The effect of polymeric binders in the sulfur cathode on the cycling performance for lithium–sulfur batteries

2019 ◽  
Vol 55 (97) ◽  
pp. 14609-14612
Author(s):  
Ji-Yong Eom ◽  
Seong-In Kim ◽  
Vitalii Ri ◽  
Chunjoong Kim
Keyword(s):  
Electrochemical Performance ◽  
Cycling Performance ◽  
Sulfur Cathode ◽  
Lithium Sulfur Batteries ◽  
Polymeric Binders ◽  
Sulfur Cathodes ◽  
Lithium Sulfur

We study the structural and electrochemical performance of sulfur cathodes prepared with two different binders, PVdF and SBR/CMC. Enhanced battery performance is observed in the SBR/CMC-based electrode and its origin is scrutinized.

Flexible freestanding sandwich-structured sulfur cathode with superior performance for lithium–sulfur batteries

2014 ◽  
Vol 2 (23) ◽  
pp. 8623-8627 ◽  
Author(s):  
Jiangxuan Song ◽  
Zhaoxin Yu ◽  
Terrence Xu ◽  
Shuru Chen ◽  
Hiesang Sohn ◽  
...  
Keyword(s):  
Rate Capability ◽  
Cycling Stability ◽  
Superior Performance ◽  
Sulfur Cathode ◽  
Lithium Sulfur Batteries ◽  
Excellent Cycling Stability ◽  
Sulfur Cathodes ◽  
Areal Capacity ◽  
Lithium Sulfur

Flexible freestanding sandwich-structured sulfur cathodes are developed for lithium–sulfur batteries, which exhibit excellent cycling stability and rate capability. A high areal capacity of ∼4 mA h cm−2 is also demonstrated based on this new cathode configuration.

PAA/PEDOT:PSS as a multifunctional, water-soluble binder to improve the capacity and stability of lithium–sulfur batteries

RSC Advances ◽  
2016 ◽  
Vol 6 (47) ◽  
pp. 40650-40655 ◽  
Author(s):  
Jin Pan ◽  
Guiyin Xu ◽  
Bing Ding ◽  
Zhi Chang ◽  
Aixiu Wang ◽  
...  
Keyword(s):  
Synergistic Effect ◽  
Cycling Performance ◽  
Water Soluble ◽  
Lithium Sulfur Batteries ◽  
Sulfur Cathodes ◽  
Lithium Sulfur

An improved cycling performance of sulfur cathodes is attributed to the synergistic effect of PAA and PEDOT:PSS.

Gel based sulfur cathodes with a high sulfur content and large mass loading for high-performance lithium–sulfur batteries

2017 ◽  
Vol 5 (4) ◽  
pp. 1650-1657 ◽  
Author(s):  
Shiqi Li ◽  
Tong Mou ◽  
Guofeng Ren ◽  
Juliusz Warzywoda ◽  
Zidong Wei ◽  
...  
Keyword(s):  
Sulfur Content ◽  
High Performance ◽  
Large Mass ◽  
Mass Loading ◽  
Sulfur Cathode ◽  
High Sulfur Content ◽  
Lithium Sulfur Batteries ◽  
Sulfur Cathodes ◽  
Lithium Sulfur ◽  
High Sulfur Loading

A bacterial cellulose based carbon nanoribbon aerogel was employed for a gel-based sulfur cathode, simultaneously achieving both a high sulfur content (90%) and a high sulfur loading (6.4 mg cm−2) with a large capacity of 943 mA h g−1or 5.9 mA h cm−2.

