Nanoarchitectured metal–organic framework/polypyrrole hybrids for brackish water desalination using capacitive deionization

2019 ◽  
Vol 6 (7) ◽  
pp. 1433-1437 ◽  
Author(s):  
Ziming Wang ◽  
Xingtao Xu ◽  
Jeonghun Kim ◽  
Victor Malgras ◽  
Ran Mo ◽  
...  
Keyword(s):  
Brackish Water ◽  
Metal Organic Framework ◽  
Water Desalination ◽  
Capacitive Deionization ◽  
Metal Organic ◽  
First Time ◽  
Organic Framework

Metal–organic framework/polypyrrole hybrids are synthesized and directly used in capacitive deionization for the first time.

Solvent-Free Powder Synthesis and MOF-CVD Thin Films of the Mesoporous Metal-Organic Framework MAF-6

2019 ◽  
Author(s):  
Timothée Stassin ◽  
Ivo Stassen ◽  
Joao Marreiros ◽  
Alexander John Cruz ◽  
Rhea Verbeke ◽  
...  
Keyword(s):  
Vapor Phase ◽  
Metal Organic Framework ◽  
Chemical Vapor ◽  
Uptake Capacity ◽  
Powder Synthesis ◽  
Crystalline Films ◽  
Metal Organic ◽  
Mesoporous Metal ◽  
First Time ◽  
Organic Framework

A simple solvent- and catalyst-free method is presented for the synthesis of the mesoporous metal-organic framework (MOF) MAF-6 (RHO-Zn(eIm)2) based on the reaction of ZnO with 2-ethylimidazole vapor at temperatures ≤ 100 °C. By translating this method to a chemical vapor deposition (CVD) protocol, mesoporous crystalline films could be deposited for the first time entirely from the vapor phase. A combination of PALS and Kr physisorption measurements confirmed the porosity of these MOF-CVD films and the size of the MAF-6 supercages (diam. ~2 nm), in close agreement with powder data and calculations. MAF-6 powders and films were further characterized by XRD, TGA, SEM, FTIR, PDF and EXAFS. The exceptional uptake capacity of the mesoporous MAF-6 in comparison to the microporous ZIF-8 is demonstrated by vapor-phase loading of a molecule larger than the ZIF-8 windows.

Metal–organic frameworks: a universal strategy towards super-elastic hydrogels

2019 ◽  
Vol 10 (18) ◽  
pp. 2263-2272 ◽  
Author(s):  
Huaizhi Liu ◽  
Hao Peng ◽  
Yumeng Xin ◽  
Jiuyang Zhang
Keyword(s):  
Drug Delivery ◽  
Mechanical Performance ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
High Loading ◽  
Loading Capacity ◽  
Metal Organic ◽  
First Time ◽  
Organic Framework

We reported for the first time using metal–organic framework (MOF) nanoparticles as effective nanofillers to significantly enhance the mechanical performance of hydrogels. The MOF hydrogels have been developed for drug delivery materials with high loading capacity and much extended drug releasing profiles.

A sunlight-responsive metal–organic framework system for sustainable water desalination

2020 ◽  
Vol 3 (12) ◽  
pp. 1052-1058 ◽  
Author(s):  
Ranwen Ou ◽  
Huacheng Zhang ◽  
Vinh X. Truong ◽  
Lian Zhang ◽  
Hanaa M. Hegab ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Water Desalination ◽  
Metal Organic ◽  
Framework System ◽  
Organic Framework

scholarly journals Direct evidence of charge separation in a metal–organic framework: efficient and selective photocatalytic oxidative coupling of amines via charge and energy transfer

2018 ◽  
Vol 9 (12) ◽  
pp. 3152-3158 ◽  
Author(s):  
Caiyun Xu ◽  
Hang Liu ◽  
Dandan Li ◽  
Ji-Hu Su ◽  
Hai-Long Jiang
Keyword(s):  
Energy Transfer ◽  
Charge Separation ◽  
Oxidative Coupling ◽  
Direct Evidence ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
First Time ◽  
Organic Framework

For the first time, the photoexcited charge separation in a metal–organic framework has been evidenced with clear ESR signals, based on efficient and selective photocatalytic oxidative coupling of amines.

scholarly journals Waste PET as a Reactant for Lanthanide MOF Synthesis and Application in Sensing of Picric Acid

Polymers ◽  
2019 ◽  
Vol 11 (12) ◽  
pp. 2015 ◽  
Author(s):  
Feng Zhang ◽  
Shuyi Chen ◽  
Shengqiang Nie ◽  
Jun Luo ◽  
Shaomin Lin ◽  
...  
Keyword(s):  
Terephthalic Acid ◽  
Limit Of Detection ◽  
Picric Acid ◽  
Metal Organic Framework ◽  
Pet Bottles ◽  
Metal Organic ◽  
Lanthanide Metal ◽  
Ft Ir ◽  
First Time ◽  
Organic Framework

In this study, a lanthanide metal organic framework based on the ligand of terephthalic acid derived from waste polyethylene terephthalate (PET) bottles was designed and synthesized. The structure and morphology of the Tb-BDC was investigated by X-ray diffractometry (XRD), Fourier transform infrared spectroscopy (FT-IR), and scanning electron microscopy (SEM). The Tb-BDC displays a high selectivity and sensitivity towards picric acid (TNP). The luminescence intensities exhibit a linear relation, with a concentration of TNP over the range of 1 × 10−5–1 × 10−4 M, with a limit of detection of 1 × 10−5 M. The sensing mechanism is also discussed. This is the first time that waste PET materials have been used as the starting precursor of terephthalic acid (BDC) for the fabrication of lanthanide MOF (metal organic framework), which is applied in sensing TNP.

Metal–organic-frameworks-derived NaTi2(PO4)3/carbon composites for efficient hybrid capacitive deionization

2019 ◽  
Vol 7 (19) ◽  
pp. 12126-12133 ◽  
Author(s):  
Kai Wang ◽  
Yong Liu ◽  
Zibiao Ding ◽  
Yuquan Li ◽  
Ting Lu ◽  
...  
Keyword(s):  
Electrical Conductivity ◽  
Porous Structure ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Carbon Composites ◽  
Capacitive Deionization ◽  
Metal Organic ◽  
Organic Framework

Metal–organic-framework-derived NaTi2(PO4)3/carbon composites with unique porous structure and improved electrical conductivity exhibit high desalination performance for hybrid capacitive deionization.

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