Electrolyte-Solvent Interaction. IX. Tetra-alkylammonium Tetraphenylborides in Acetonitrile-Carbon Tetrachloride Mixtures at 25°

1960 ◽  
Vol 82 (21) ◽  
pp. 5585-5588 ◽  
Author(s):  
Donald S. Berns ◽  
Raymond M. Fuoss
1992 ◽  
Vol 46 (10) ◽  
pp. 1564-1574 ◽  
Author(s):  
R. A. Nyquist ◽  
C. W. Puehl

Solvent systems such as CHCl3/CCl4 or CDCl3/CCl4 are useful in showing that organophosphorus esters do exist as rotational isomers in solution. The functional groups such as P=O and POR in organophosphorus esters are the sites of solute/solvent interaction, since their group frequencies are more affected than group frequencies arising primarily within the R group of the organophosphorus esters. This study also shows that different complexes are formed between the solute and solvent systems as well as within the solvent system as the mole % CHCl3/CCl4 or CDCl3/CCl4 increases.


1975 ◽  
Vol 30 (7-8) ◽  
pp. 587-590
Author(s):  
V. K. Joshi

This paper deals with the study of dielectric polarisation of pyridine at 35°C in four non polar solvents namely benzene, carbon tetrachloride, dioxan and cyclohexane. The results have been discussed to understand the merits of PALIT equation. It is observed that the moment value μs obtained by this is fairly comparable with that calculated by the method of HALVERSTADT and KUMLER2. The order of apparent dipole moment has been discussed in terms of influence of solvent and solute-solvent interaction as well.


2000 ◽  
Vol 87 (5) ◽  
pp. 229-233 ◽  
Author(s):  
Beatrice Arosio ◽  
Nicoletta Gagliano ◽  
Lorena Maria Pia Fusaro ◽  
Luciano Parmeggiani ◽  
Jacopo Tagliabue ◽  
...  

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