A Novel Photoresponsive Azobenzene-Containing Miktoarm Star Polymer: Self-Assembly and Photoresponse Properties

2014 ◽  
Vol 47 (11) ◽  
pp. 3693-3700 ◽  
Author(s):  
Eva Blasco ◽  
Bernhard V. K. J. Schmidt ◽  
Christopher Barner-Kowollik ◽  
Milagros Piñol ◽  
Luis Oriol
Keyword(s):  
Self Assembly ◽  
Star Polymer ◽  
Miktoarm Star

scholarly journals Synthesis of μ-ABC Tricyclic Miktoarm Star Polymer via Intramolecular Click Cyclization

Polymers ◽  
2018 ◽  
Vol 10 (8) ◽  
pp. 877 ◽  
Author(s):  
Tomoki Shingu ◽  
Takuya Yamamoto ◽  
Kenji Tajima ◽  
Takuya Isono ◽  
Toshifumi Satoh
Keyword(s):  
Self Assembly ◽  
Diblock Copolymers ◽  
Glycidyl Ether ◽  
Chemical Properties ◽  
Star Polymer ◽  
Synthetic Approach ◽  
Glycidyl Ethers ◽  
Miktoarm Star ◽  
Functional Initiators ◽  
Physical And Chemical

Cyclic polymers exhibit unique physical and chemical properties because of the restricted chain mobility and absence of chain ends. Although many types of homopolymers and diblock copolymers possessing cyclic architectures have been synthesized to date, there are relatively few reports of cyclic triblock terpolymers because of their synthetic difficulties. In this study, a novel synthetic approach for μ-ABC tricyclic miktoarm star polymers involving t-Bu-P4-catalyzed ring-opening polymerization (ROP) of glycidyl ethers and intramolecular copper-catalyzed azido-alkyne cycloaddition (CuAAC) was developed. First, the t-Bu-P4-catalyzed ROP of decyl glycidyl ether, dec-9-enyl glycidyl ether, and 2-(2-(2-methoxyethoxy) ethoxy) ethyl glycidyl ether with the aid of functional initiators and terminators was employed for the preparation of a clickable linear triblock terpolymer precursor possessing three azido and three ethynyl groups at the selected positions. Next, the intramolecular CuAAC of the linear precursor successfully produced the well-defined tricyclic triblock terpolymer with narrow dispersity in a reasonable yield. The present strategy is useful for synthesizing model polymers for studying the topological effects on the triblock terpolymer self-assembly.

Synthesis of the First Organometallic Miktoarm Star Polymer

2003 ◽  
Vol 24 (56) ◽  
pp. 403-407 ◽  
Author(s):  
Xiao Song Wang ◽  
Mitchell A. Winnik ◽  
Ian Manners
Keyword(s):  
Star Polymer ◽  
Miktoarm Star

An all-optical photorefractive miktoarm star polymer synthesized via a combination of RAFT polymerization and click reaction

2019 ◽  
Vol 143 ◽  
pp. 104321 ◽  
Author(s):  
Wansheng Zong ◽  
Su Wang ◽  
Juan Li ◽  
Jintao Wang ◽  
Mingming Li ◽  
...  
Keyword(s):  
Click Reaction ◽  
Raft Polymerization ◽  
Star Polymer ◽  
All Optical ◽  
Miktoarm Star

Crystallization-Driven Solution Self-Assembly of μ-ABC Miktoarm Star Terpolymers with Core-Forming Polyferrocenylsilane Blocks

2014 ◽  
Vol 47 (23) ◽  
pp. 8420-8428 ◽  
Author(s):  
Adam Nunns ◽  
George R. Whittell ◽  
Mitchell A. Winnik ◽  
Ian Manners
Keyword(s):  
Self Assembly ◽  
Miktoarm Star

Tuning Solvent Quality Induces Morphological Phase Transitions in Miktoarm Star Polymer Films

2020 ◽  
Vol 53 (15) ◽  
pp. 6151-6162
Author(s):  
Zerihun G. Workineh ◽  
Giuseppe Pellicane ◽  
Mesfin Tsige
Keyword(s):  
Phase Transitions ◽  
Polymer Films ◽  
Star Polymer ◽  
Solvent Quality ◽  
Miktoarm Star

Synthesis of miktoarm star amphiphilic block copolymers via combination of NMRP and ATRP and investigation on self-assembly behaviors

2009 ◽  
Vol 47 (22) ◽  
pp. 6304-6315 ◽  
Author(s):  
Weidong Zhang ◽  
Wei Zhang ◽  
Nianchen Zhou ◽  
Jian Zhu ◽  
Zhenping Cheng ◽  
...  
Keyword(s):  
Block Copolymers ◽  
Self Assembly ◽  
Amphiphilic Block Copolymers ◽  
Miktoarm Star
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