Molecular and Crystalline Microstructure of Ferroelectric Poly(vinylidene fluoride-co-trifluoroethylene) Ultrathin Films on Bare and Self-Assembled Monolayer-Modified Au Substrates

2008 ◽  
Vol 41 (1) ◽  
pp. 109-119 ◽  
Author(s):  
Youn Jung Park ◽  
Seok Ju Kang ◽  
Cheolmin Park ◽  
Bernard Lotz ◽  
Annette Thierry ◽  
...  
Membranes ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 301
Author(s):  
Xingjia Li ◽  
Zhi Shi ◽  
Xiuli Zhang ◽  
Xiangjian Meng ◽  
Zhiqiang Huang ◽  
...  

The effect of testing temperature and storage period on the polarization fatigue properties of poly (vinylidene fluoride-trifluoroethylene) (P(VDF–TrFE)) ultrathin film devices were investigated. The experimental results show that, even after stored in air for 150 days, the relative remanent polarization (Pr/Pr(0)) of P(VDF–TrFE) of ultrathin films can keep at a relatively high level of 0.80 at 25 °C and 0.70 at 60 °C. To account for this result, a hydrogen fluoride (HF) formation inhibition mechanism was proposed, which correlated the testing temperature and the storage period with the microstructure of P(VDF–TrFE) molecular chain. Moreover, a theoretical model was constructed to describe the polarization fatigue evolution of P(VDF–TrFE) samples.


2014 ◽  
Vol 104 (10) ◽  
pp. 103505 ◽  
Author(s):  
Xiuli Zhang ◽  
Xiaoli Du ◽  
Ying Hou ◽  
Zhaoyue Lü ◽  
Haisheng Xu

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