Sequestering Hydrated Fluoride in a Three-Dimensional Non-Interpenetrated Octahedral Coordination Polymer via a Single-Crystal-to-Single-Crystal Fashion

2012 ◽  
Vol 12 (7) ◽  
pp. 3369-3373 ◽  
Author(s):  
N. N. Adarsh ◽  
Axelle Grélard ◽  
Erick J. Dufourc ◽  
Parthasarathi Dastidar
Keyword(s):  
Coordination Polymer ◽  
Single Crystal ◽  
Three Dimensional ◽  
Octahedral Coordination

catena-Poly[[[2-(2-pyridyl)-1H-benzimidazole]cobalt(II)]-μ-benzene-1,4-dicarboxylato]

2007 ◽  
Vol 63 (11) ◽  
pp. m2726-m2726 ◽  
Author(s):  
Chang-Kun Xia ◽  
Wen Wu ◽  
Qiu-Yun Chen ◽  
Ji-Min Xie
Keyword(s):  
Coordination Polymer ◽  
Hydrogen Bonds ◽  
Benzene Ring ◽  
Three Dimensional ◽  
Chain Structure ◽  
Octahedral Coordination ◽  
Pyridyl Ring ◽  
Zigzag Chain ◽  
Coordination Environment ◽  
Π Interactions

In the title coordination polymer, [Co(C8H4O4)(C12H9N3)] n , the CoII atom exists in an octahedral coordination environment formed by four carboxylate O atoms from two benzene-1,4-dicarboxylate ligands, and two N atoms from the 2-(2-pyridyl)benzimidazole ligand. Bridging by the benzene-1,4-dicarboxylate ligand leads to a zigzag chain structure, and intermolecular N—H...O hydrogen bonds as well as π–π interactions between the pyridyl ring and the benzene ring of the 2-(2-pyridyl)benzimidazole ligand (centroid–centroid distances = 3.678 and 3.697 Å) link the chains into a three-dimensional framework.

Expanding uranyl dicyanoaurate coordination polymers into the second and third dimensions

2020 ◽  
Vol 98 (7) ◽  
pp. 365-372
Author(s):  
Matthew L. Brown ◽  
Daniel B. Leznoff
Keyword(s):  
Coordination Polymer ◽  
Single Crystal ◽  
Coordination Polymers ◽  
Solvothermal Synthesis ◽  
Linear Chain ◽  
Three Dimensional ◽  
Synthesis And Characterization ◽  
Crystal Transformation ◽  
System A

The solvothermal synthesis and characterization of a three-dimensional, interpenetrated uranyl dicyanoaurate coordination polymer, K2(UO2)2(UO2)2(Au(CN)2)2(O)2(NO3)4, from UO2(NO3)2·6H2O and KAu(CN)2 is described. The structure contains a three-dimensional (3D) lattice of planar tetranuclear uranyl–oxo–nitrate clusters connected by dicyanoaurate linkers, with the rotation of the clusters providing the increased dimensionality. The material undergoes a reversible single-crystal to single-crystal transformation on exposure to water vapour, which is taken up in the channels of the 3D system. A second uranyl dicyanoaurate coordination polymer of the form [UO2(DMSO)3(H2O)(Au(CN)2)][Au(CN)2] was structurally characterized as a linear chain of dicyanoaurate units connected by gold–gold bonds with pendant uranyl–water–DMSO adducts that are hydrogen bonded into a two-dimensional sheet. Both materials exhibit emission arising from both the uranyl moiety and the gold(I) centre and represent the first multidimensional uranyl–dicyanoaurate coordination polymers.

A Three-Dimensional Silver(I) Framework Assembled from Nitrilotriacetate

2005 ◽  
Vol 58 (2) ◽  
pp. 115 ◽  
Author(s):  
Chun-Long Chen ◽  
Qian Zhang ◽  
Ji-Jun Jiang ◽  
Qin Wang ◽  
Cheng-Yong Su
Keyword(s):  
Crystal Structure ◽  
Ir Spectroscopy ◽  
Coordination Polymer ◽  
Single Crystal ◽  
Elemental Analysis ◽  
Three Dimensional ◽  
Single Crystal Structure ◽  
X Ray Diffraction ◽  
X Ray ◽  
Coordination Numbers

The reaction of AgCF3CO2 with nitrilotriacetate (NTA) yields the three-dimensional silver(i) coordination polymer {Ag3[N(CH2COO)3]}n 1 which was characterized by means of elemental analysis and IR spectroscopy as well as X-ray diffraction. The single crystal structure shows that the NTA3– anions act as unusual heptadentate 13-coordination agents and the silver(i) atoms exhibit various coordination numbers in the range 3–6.

A new CdII coordination polymer with a self-penetrating architecture induced by the molecular conformation of a rigid bithiophene ligand

2018 ◽  
Vol 74 (2) ◽  
pp. 218-223 ◽  
Author(s):  
Ning-Ning Ji ◽  
Zhi-Qiang Shi ◽  
Hai-Liang Hu
Keyword(s):  
Coordination Polymer ◽  
Single Crystal ◽  
Coordination Polymers ◽  
Molecular Conformation ◽  
Topological Analysis ◽  
Three Dimensional ◽  
X Ray Diffraction ◽  
X Ray ◽  
Design And Synthesis ◽  
Mixed Ligands

