scholarly journals Dramatic rate-enhancement of oxygen atom transfer by an iron(iv)-oxo species by equatorial ligand field perturbations

2018 ◽  
Vol 47 (42) ◽  
pp. 14945-14957 ◽  
Author(s):  
Gourab Mukherjee ◽  
Calvin W. Z. Lee ◽  
Sayanta Sekhar Nag ◽  
Aligulu Alili ◽  
Fabián G. Cantú Reinhard ◽  
...  
Keyword(s):  
Oxygen Atom ◽  
Coordination Sphere ◽  
Ligand Field ◽  
Atom Transfer ◽  
Oxygen Atom Transfer ◽  
Rate Enhancement ◽  
Ligand System ◽  
System P ◽  
Equatorial Ligand

The reactivity and characterization of a novel iron(iv)-oxo species is reported that gives enhanced reactivity as a result of second-coordination sphere perturbations of the ligand system.

Oxygen atom transfer in low-temperature matrixes. 1. Formation and characterization of matrix-isolated OMF3 (M = P, As)

1982 ◽  
Vol 21 (9) ◽  
pp. 3385-3393 ◽  
Author(s):  
Anthony J. Downs ◽  
Geoffrey P. Gaskill ◽  
Simon B. Saville
Keyword(s):  
Low Temperature ◽  
Oxygen Atom ◽  
Atom Transfer ◽  
Oxygen Atom Transfer

Synthesis and characterization of thiocyanato and chlorodioxo tungsten(VI) compounds: Comparative oxygen atom transfer capability with molybdenum analogs

2006 ◽  
Vol 359 (1) ◽  
pp. 81-89 ◽  
Author(s):  
Henri Arzoumanian ◽  
Giuseppe Agrifoglio ◽  
Mario V. Capparelli ◽  
Reinaldo Atencio ◽  
Alexander Briceño ◽  
...  
Keyword(s):  
Oxygen Atom ◽  
Synthesis And Characterization ◽  
Atom Transfer ◽  
Oxygen Atom Transfer ◽  
Transfer Capability
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