Hydroxylated carbon nanotube enhanced sulfur cathodes for improved electrochemical performance of lithium–sulfur batteries

2015 ◽  
Vol 51 (71) ◽  
pp. 13682-13685 ◽  
Author(s):  
Joo Hyun Kim ◽  
Kun Fu ◽  
Junghyun Choi ◽  
Seho Sun ◽  
Jeonghyun Kim ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Carbon Nanotube ◽  
Electrochemical Performance ◽  
Lithium Sulfur Batteries ◽  
Multi Walled Carbon Nanotubes ◽  
Walled Carbon Nanotubes ◽  
Sulfur Cathodes ◽  
Lithium Sulfur

Hydroxylated multi-walled carbon nanotubes were introduced into sulfur cathodes to utilize the hydrophilic attraction between the OH group and polysulfides as well as to increase the utilization of sulfur.

scholarly journals Recent advances of hollow-structured sulfur cathodes for lithium–sulfur batteries

2020 ◽  
Vol 4 (9) ◽  
pp. 2517-2547
Author(s):  
Xia Huang ◽  
Tengfei Qiu ◽  
Xinghao Zhang ◽  
Lei Wang ◽  
Bin Luo ◽  
...  
Keyword(s):  
Electrochemical Performance ◽  
High Performance ◽  
Recent Advances ◽  
Lithium Sulfur Batteries ◽  
Sulfur Cathodes ◽  
Lithium Sulfur

This review summarises recent advances of hollow-structured sulfur cathodes for high performance lithium sulfur batteries, focusing on their synthesis, structure, electrochemical performance, advantages and challenges.

Cubic MnSe2 microcube enabling high-performance sulfur cathode for lithium-sulfur batteries

2021 ◽  
Author(s):  
Jian Bao ◽  
Xin-Yang Yue ◽  
Rui-Jie Luo ◽  
Yong-Ning Zhou
Keyword(s):  
Strong Interaction ◽  
High Performance ◽  
Sulfur Cathode ◽  
Shuttle Effect ◽  
Lithium Polysulfide ◽  
Lithium Sulfur Batteries ◽  
Sulfur Cathodes ◽  
Lithium Sulfur

Cubic MnSe2 microcubes are introduced into sulfur cathodes to prevent the shuttle effect of lithium polysulfide through binding with polysulfide via the strong interaction between Se and S, thus alleviate...

Synthesis of carbon nanoflake/sulfur arrays as cathode materials of lithium-sulfur batteries

2018 ◽  
Vol 11 (06) ◽  
pp. 1840001 ◽  
Author(s):  
Fan Wang ◽  
Xinqi Liang ◽  
Minghua Chen ◽  
Xinhui Xia
Keyword(s):  
Cathode Materials ◽  
Cycling Performance ◽  
High Rate ◽  
Synthetic Method ◽  
Sulfur Cathode ◽  
Dual Roles ◽  
High Quality ◽  
Shuttle Effect ◽  
Lithium Sulfur Batteries ◽  
Lithium Sulfur

It is of great importance to develop high-quality carbon/sulfur cathode for lithium-sulfur batteries (LSBs). Herein, we report a facile strategy to embed sulfur into interconnected carbon nanoflake matrix forming integrated electrode. Interlinked carbon nanoflakes have dual roles not only as a highly conductive matrix to host sulfur, but also act as blocking barriers to suppress the shuttle effect of intermediate polysulfides. In the light of these positive characteristics, the obtained carbon nanoflake/S cathode exhibit good LSBs performances with high capacities (1117[Formula: see text]mAh[Formula: see text]g[Formula: see text] at 0.2[Formula: see text]C, and 741[Formula: see text]mAh[Formula: see text]g[Formula: see text] at 0.6[Formula: see text]C) and good high-rate cycling performance. Our synthetic method provides a novel way to construct enhanced carbon/sulfur cathode for LSBs.

Hollow polyaniline sphere@sulfur composites for prolonged cycling stability of lithium–sulfur batteries

2014 ◽  
Vol 2 (27) ◽  
pp. 10350-10354 ◽  
Author(s):  
Guoqiang Ma ◽  
Zhaoyin Wen ◽  
Jun Jin ◽  
Yan Lu ◽  
Xiangwei Wu ◽  
...  
Keyword(s):  
Electrochemical Performance ◽  
Volume Expansion ◽  
Cycling Stability ◽  
Sulfur Cathode ◽  
Shuttle Effect ◽  
Excellent Electrochemical Performance ◽  
Lithium Sulfur Batteries ◽  
Lithium Sulfur

Sulfur cathode with excellent electrochemical performance based on hollow PANI spheres, which can suppress the shuttle effect and buffer the volume expansion.

Sign in / Sign up

Export Citation Format

Share Document