Cerium-based porous coordination polymers with hierarchical superstructures: fabrication, formation mechanism and their thermal conversion to hierarchical CeO2

2015 ◽  
Vol 2 (6) ◽  
pp. 567-575 ◽  
Author(s):  
Yong-Xia Zhao ◽  
Zhi-Wen Nie ◽  
Meng-Meng Shi ◽  
Cheng-Hui Zeng ◽  
Yuan Li ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Formation Mechanism ◽  
Coordination Polymers ◽  
Three Dimensional ◽  
Hierarchical Structures ◽  
Thermal Conversion ◽  
Porous Coordination Polymers ◽  
Polymer Precursors ◽  
Porous Coordination Polymer

Novel three-dimensional (3D) ceria hierarchical structures have been prepared via a thermolysis of the corresponding porous coordination polymer precursors.

scholarly journals Soft 2D Layer Porous Coordination Polymers with 1,2-Di(4-pyridyl)ethane

2013 ◽  
Vol 66 (4) ◽  
pp. 464 ◽  
Author(s):  
Keisuke Kishida ◽  
Satoshi Horike ◽  
Kanokwan Kongpatpanich ◽  
Susumu Kitagawa
Keyword(s):  
Coordination Polymer ◽  
Crystal Structures ◽  
Coordination Polymers ◽  
Adsorption Isotherms ◽  
Gas Adsorption ◽  
Porous Structures ◽  
Porous Coordination Polymers ◽  
Substituent Group ◽  
Layer Structures ◽  
Porous Coordination Polymer

Porous coordination polymer compounds consisting of Zn2+, 1,2-di(4-pyridyl)ethane, and dicarboxylates were synthesised and their crystal structures were determined. These are doubly interpenetrated 2D layer structures, and the flexibility of porous structures is dependent on the substituent group of the dicarboxylate. From gas adsorption studies, distinct adsorption isotherms were observed for CO2, CH4, C2H4, and C2H6 at 195 K and 273 K, respectively.

scholarly journals Al-Based porous coordination polymer derived nanoporous carbon for immobilization of glucose oxidase and its application in glucose/O2 biofuel cell and biosensor

RSC Advances ◽  
2017 ◽  
Vol 7 (20) ◽  
pp. 11872-11879 ◽  
Author(s):  
Zepeng Kang ◽  
Kailong Jiao ◽  
Ruiyun Peng ◽  
Zongqian Hu ◽  
Shuqiang Jiao
Keyword(s):  
Coordination Polymer ◽  
Glucose Oxidase ◽  
Coordination Polymers ◽  
Nanoporous Carbon ◽  
Biofuel Cell ◽  
Porous Coordination Polymers ◽  
Porous Coordination Polymer

Herein, we report the first example of using the Al-based porous coordination polymers (Al-PCP) as a template for preparation of nanoporous carbon through a two-step carbonized method.

Enhancement of guest-responsivity by mesocrystallization of porous coordination polymers

2017 ◽  
Vol 5 (15) ◽  
pp. 3706-3713 ◽  
Author(s):  
Akio Mishima ◽  
Tomomi Koshiyama ◽  
Jose A. Real ◽  
Masaaki Ohba
Keyword(s):  
Coordination Polymer ◽  
Spin State ◽  
Coordination Polymers ◽  
Aqueous Suspension ◽  
State Change ◽  
Porous Coordination Polymers ◽  
Porous Coordination Polymer

Guest-responsivity accompanying spin-state change of a porous coordination polymer was enhanced by mesocrystallization in both solid and aqueous suspension states.

Mesoporous Co3O4@carbon composites derived from microporous cobalt-based porous coordination polymers for enhanced electrochemical properties in supercapacitors

RSC Advances ◽  
2016 ◽  
Vol 6 (22) ◽  
pp. 18465-18470 ◽  
Author(s):  
Shuang Wang ◽  
Ting Wang ◽  
Ying Shi ◽  
Guang Liu ◽  
Jinping Li
Keyword(s):  
Coordination Polymer ◽  
Electrochemical Properties ◽  
Coordination Polymers ◽  
Carbon Composites ◽  
Porous Coordination Polymers ◽  
One Step ◽  
Porous Coordination Polymer

In this work, mesoporous Co3O4@carbon composites were prepared through a simple, one-step, carbonization of microporous cobalt-based porous coordination polymer ZSA-1.

