Three-Dimensional Porous Coordination Polymer Functionalized with Amide Groups Based on Tridentate Ligand:  Selective Sorption and Catalysis

2007 ◽  
Vol 129 (9) ◽  
pp. 2607-2614 ◽  
Author(s):  
Shinpei Hasegawa ◽  
Satoshi Horike ◽  
Ryotaro Matsuda ◽  
Shuhei Furukawa ◽  
Katsunori Mochizuki ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Three Dimensional ◽  
Tridentate Ligand ◽  
Selective Sorption ◽  
Porous Coordination Polymer

scholarly journals Synthesis, Crystal Structure, and Properties of a New Coordination Polymer Built from N/O-Donor Mixed Ligands

Crystals ◽  
2018 ◽  
Vol 8 (10) ◽  
pp. 372
Author(s):  
Mei-An Zhu ◽  
Shuai-Shuai Han ◽  
Feng Deng ◽  
Jia-Le Li ◽  
Shui-Sheng Chen
Keyword(s):  
Coordination Polymer ◽  
Weak Interactions ◽  
Three Dimensional ◽  
Luminescent Properties ◽  
Tridentate Ligand ◽  
Supramolecular Polymer ◽  
X Ray Diffraction ◽  
X Ray ◽  
Mixed Ligands ◽  
Benzenedicarboxylic Acid

The coordination polymer, namely, [Cd(H2L)(nobda)]n (1) was prepared by the reaction of Cd(NO3)2·4H2O with 4-amino-1,2-benzenedicarboxylic acid (H2nobda) and 1,4-di(1H-imidazol-4-yl)benzene (H2L), and characterized by single-crystal X-ray diffraction, elemental analysis, infrared (IR) spectroscopy, thermogravimetric analysis, and powder X-ray diffraction (PXRD). The carboxylic acid of H2nobda ligands was completely deprotonated to be nobda2− anions, which act as tridentate ligand to connect the Cd2+ to form two-dimensional (2D) network, while the neutral H2L ligands serve as a linear didentate bridge to connect two adjacent Cd2+ ions upper and down the 2D layer. The adjacent 2D layers were further linked into the three-dimensional (3D) supramolecular polymer by the weak interactions such as hydrogen bonds and π−π stacking interactions. The ultraviolet-visible (UV-vis) absorption spectra and luminescent properties in the solid state at room temperature have been investigated.

Selective sorption of oxygen and nitric oxide by an electron-donating flexible porous coordination polymer

2010 ◽  
Vol 2 (8) ◽  
pp. 633-637 ◽  
Author(s):  
Satoru Shimomura ◽  
Masakazu Higuchi ◽  
Ryotaro Matsuda ◽  
Ko Yoneda ◽  
Yuh Hijikata ◽  
...  
Keyword(s):  
Nitric Oxide ◽  
Coordination Polymer ◽  
Selective Sorption ◽  
Porous Coordination Polymer

Three-dimensional iron(ii) porous coordination polymer exhibiting carbon dioxide-dependent spin crossover

2018 ◽  
Vol 54 (34) ◽  
pp. 4262-4265 ◽  
Author(s):  
Jong Won Shin ◽  
Ah Rim Jeong ◽  
Sungeun Jeoung ◽  
Hoi Ri Moon ◽  
Yuki Komatsumaru ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Coordination Polymer ◽  
Spin Crossover ◽  
Three Dimensional ◽  
Porous Coordination Polymer

A three-dimensional iron(ii) porous coordination polymer has been observed spin crossover behaviours through the sorption of H2O and CO2, respectively.

A Silver(I) Coordination Polymer Based on a Schiff Base Ligand: Synthesis, Crystal Structure and Luminescence Properties

2013 ◽  
Vol 68 (3) ◽  
pp. 284-288 ◽  
Author(s):  
Lin Yu Jin ◽  
Meng Meng Li ◽  
Dong Bin Dang ◽  
Yan Bai ◽  
Yan Ning Zheng
Keyword(s):  
Coordination Polymer ◽  
Room Temperature ◽  
Three Dimensional ◽  
Chain Structure ◽  
Luminescence Properties ◽  
Tridentate Ligand ◽  
Supramolecular Network ◽  
Zigzag Chain ◽  
X Ray Diffraction ◽  
X Ray

A new Ag(I) coordination polymer [AgL(NO3)]n 1 (L=4-(pyridine-2-yl)methyleneamino-1,2,4- trizaole) has been synthesized and characterized by IR spectroscopy, elemental analysis, powder and single-crystal X-ray diffraction. The Ag(I) atom has a seesaw environment with an N3O donor set from three N atoms of two ligands and one O atom of one NO-3 anion. Each twisted tridentate ligand is bound to two silver centers, and each silver atom is coordinated by two ligands thereby generating a zigzag chain structure. The chains interact with each other featuring a three-dimensional supramolecular network through multiple weak C-H···π interactions and C-H···O hydrogen bonds. The luminescence properties of the polymer 1 were investigated in the solid state at room temperature.

Cerium-based porous coordination polymers with hierarchical superstructures: fabrication, formation mechanism and their thermal conversion to hierarchical CeO2

2015 ◽  
Vol 2 (6) ◽  
pp. 567-575 ◽  
Author(s):  
Yong-Xia Zhao ◽  
Zhi-Wen Nie ◽  
Meng-Meng Shi ◽  
Cheng-Hui Zeng ◽  
Yuan Li ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Formation Mechanism ◽  
Coordination Polymers ◽  
Three Dimensional ◽  
Hierarchical Structures ◽  
Thermal Conversion ◽  
Porous Coordination Polymers ◽  
Polymer Precursors ◽  
Porous Coordination Polymer

Novel three-dimensional (3D) ceria hierarchical structures have been prepared via a thermolysis of the corresponding porous coordination polymer precursors.

A novel pillared-layer-type porous coordination polymer featuring three-dimensional pore system and high methane storage capacity

2016 ◽  
Vol 59 (8) ◽  
pp. 970-974 ◽  
Author(s):  
Jiao-Min Lin ◽  
Chun-Ting He ◽  
Pei-Qin Liao ◽  
Dong-Dong Zhou ◽  
Jie-Peng Zhang ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Storage Capacity ◽  
Three Dimensional ◽  
Methane Storage ◽  
Pore System ◽  
Porous Coordination Polymer

[Ni3(cit)2(pyz)(H2O)4](H2O)4: A New Three-dimensional Porous Coordination Polymer with a Pillared Layer Structure

2004 ◽  
Vol 33 (11) ◽  
pp. 1514-1515 ◽  
Author(s):  
Ting Yu ◽  
Yunqi Tian ◽  
Zhenxia Chen ◽  
Jinxi Chen ◽  
Linhong Weng ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Layer Structure ◽  
Three Dimensional ◽  
Porous Coordination Polymer
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