Electrolyte-Solvent Interaction. V. Tetrabutylammonium Bromide in Ethanol-Carbon Tetrachloride Mixtures

1954 ◽  
Vol 76 (23) ◽  
pp. 5902-5904 ◽  
Author(s):  
Hussein Sadek ◽  
Raymond M. Fuoss
Keyword(s):  
Carbon Tetrachloride ◽  
Tetrabutylammonium Bromide ◽  
Solvent Interaction

Conductivity and Viscosity of the Tetrabutylammonium Bromide – Carbon Tetrachloride System

1972 ◽  
Vol 50 (10) ◽  
pp. 1600-1603 ◽  
Author(s):  
K. F. Denning ◽  
James A. Plambeck
Keyword(s):  
Carbon Tetrachloride ◽  
Temperature Dependence ◽  
Tetrabutylammonium Bromide ◽  
Viscosity Measurements ◽  
Ratio Range

Conductivity and viscosity measurements have been made on tetra-n-butylammonium bromide – carbon tetrachloride solutions for the mole ratio range 1:40 to 1:2 at temperatures from 25 to 40 °C. At any individual concentration, both conductivity and viscosity follow an Arrhenius type temperature dependence. Viscosity increases exponentially with tetrabutylammonium bromide concentration while conductivity has a maximum at approximately 1:5 mole ratio R4NBr–CCl4.

Infrared Study of Some Organophosphorus Esters in Carbon Tetrachloride and/or Chloroform 1% Solutions

1992 ◽  
Vol 46 (10) ◽  
pp. 1564-1574 ◽  
Author(s):  
R. A. Nyquist ◽  
C. W. Puehl
Keyword(s):  
Carbon Tetrachloride ◽  
Functional Groups ◽  
Solvent System ◽  
Infrared Study ◽  
Solvent Interaction ◽  
Rotational Isomers ◽  
Solvent Systems ◽  
Solute Solvent Interaction ◽  
Organophosphorus Esters

Solvent systems such as CHCl3/CCl4 or CDCl3/CCl4 are useful in showing that organophosphorus esters do exist as rotational isomers in solution. The functional groups such as P=O and POR in organophosphorus esters are the sites of solute/solvent interaction, since their group frequencies are more affected than group frequencies arising primarily within the R group of the organophosphorus esters. This study also shows that different complexes are formed between the solute and solvent systems as well as within the solvent system as the mole % CHCl3/CCl4 or CDCl3/CCl4 increases.

Dielectric Polarisation of Pyridine

1975 ◽  
Vol 30 (7-8) ◽  
pp. 587-590
Author(s):  
V. K. Joshi
Keyword(s):  
Dipole Moment ◽  
Carbon Tetrachloride ◽  
Polar Solvents ◽  
Solvent Interaction ◽  
Solute Solvent Interaction ◽  
The Moment ◽  
Dielectric Polarisation ◽  
Influence Of Solvent

This paper deals with the study of dielectric polarisation of pyridine at 35°C in four non polar solvents namely benzene, carbon tetrachloride, dioxan and cyclohexane. The results have been discussed to understand the merits of PALIT equation. It is observed that the moment value μs obtained by this is fairly comparable with that calculated by the method of HALVERSTADT and KUMLER2. The order of apparent dipole moment has been discussed in terms of influence of solvent and solute-solvent interaction as well.

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