Detection, Isolation, and Characterization of Intermediates in Oxygen Atom Transfer Reactions in Molybdoenzyme Model Systems

2000 ◽  
Vol 122 (38) ◽  
pp. 9298-9299 ◽  
Author(s):  
Paul D. Smith ◽  
Andrew J. Millar ◽  
Charles G. Young ◽  
Amit Ghosh ◽  
Partha Basu
Author(s):  
Leila G. Ranis ◽  
Jacqueline Gianino ◽  
Justin M. Hoffman ◽  
Seth N. Brown

Eight-coordinate MoO2(DOPOQ)2 can donate two oxygen atoms to substrates such as phosphines in a four-electron nonclassical oxygen atom transfer reaction.


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