also have high thermodynamic stability, with a pronounced stabilizing effect of substituting aluminium for iron, illustrating a simple design to access stable, highly proton-conductive MOFs without using complex organic ligands. <br>

High proton conduction in an excellent water-stable gadolinium metal–organic framework

2019 ◽  
Vol 55 (9) ◽  
pp. 1241-1244 ◽  
Author(s):  
Xiu-Shuang Xing ◽  
Zhi-Hua Fu ◽  
Ning-Ning Zhang ◽  
Xiao-Qing Yu ◽  
Ming-Sheng Wang ◽  
...  
Keyword(s):  
Proton Conductivity ◽  
Metal Organic Framework ◽  
Proton Conduction ◽  
Proton Conducting ◽  
High Proton ◽  
Metal Organic ◽  
Organic Framework

Proton conductivity of a new gadolinium(iii) metal–organic framework, is among the highest values for proton-conducting MOFs.

Multifunctional luminescent Zn(ii)-based metal–organic framework for high proton-conductivity and detection of Cr3+ ions in the presence of mixed metal ions

2018 ◽  
Vol 47 (5) ◽  
pp. 1383-1387 ◽  
Author(s):  
Xing Meng ◽  
Mei-Jie Wei ◽  
Hai-Ning Wang ◽  
Hong-Ying Zang ◽  
Zi-Yan Zhou
Keyword(s):  
Metal Ions ◽  
Proton Conductivity ◽  
Metal Organic Framework ◽  
High Proton Conductivity ◽  
Sensing Properties ◽  
Mixed Metal ◽  
High Proton ◽  
Rectangular Channels ◽  
Metal Organic ◽  
Organic Framework

A luminescent MOF with rectangular channels shows high proton conductivity up to 0.95 × 10−2 S cm−1 and selective Cr3+ sensing properties in presence of mixed metal ions.

A stable porphyrinic metal–organic framework pore-functionalized by high-density carboxylic groups for proton conduction

2017 ◽  
Vol 5 (28) ◽  
pp. 14525-14529 ◽  
Author(s):  
Hao Wu ◽  
Fan Yang ◽  
Xiu-Liang Lv ◽  
Bin Wang ◽  
Yong-Zheng Zhang ◽  
...  
Keyword(s):  
Proton Conductivity ◽  
Metal Organic Framework ◽  
Proton Conduction ◽  
High Density ◽  
Carboxylic Group ◽  
High Proton Conductivity ◽  
High Proton ◽  
Carboxylic Groups ◽  
Metal Organic ◽  
Organic Framework

A highly stable porphyrinic MOF with free-carboxylic group functionalized pore surfaces exhibits a high proton conductivity of 3.9 × 10−2 S cm−1 at 80 °C and 97% RH, which is comparable to most of the reported proton conductive MOFs.

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