Isolation, Characterization of an Intermediate in an Oxygen Atom-Transfer Reaction, and the Determination of the Bond Dissociation Energy

2004 ◽  
Vol 126 (28) ◽  
pp. 8604-8605 ◽  
Author(s):  
Victor N. Nemykin ◽  
Julia Laskin ◽  
Partha Basu
Keyword(s):  
Oxygen Atom ◽  
Bond Dissociation Energy ◽  
Dissociation Energy ◽  
Transfer Reaction ◽  
Atom Transfer ◽  
Oxygen Atom Transfer ◽  
Bond Dissociation

Nonclassical oxygen atom transfer reactions of an eight-coordinate dioxomolybdenum(vi) complex

2021 ◽  
Author(s):  
Leila G. Ranis ◽  
Jacqueline Gianino ◽  
Justin M. Hoffman ◽  
Seth N. Brown
Keyword(s):  
Oxygen Atom ◽  
Transfer Reaction ◽  
Transfer Reactions ◽  
Atom Transfer ◽  
Oxygen Atom Transfer ◽  
Oxygen Atom Transfer Reactions ◽  
Atom Transfer Reactions ◽  
Oxygen Atoms

Eight-coordinate MoO2(DOPOQ)2 can donate two oxygen atoms to substrates such as phosphines in a four-electron nonclassical oxygen atom transfer reaction.

Oxygen atom transfer in low-temperature matrixes. 1. Formation and characterization of matrix-isolated OMF3 (M = P, As)

1982 ◽  
Vol 21 (9) ◽  
pp. 3385-3393 ◽  
Author(s):  
Anthony J. Downs ◽  
Geoffrey P. Gaskill ◽  
Simon B. Saville
Keyword(s):  
Low Temperature ◽  
Oxygen Atom ◽  
Atom Transfer ◽  
Oxygen Atom Transfer

Determination of the heat of formation of trimethylindium and calculation of the mean In—CH3 bond dissociation energy

1968 ◽  
Vol 46 (10) ◽  
pp. 1633-1634 ◽  
Author(s):  
W. D. Clark ◽  
S. J. W. Price
Keyword(s):  
Bond Dissociation Energy ◽  
Dissociation Energy ◽  
Chloroform Solution ◽  
Kinetic Studies ◽  
Heat Of Formation ◽  
Enthalpy Of Reaction ◽  
Kcal Mole ◽  
Bond Dissociation ◽  
The Mean

The enthalpy of reaction of In(CH3)3,c with a chloroform solution of bromine is −162.5 kcal mole−1. With this value ΔHf0298[In(CH3)3,c] = 29.5 kcal mole−1 and ΔHf0298[In(CH3)3,g] = 41.1 kcal mole−1. Combining the latter with ΔHf0298[CH3,g] = 33.2 kcal mole−1 and ΔHf0298[In,g] = 58.2 kcal mole−1 then gives E(In—CH3) = 38.9 kcal mole−1. From previous kinetic studies D[(CH3)2In—CH3] + D[In—CH3] = 87.9 kcal mole−1. Hence D[CH3In—CH3] = 28.8 kcal mole−1.

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