Cobalt oxide 2D nano-assemblies from infinite coordination polymer precursors mediated by a multidentate pyridyl ligand

2016 ◽  
Vol 45 (18) ◽  
pp. 7866-7874 ◽  
Author(s):  
Guo-Rong Li ◽  
Chen-Chao Xie ◽  
Zhu-Rui Shen ◽  
Ze Chang ◽  
Xian-He Bu
Keyword(s):  
Coordination Polymer ◽  
Cobalt Oxide ◽  
Coordination Polymers ◽  
Polymer Precursors ◽  
2D Nanomaterials ◽  
Pyridyl Ligand

This work offered a successful example of the fabrication of cobalt oxide 2D nanomaterials utilizing infinite coordination polymers with a well-defined morphology as precursors.

Expanding uranyl dicyanoaurate coordination polymers into the second and third dimensions

2020 ◽  
Vol 98 (7) ◽  
pp. 365-372
Author(s):  
Matthew L. Brown ◽  
Daniel B. Leznoff
Keyword(s):  
Coordination Polymer ◽  
Single Crystal ◽  
Coordination Polymers ◽  
Solvothermal Synthesis ◽  
Linear Chain ◽  
Three Dimensional ◽  
Synthesis And Characterization ◽  
Crystal Transformation ◽  
System A

The solvothermal synthesis and characterization of a three-dimensional, interpenetrated uranyl dicyanoaurate coordination polymer, K2(UO2)2(UO2)2(Au(CN)2)2(O)2(NO3)4, from UO2(NO3)2·6H2O and KAu(CN)2 is described. The structure contains a three-dimensional (3D) lattice of planar tetranuclear uranyl–oxo–nitrate clusters connected by dicyanoaurate linkers, with the rotation of the clusters providing the increased dimensionality. The material undergoes a reversible single-crystal to single-crystal transformation on exposure to water vapour, which is taken up in the channels of the 3D system. A second uranyl dicyanoaurate coordination polymer of the form [UO2(DMSO)3(H2O)(Au(CN)2)][Au(CN)2] was structurally characterized as a linear chain of dicyanoaurate units connected by gold–gold bonds with pendant uranyl–water–DMSO adducts that are hydrogen bonded into a two-dimensional sheet. Both materials exhibit emission arising from both the uranyl moiety and the gold(I) centre and represent the first multidimensional uranyl–dicyanoaurate coordination polymers.

Hybrid materials based on transition metal–BTC–benzimidazole: solvent assisted crystallographic and structural switching

CrystEngComm ◽  
2018 ◽  
Vol 20 (41) ◽  
pp. 6602-6612 ◽  
Author(s):  
Ranjay K. Tiwari ◽  
J. N. Behera
Keyword(s):  
Crystal Structure ◽  
Transition Metal ◽  
Structure Analysis ◽  
Hybrid Materials ◽  
Coordination Polymers ◽  
Three Dimensional ◽  
Hierarchical Structures ◽  
Crystal Structure Analysis ◽  
Solvothermal Condition ◽  
1D Chain

Five transition metal–BTC–BIm based coordination polymers with hierarchical structures were synthesized under hydro/solvothermal condition. Crystal structure analysis of the compounds showed that 1 forms a 1D chain, 2 and 3 have 2D layers, while 4 and 5 have three-dimensional architectures.

Solid-state thermal conversion of a nanoporous metal–organic framework to a nonporous coordination polymer

RSC Advances ◽  
2015 ◽  
Vol 5 (63) ◽  
pp. 50778-50782 ◽  
Author(s):  
Fatemeh Shahangi Shirazi ◽  
Kamran Akhbari
Keyword(s):  
Solid State ◽  
Thermal Treatment ◽  
Coordination Polymer ◽  
Metal Organic Framework ◽  
Three Dimensional ◽  
Thermal Conversion ◽  
Grid Network ◽  
Nanoporous Metal ◽  
Metal Organic ◽  
Organic Framework

A nanoporous metal–organic framework with pillared 2D square-grid network, converts to a nonporous three-dimensional coordination polymer of upon thermal treatment at 350 °C.

Three-dimensional iron(ii) porous coordination polymer exhibiting carbon dioxide-dependent spin crossover

2018 ◽  
Vol 54 (34) ◽  
pp. 4262-4265 ◽  
Author(s):  
Jong Won Shin ◽  
Ah Rim Jeong ◽  
Sungeun Jeoung ◽  
Hoi Ri Moon ◽  
Yuki Komatsumaru ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Coordination Polymer ◽  
Spin Crossover ◽  
Three Dimensional ◽  
Porous Coordination Polymer

A three-dimensional iron(ii) porous coordination polymer has been observed spin crossover behaviours through the sorption of H2O and CO2, respectively.

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