Dielectric properties and ferroelectric behavior of poly(vinylidene fluoride-trifluoroethylene) 50/50 copolymer ultrathin films

2001 ◽  
Vol 80 (12) ◽  
pp. 2259-2266 ◽  
Author(s):  
Haisheng Xu
2009 ◽  
Vol 1240 ◽  
Author(s):  
Jun-Hong Lin ◽  
David Sheng-Guo Lu ◽  
Minren Lin ◽  
Qiming Zhang

AbstractPoly(vinylidene fluoride trifluoroethylene chlorofluoroethylene) (P(VDF-TrFE-CFE)) terpolymer nanorods embedded in Anodic Alumina Oxide( AAO) templates with pore sizes of 25, 70, and 200nm diameter were fabricated by extending the time of the wetting process. The instability of the wetting process induced the terpolymer infiltration into the inner space of tepolymer nanotubes, which formed mostly filled terpolymer nanorods. It was observed that all these nanorods embedded in AAO templates still possess relaxor ferroelectric behavior. The broad dielectric peak shifts progressively to higher temperatures with increasing frequency and the frequency- permittivity peak temperature fits well with the Vogel-Fulcher (V-F) relation. Moreover, the freezing temperature of the V-F relation is reduced, with the reduction of nanorod diameter. This indicates that the lateral confinement of the nanorods influences the relaxor ferroelectric behavior of the relaxor ferroelectric P(VDF-TrFE-CFE) terpolymer.


Membranes ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 301
Author(s):  
Xingjia Li ◽  
Zhi Shi ◽  
Xiuli Zhang ◽  
Xiangjian Meng ◽  
Zhiqiang Huang ◽  
...  

The effect of testing temperature and storage period on the polarization fatigue properties of poly (vinylidene fluoride-trifluoroethylene) (P(VDF–TrFE)) ultrathin film devices were investigated. The experimental results show that, even after stored in air for 150 days, the relative remanent polarization (Pr/Pr(0)) of P(VDF–TrFE) of ultrathin films can keep at a relatively high level of 0.80 at 25 °C and 0.70 at 60 °C. To account for this result, a hydrogen fluoride (HF) formation inhibition mechanism was proposed, which correlated the testing temperature and the storage period with the microstructure of P(VDF–TrFE) molecular chain. Moreover, a theoretical model was constructed to describe the polarization fatigue evolution of P(VDF–TrFE) samples.


2017 ◽  
Vol 5 (47) ◽  
pp. 12430-12440 ◽  
Author(s):  
N. Phatharapeetranun ◽  
B. Ksapabutr ◽  
D. Marani ◽  
J. R. Bowen ◽  
V. Esposito

“3D-printed” anisotropy BTNFs/PVDF nanohybrids are successfully fabricated by the FDM technique which is attractive for developing novel functionalities in dielectric devices.


2015 ◽  
Vol 146 ◽  
pp. 1-5 ◽  
Author(s):  
Kanyapak Silakaew ◽  
Wantana Saijingwong ◽  
Keerati Meeporn ◽  
Santi Maensiri ◽  
Prasit Thongbai

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