scholarly journals Diastereo- and Enantioselective Ruthenium-Catalyzed Hydrohydroxyalkylation of 2-Silyl-butadienes: Carbonylsyn-Crotylation from the Alcohol Oxidation Level

2011 ◽  
Vol 133 (27) ◽  
pp. 10582-10586 ◽  
Author(s):  
Jason R. Zbieg ◽  
Joseph Moran ◽  
Michael J. Krische
Keyword(s):  
Alcohol Oxidation ◽  
Oxidation Level

ChemInform Abstract: Cu(II)-Catalyzed Oxidative Esterification of 2-Carbonyl Substituted Phenols from the Alcohol Oxidation Level.

ChemInform ◽  
2014 ◽  
Vol 45 (13) ◽  
pp. no-no
Author(s):  
Satyasheel Sharma ◽  
Jihye Park ◽  
Mirim Kim ◽  
Jong Hwan Kwak ◽  
Young Hoon Jung ◽  
...  
Keyword(s):  
Alcohol Oxidation ◽  
Substituted Phenols ◽  
Oxidative Esterification ◽  
Oxidation Level

ChemInform Abstract: Palladium-Catalyzed Direct Acylation of Ketoximes and Aldoximes from the Alcohol Oxidation Level Through C-H Bond Activation.

ChemInform ◽  
2014 ◽  
Vol 45 (11) ◽  
pp. no-no
Author(s):  
Satyasheel Sharma ◽  
Minyoung Kim ◽  
Jihye Park ◽  
Mirim Kim ◽  
Jong Hwan Kwak ◽  
...  
Keyword(s):  
Bond Activation ◽  
Alcohol Oxidation ◽  
Oxidation Level ◽  
Palladium Catalyzed ◽  
Direct Acylation

Palladium-Catalyzed Direct Acylation of Ketoximes and Aldoximes from the Alcohol Oxidation Level through C-H Bond Activation

2013 ◽  
Vol 2013 (29) ◽  
pp. 6656-6665 ◽  
Author(s):  
Satyasheel Sharma ◽  
Minyoung Kim ◽  
Jihye Park ◽  
Mirim Kim ◽  
Jong Hwan Kwak ◽  
...  
Keyword(s):  
Bond Activation ◽  
Alcohol Oxidation ◽  
Oxidation Level ◽  
Palladium Catalyzed ◽  
Direct Acylation

scholarly journals Elongation of 1,3-Polyols via Iterative Catalyst-Directed Carbonyl Allylation from the Alcohol Oxidation Level

2009 ◽  
Vol 11 (14) ◽  
pp. 3112-3115 ◽  
Author(s):  
Abbas Hassan ◽  
Yu Lu ◽  
Michael J. Krische
Keyword(s):  
Alcohol Oxidation ◽  
Oxidation Level ◽  
Carbonyl Allylation

scholarly journals Copper-catalyzed C–C bond-forming transformation of CO2 to alcohol oxidation level: selective synthesis of homoallylic alcohols from allenes, CO2, and hydrosilanes

2015 ◽  
Vol 51 (65) ◽  
pp. 13020-13023 ◽  
Author(s):  
Yosuke Tani ◽  
Kazunari Kuga ◽  
Tetsuaki Fujihara ◽  
Jun Terao ◽  
Yasushi Tsuji
Keyword(s):  
Alcohol Oxidation ◽  
Selective Synthesis ◽  
Oxidation Level ◽  
Bond Forming ◽  
Homoallylic Alcohols

Title transformation has been disclosed wherein CO2 is chemoselectively reduced to the alcohol oxidation level to provide homoallylic alcohols, with esters or other reducible functionalities on the allenes being intact.

The Chemistry of Pyrrolic Compounds. LXII. The Oxidative Cyclization of Bilenes-b: Identification of the Expelled Carbon Fragment

1990 ◽  
Vol 43 (2) ◽  
pp. 383 ◽  
Author(s):  
EJ Atkinson ◽  
JJ Brophy ◽  
PS Clezy
Keyword(s):  
Acetic Acid ◽  
Trifluoroacetic Acid ◽  
Alcohol Oxidation ◽  
Oxidative Cyclization ◽  
Careful Examination ◽  
Benzyl Acetate ◽  
Oxidation Level ◽  
Porphyrin Derivative ◽  
Carbon Fragment ◽  
By Products

Oxidative cyclization of the 1,19-dibenzylbilene-b salt (12) with copper(II) acetate in acetic acid/methanol yielded the expected meso-phenylporphyrin (13). Careful examination of the by-products by g.l.c./m.s , revealed the presence of benzyl acetate, indicating the fragment excluded was lost at the alcohol oxidation level. When trifluoroacetic acid was present in the cyclization mixture benzyl trifluoroacetate was the only fragment identified. Heating the meso-phenylporphyrin (13) yielded the cyclic ketonic porphyrin derivative (14).

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