Scanning Tunneling and Atomic Force Microscopy Evidence for Covalent and Noncovalent Interactions between Aryl Films and Highly Ordered Pyrolytic Graphite

2014 ◽  
Vol 118 (11) ◽  
pp. 5820-5826 ◽  
Author(s):  
Haifeng Ma ◽  
Lita Lee ◽  
Paula A. Brooksby ◽  
Simon A. Brown ◽  
Sara J. Fraser ◽  
...  
1997 ◽  
Vol 12 (8) ◽  
pp. 1942-1945 ◽  
Author(s):  
H. J. Gao ◽  
H. X. Zhang ◽  
Z. Q. Xue ◽  
S. J. Pang

Scanning tunneling microscopy (STM) and atomic force microscopy (AFM) investigation of tetracyanoquinodimethane (TCNQ) and the related C60-TCNQ thin films is presented. Periodic molecular chains of the TCNQ on highly oriented pyrolytic graphite (HOPG) substrates were imaged, which demonstrated that the crystalline (001) plane was parallel to the substrate. For the C60-TCNQ thin films, we found that there were grains on the film surface. STM images within the grain revealed that the well-ordered rows and terraces, and the parallel rows in different grains were generally not in the same orientation. Moreover, the grain boundary was also observed. In addition, AFM was employed to modify the organic TCNQ film surface for the application of this type of materials to information recording and storage at the nanometer scale. The nanometer holes were successfully created on the TCNQ thin film by the AFM.


2015 ◽  
Vol 17 (1) ◽  
pp. 325-333 ◽  
Author(s):  
Ben McLean ◽  
Hua Li ◽  
Ryan Stefanovic ◽  
Ross J. Wood ◽  
Grant B. Webber ◽  
...  

Atomic force microscopy (AFM) force measurements have been used to study the solvate ionic liquid (IL) double layer nanostructure at highly ordered pyrolytic graphite (HOPG) and Au(111) electrode surfaces as a function of potential.


2021 ◽  
Vol 03 (02) ◽  
pp. 128-133
Author(s):  
Zijie Qiu ◽  
Qiang Sun ◽  
Shiyong Wang ◽  
Gabriela Borin Barin ◽  
Bastian Dumslaff ◽  
...  

Intramolecular methyl–methyl coupling on Au (111) is explored as a new on-surface protocol for edge extension in graphene nanoribbons (GNRs). Characterized by high-resolution scanning tunneling microscopy, noncontact atomic force microscopy, and Raman spectroscopy, the methyl–methyl coupling is proven to indeed proceed at the armchair edges of the GNRs, forming six-membered rings with sp3- or sp2-hybridized carbons.


Author(s):  
Natalia A. Lashkova ◽  
Nikita V. Permiakov ◽  
Alexander I. Maximov ◽  
Yulia M. Spivak ◽  
Vyacheslav A. Moshnikov

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