Synthesis and characterization of two dioxidomolybdenum(VI) complexes bearing amidinato and pyrazolato ligands and their use in thin film growth and oxygen atom transfer reactions

Polyhedron ◽  
2018 ◽  
Vol 147 ◽  
pp. 36-41 ◽  
Author(s):  
Oussama M. El-Kadri ◽  
Ameer A. Siddique ◽  
Matthew D. Eaton ◽  
Naba K. Nath
Keyword(s):  
Thin Film ◽  
Oxygen Atom ◽  
Film Growth ◽  
Thin Film Growth ◽  
Transfer Reactions ◽  
Synthesis And Characterization ◽  
Atom Transfer ◽  
Oxygen Atom Transfer ◽  
Oxygen Atom Transfer Reactions

Nonclassical oxygen atom transfer reactions of an eight-coordinate dioxomolybdenum(vi) complex

2021 ◽  
Author(s):  
Leila G. Ranis ◽  
Jacqueline Gianino ◽  
Justin M. Hoffman ◽  
Seth N. Brown
Keyword(s):  
Oxygen Atom ◽  
Transfer Reaction ◽  
Transfer Reactions ◽  
Atom Transfer ◽  
Oxygen Atom Transfer ◽  
Oxygen Atom Transfer Reactions ◽  
Atom Transfer Reactions ◽  
Oxygen Atoms

Eight-coordinate MoO2(DOPOQ)2 can donate two oxygen atoms to substrates such as phosphines in a four-electron nonclassical oxygen atom transfer reaction.

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