scholarly journals Copper-catalyzed C–C bond-forming transformation of CO2 to alcohol oxidation level: selective synthesis of homoallylic alcohols from allenes, CO2, and hydrosilanes

2015 ◽  
Vol 51 (65) ◽  
pp. 13020-13023 ◽  
Author(s):  
Yosuke Tani ◽  
Kazunari Kuga ◽  
Tetsuaki Fujihara ◽  
Jun Terao ◽  
Yasushi Tsuji
Keyword(s):  
Alcohol Oxidation ◽  
Selective Synthesis ◽  
Oxidation Level ◽  
Bond Forming ◽  
Homoallylic Alcohols

Title transformation has been disclosed wherein CO2 is chemoselectively reduced to the alcohol oxidation level to provide homoallylic alcohols, with esters or other reducible functionalities on the allenes being intact.

ChemInform Abstract: Cu(II)-Catalyzed Oxidative Esterification of 2-Carbonyl Substituted Phenols from the Alcohol Oxidation Level.

ChemInform ◽  
2014 ◽  
Vol 45 (13) ◽  
pp. no-no
Author(s):  
Satyasheel Sharma ◽  
Jihye Park ◽  
Mirim Kim ◽  
Jong Hwan Kwak ◽  
Young Hoon Jung ◽  
...  
Keyword(s):  
Alcohol Oxidation ◽  
Substituted Phenols ◽  
Oxidative Esterification ◽  
Oxidation Level

Catalytic synthesis of amines and N-containing heterocycles: Amidate complexes for selective C–N and C–C bond-forming reactions

2010 ◽  
Vol 82 (7) ◽  
pp. 1503-1515 ◽  
Author(s):  
Patrick Eisenberger ◽  
Laurel L. Schafer
Keyword(s):  
Transition Metal ◽  
Catalytic Synthesis ◽  
Transition Metal Catalysts ◽  
Selective Synthesis ◽  
High Oxidation State ◽  
Early Transition Metal ◽  
Bond Forming ◽  
Group 4 ◽  
High Oxidation ◽  
Bond Forming Reactions

The direct, 100 % atom-economic, and selective synthesis of amines is a challenging task that can be achieved, making use of early transition-metal catalysts. Here we report the synthesis and application of group 4 and 5 high-oxidation-state metal amidate complexes in catalytic C–N (hydroamination) and C–C (hydroaminoalkylation) bond-forming reactions to access substituted amines.

ChemInform Abstract: Palladium-Catalyzed Direct Acylation of Ketoximes and Aldoximes from the Alcohol Oxidation Level Through C-H Bond Activation.

ChemInform ◽  
2014 ◽  
Vol 45 (11) ◽  
pp. no-no
Author(s):  
Satyasheel Sharma ◽  
Minyoung Kim ◽  
Jihye Park ◽  
Mirim Kim ◽  
Jong Hwan Kwak ◽  
...  
Keyword(s):  
Bond Activation ◽  
Alcohol Oxidation ◽  
Oxidation Level ◽  
Palladium Catalyzed ◽  
Direct Acylation
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