scholarly journals Process Chemistry and Design Alternatives for Converting Dilute Acetic Acid to Esters in Reactive Distillation

2006 ◽  
Vol 45 (5) ◽  
pp. 1722-1733 ◽  
Author(s):  
Wan-Jen Hung ◽  
I-Kuan Lai ◽  
Yi-Wei Chen ◽  
Shih-Bo Hung ◽  
Hsiao-Ping Huang ◽  
...  
2008 ◽  
Vol 25 (6) ◽  
pp. 1252-1266 ◽  
Author(s):  
Amornchai Arpornwichanop ◽  
Chantarawadee Wiwittanaporn ◽  
Suthida Authayanun ◽  
Suttichai Assabumrungrat

2002 ◽  
Vol 41 (13) ◽  
pp. 3233-3246 ◽  
Author(s):  
Sheng-Feng Chiang ◽  
Chien-Lin Kuo ◽  
Cheng-Ching Yu ◽  
David S. H. Wong

Author(s):  
Abdulwahab Giwa ◽  
Saidat Olanipekun Giwa

This work has been carried out to demonstrate the application of a process simulator known as CHEMCAD to the modelling and the simulation of a reactive distillation process used for the production of n-butyl acetate, with water as the by-product, from the esterification reaction between acetic acid and n-butanol. The esterification reaction, which is generally an equilibrium type, was modelled as two kinetic reaction types in the reaction section of the column used, which had 17 stages with the middle section (stages 6 – 12) being the reaction section. A reflux ratio of 3 and reboiler duty of 78 kJ/min as well as 30 mL/min of each of the reactants with 99% molar purity were used for the simulation of the column. The results obtained revealed that the developed model was a valid one because there was a very good agreement between the results and the theoretical knowledge of a distillation column based on the fact that the desired (which was the heavy) product (n-butyl acetate) was found to have the highest mole fraction in the bottom section of the column while the by-product of the process (water) was discovered to have a mole fraction higher than that of n-butyl acetate in the top (condenser) section of the column. Therefore, CHEMCAD has been applied to the steady-state simulation of the reactive distillation process used for the production of n-butyl acetate from the esterification reaction of acetic acid and n-butanol successfully.


2011 ◽  
Vol 50 (15) ◽  
pp. 9209-9220 ◽  
Author(s):  
Alvaro Orjuela ◽  
Aspi Kolah ◽  
Carl T. Lira ◽  
Dennis J. Miller

2014 ◽  
Vol 52 ◽  
pp. 559-566 ◽  
Author(s):  
C. Prapainainar ◽  
C. Yotkamchonkun ◽  
S. Panjatharakul ◽  
T. Ratana ◽  
S. Seeyangnok ◽  
...  

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