scholarly journals Gas Adsorption, Magnetism, and Single-Crystal to Single-Crystal Transformation Studies of a Three-Dimensional Mn(II) Porous Coordination Polymer

2014 ◽  
Vol 14 (11) ◽  
pp. 5585-5592 ◽  
Author(s):  
Rashmi A. Agarwal ◽  
Soumya Mukherjee ◽  
E. Carolina Sañudo ◽  
Sujit K. Ghosh ◽  
Parimal K. Bharadwaj
Keyword(s):  
Coordination Polymer ◽  
Single Crystal ◽  
Gas Adsorption ◽  
Three Dimensional ◽  
Crystal Transformation ◽  
Porous Coordination Polymer

Expanding uranyl dicyanoaurate coordination polymers into the second and third dimensions

2020 ◽  
Vol 98 (7) ◽  
pp. 365-372
Author(s):  
Matthew L. Brown ◽  
Daniel B. Leznoff
Keyword(s):  
Coordination Polymer ◽  
Single Crystal ◽  
Coordination Polymers ◽  
Solvothermal Synthesis ◽  
Linear Chain ◽  
Three Dimensional ◽  
Synthesis And Characterization ◽  
Crystal Transformation ◽  
System A

The solvothermal synthesis and characterization of a three-dimensional, interpenetrated uranyl dicyanoaurate coordination polymer, K2(UO2)2(UO2)2(Au(CN)2)2(O)2(NO3)4, from UO2(NO3)2·6H2O and KAu(CN)2 is described. The structure contains a three-dimensional (3D) lattice of planar tetranuclear uranyl–oxo–nitrate clusters connected by dicyanoaurate linkers, with the rotation of the clusters providing the increased dimensionality. The material undergoes a reversible single-crystal to single-crystal transformation on exposure to water vapour, which is taken up in the channels of the 3D system. A second uranyl dicyanoaurate coordination polymer of the form [UO2(DMSO)3(H2O)(Au(CN)2)][Au(CN)2] was structurally characterized as a linear chain of dicyanoaurate units connected by gold–gold bonds with pendant uranyl–water–DMSO adducts that are hydrogen bonded into a two-dimensional sheet. Both materials exhibit emission arising from both the uranyl moiety and the gold(I) centre and represent the first multidimensional uranyl–dicyanoaurate coordination polymers.

Double-step CO2 sorption and guest-induced single-crystal-to-single-crystal transformation in a flexible porous framework

2015 ◽  
Vol 44 (22) ◽  
pp. 10141-10145 ◽  
Author(s):  
Wei-Ping Wu ◽  
Zhi-Sen Li ◽  
Bo Liu ◽  
Ping Liu ◽  
Zheng-Ping Xi ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Single Crystal ◽  
Room Temperature ◽  
Double Step ◽  
Co2 Sorption ◽  
Porous Framework ◽  
Crystal Transformation ◽  
Porous Coordination Polymer

A new 2D highly flexible and breathing porous coordination polymer has been synthesized, which exhibits selective and double-step hysteretic adsorption for CO2, and shows a single-crystal-to-single-crystal transformation induced by CH2Cl2 at room temperature.

Solvent-Induced Single Crystal–Single Crystal Transformation of an Interpenetrated Three-Dimensional Copper Triazole Catalytic Framework

2016 ◽  
Vol 55 (9) ◽  
pp. 4069-4071 ◽  
Author(s):  
Ying Wang ◽  
Shan-Shan Meng ◽  
Peng-Xiang Lin ◽  
Yi-Wei Xiao ◽  
Qing-Qing Ma ◽  
...  
Keyword(s):  
Single Crystal ◽  
Three Dimensional ◽  
Crystal Transformation

Single-crystal to single-crystal transformation from a 1-D chain-like structure to a 2-D coordination polymer on heating

CrystEngComm ◽  
2013 ◽  
Vol 15 (28) ◽  
pp. 5606 ◽  
Author(s):  
Xu-Jia Hong ◽  
Ming-Fang Wang ◽  
Hong-Guang Jin ◽  
Qing-Guang Zhan ◽  
Yi-Ting Liu ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Single Crystal ◽  
Crystal Transformation

Single-Crystal-to-Single-Crystal Transformation of Hydrogen-Bonded Triple-Stranded Ladder Coordination Polymer via Photodimerization Reaction

2019 ◽  
Vol 58 (15) ◽  
pp. 10167-10173 ◽  
Author(s):  
Hasan Ali Al-Mohsin ◽  
Ammar AlMousa ◽  
Sulayman A. Oladepo ◽  
Almaz S. Jalilov ◽  
Mohammed Fettouhi ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Single Crystal ◽  
Crystal Transformation ◽  
Hydrogen Bonded
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