Three-Dimensional Robust Porous Coordination Polymer with Schiff Base Site on the Pore Wall: Synthesis, Single-Crystal-to-Single-Crystal Reversibility, and Selective CO2Adsorption

2011 ◽  
Vol 11 (9) ◽  
pp. 3905-3911 ◽  
Author(s):  
Rajdip Dey ◽  
Ritesh Haldar ◽  
Tapas Kumar Maji ◽  
Debajyoti Ghoshal
Keyword(s):  
Schiff Base ◽  
Coordination Polymer ◽  
Single Crystal ◽  
Three Dimensional ◽  
Pore Wall ◽  
Base Site ◽  
Porous Coordination Polymer

scholarly journals Gas Adsorption, Magnetism, and Single-Crystal to Single-Crystal Transformation Studies of a Three-Dimensional Mn(II) Porous Coordination Polymer

2014 ◽  
Vol 14 (11) ◽  
pp. 5585-5592 ◽  
Author(s):  
Rashmi A. Agarwal ◽  
Soumya Mukherjee ◽  
E. Carolina Sañudo ◽  
Sujit K. Ghosh ◽  
Parimal K. Bharadwaj
Keyword(s):  
Coordination Polymer ◽  
Single Crystal ◽  
Gas Adsorption ◽  
Three Dimensional ◽  
Crystal Transformation ◽  
Porous Coordination Polymer

scholarly journals catena-Poly[[(2-{[2-(dimethylammonio)ethyl]iminomethyl}pyridine-κ2N,N′)bis(thiocyanato-κN)manganese(II)]-μ-thiocyanato-κ2N:S]

2012 ◽  
Vol 68 (8) ◽  
pp. m1131-m1131
Author(s):  
Jun Wang ◽  
Wubiao Zhu ◽  
Jichang Li
Keyword(s):  
Schiff Base ◽  
Coordination Polymer ◽  
Hydrogen Bonds ◽  
Three Dimensional ◽  
Supramolecular Network ◽  
One Dimensional ◽  
Distorted Octahedral ◽  
Title One

In the title one-dimensional coordination polymer, [Mn(NCS)3(C10H16N3)]n, the MnIIatom is coordinated by anN,N′-bidentate Schiff base and four thiocyanate ligands in a distorted octahedral N5S geometry. Bridging thiocyanate ligands interconnect adjacent [Mn(NCS)2(C10H16N3)] units, giving rise to helical chains extending along thebaxis. The chains are further linked through N—H...S hydrogen bonds, leading to a three-dimensional supramolecular network.

Expanding uranyl dicyanoaurate coordination polymers into the second and third dimensions

2020 ◽  
Vol 98 (7) ◽  
pp. 365-372
Author(s):  
Matthew L. Brown ◽  
Daniel B. Leznoff
Keyword(s):  
Coordination Polymer ◽  
Single Crystal ◽  
Coordination Polymers ◽  
Solvothermal Synthesis ◽  
Linear Chain ◽  
Three Dimensional ◽  
Synthesis And Characterization ◽  
Crystal Transformation ◽  
System A

The solvothermal synthesis and characterization of a three-dimensional, interpenetrated uranyl dicyanoaurate coordination polymer, K2(UO2)2(UO2)2(Au(CN)2)2(O)2(NO3)4, from UO2(NO3)2·6H2O and KAu(CN)2 is described. The structure contains a three-dimensional (3D) lattice of planar tetranuclear uranyl–oxo–nitrate clusters connected by dicyanoaurate linkers, with the rotation of the clusters providing the increased dimensionality. The material undergoes a reversible single-crystal to single-crystal transformation on exposure to water vapour, which is taken up in the channels of the 3D system. A second uranyl dicyanoaurate coordination polymer of the form [UO2(DMSO)3(H2O)(Au(CN)2)][Au(CN)2] was structurally characterized as a linear chain of dicyanoaurate units connected by gold–gold bonds with pendant uranyl–water–DMSO adducts that are hydrogen bonded into a two-dimensional sheet. Both materials exhibit emission arising from both the uranyl moiety and the gold(I) centre and represent the first multidimensional uranyl–dicyanoaurate coordination polymers.

A Three-Dimensional Silver(I) Framework Assembled from Nitrilotriacetate

2005 ◽  
Vol 58 (2) ◽  
pp. 115 ◽  
Author(s):  
Chun-Long Chen ◽  
Qian Zhang ◽  
Ji-Jun Jiang ◽  
Qin Wang ◽  
Cheng-Yong Su
Keyword(s):  
Crystal Structure ◽  
Ir Spectroscopy ◽  
Coordination Polymer ◽  
Single Crystal ◽  
Elemental Analysis ◽  
Three Dimensional ◽  
Single Crystal Structure ◽  
X Ray Diffraction ◽  
X Ray ◽  
Coordination Numbers

The reaction of AgCF3CO2 with nitrilotriacetate (NTA) yields the three-dimensional silver(i) coordination polymer {Ag3[N(CH2COO)3]}n 1 which was characterized by means of elemental analysis and IR spectroscopy as well as X-ray diffraction. The single crystal structure shows that the NTA3– anions act as unusual heptadentate 13-coordination agents and the silver(i) atoms exhibit various coordination numbers in the range 3–6.

Sequential Single-Crystal-to-Single-Crystal Vapochromic inclusion in non-porous coordination polymer: Unravelling dynamic rearrangement for selective pyridine sensing

2021 ◽  
Author(s):  
Estefania Fernandez-Bartolomé ◽  
Esther Resines-Urien ◽  
Maria Murillo-Vidal ◽  
Lucia Piñeiro-Lopez ◽  
Jose Sanchez Costa
Keyword(s):  
Coordination Polymer ◽  
Single Crystal ◽  
Porous Materials ◽  
Metal Organic Frameworks ◽  
Covalent Organic Frameworks ◽  
Potential Applications ◽  
Metal Organic ◽  
Porous Coordination Polymer

Alternative porous materials beyond zeolites, such as metal-organic frameworks (MOF) or covalent organic frameworks (COF), have provided a variety of materials with potential applications ranging from sensing to catalysis. However,...

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