The design and synthesis of coordination polymers with a self-penetrating architecture has attracted much interest not only due to their interesting structures but also due to their potential applications. 5,5′-Bis(pyridin-4-yl)-2,2′-bithiophene (bpbp), as a conjugated bithiophene ligand, can exhibit trans and cis conformations and this can lead to the construction of a self-penetrating architecture. In addition, the semi-rigid ancillary ligand 4,4′-oxybis(benzoic acid) (H2oba) can adopt different coordination modes, resulting in coordination polymers with high-dimensional skeletons. A new CdII coordination polymer based on mixed ligands, namely poly[diaquapentakis[μ-5,5′-bis(pyridin-4-yl)-2,2′-bithiophene-κ2 N:N′]bis(nitrato-κ2 O,O′)tetrakis(μ3-4,4′-oxydibenzoato)-κ10 O:O,O′:O′′,O′′′;κ6 O:O′:O′′-pentacadmium(II)], [Cd5(C14H14O5)4(NO3)2(C18H12N2S2)5(H2O)2] n , (I), has been synthesized under solvothermal conditions and characterized by single-crystal X-ray diffraction, IR spectroscopy and elemental analysis. Single-crystal X-ray diffraction indicates that there are three crystallographically independent CdII cations, three bpbp ligands, two deprotonated oba2− ligands, one nitrate ligand and one coordinated water molecule in the asymmetric unit. One CdII centre is seven-coordinated, exhibiting a distorted {CdN2O5} pentagonal bipyramidal geometry, while the other two Cd centres are both six-coordinated, showing slightly distorted {CdN2O4} octahedral geometries. The most interesting feature is the co-existence of trans and cis conformations in a single net, allowing structural interpenetration via self-threading and yet the expected self-penetrating structure was obtained. Topological analysis shows that the whole three-dimensional framework can be classified as a 3-nodal (4,6,6)-c net with Schläfli symbol {613.82}2{66}, which is a new topology. Furthermore, the luminescence properties of (I) were examined in the solid state at room temperature.

A new three-dimensional cobalt(II) coordination polymer based on V-shaped 3,4′-oxydibenzoate: synthesis, crystal structure and magnetic properties

2019 ◽  
Vol 75 (7) ◽  
pp. 990-995 ◽  
Author(s):  
Wenlong Lan ◽  
Zhen Zhou ◽  
Fu-Chao Jia ◽  
Xiaoyun Hao ◽  
Yong Dou ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Single Crystal ◽  
Self Assembly ◽  
Three Dimensional ◽  
Bidentate Ligand ◽  
Antiferromagnetic Coupling ◽  
X Ray Diffraction ◽  
X Ray ◽  
X Ray Crystallography ◽  
Monodentate Ligands

A new coordination polymer (CP), namely poly[(μ-4,4′-bipyridine)(μ3-3,4′-oxydibenzoato)cobalt(II)], [Co(C14H8O5)(C10H8N2)] n or [Co(3,4′-obb)(4,4′-bipy)] n (1), was prepared by the self-assembly of Co(NO3)2·6H2O with the rarely used 3,4′-oxydibenzoic acid (3,4′-obbH2) ligand and 4,4′-bipyridine (4,4′-bipy) under solvothermal conditions, and has been structurally characterized by elemental analysis, IR spectroscopy, single-crystal X-ray crystallography and powder X-ray diffraction (PXRD). Single-crystal X-ray diffraction reveals that each CoII ion is six-coordinated by four O atoms from three 3,4′-obb2− ligands, of which two function as monodentate ligands and the other as a bidentate ligand, and by two N atoms from bridging 4,4′-bipy ligands, thereby forming a distorted octahedral CoN2O4 coordination geometry. Adjacent crystallographically equivalent CoII ions are bridged by the O atoms of 3,4′-obb2− ligands, affording an eight-membered Co2O4C2 ring which is further extended into a two-dimensional [Co(3,4′-obb)] n sheet along the ab plane via 3,4′-obb2− functioning as a bidentate bridging ligand. The planes are interlinked into a three-dimensional [Co(3,4′-obb)(4,4′-bipy)] n network by 4,4′-bipy ligands acting as pillars along the c axis. Magnetic investigations on CP 1 disclose an antiferromagnetic coupling within the dimeric Co2 unit and a metamagnetic behaviour at low temperature resulting from intermolecular π–π interactions between the parallel 4,4′-bipy ligands.

scholarly journals Gas Adsorption, Magnetism, and Single-Crystal to Single-Crystal Transformation Studies of a Three-Dimensional Mn(II) Porous Coordination Polymer

2014 ◽  
Vol 14 (11) ◽  
pp. 5585-5592 ◽  
Author(s):  
Rashmi A. Agarwal ◽  
Soumya Mukherjee ◽  
E. Carolina Sañudo ◽  
Sujit K. Ghosh ◽  
Parimal K. Bharadwaj
Keyword(s):  
Coordination Polymer ◽  
Single Crystal ◽  
Gas Adsorption ◽  
Three Dimensional ◽  
Crystal Transformation ◽  
Porous Coordination Polymer

scholarly journals Synthesis, Crystal Structure, and Luminescence Properties of a New Calcium(II) Coordination Polymer Based on L-Malic Acid

2013 ◽  
Vol 2013 ◽  
pp. 1-7
Author(s):  
Duraisamy Senthil Raja ◽  
Jheng-Hong Luo ◽  
Ting-Guang Chang ◽  
Sheng-Han Lo ◽  
Cheng-You Wu ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Coordination Polymer ◽  
Single Crystal ◽  
Malic Acid ◽  
Three Dimensional ◽  
Crystal Structure Analysis ◽  
X Ray Diffraction ◽  
X Ray ◽  
Complex Forms ◽  
Very High

A new calcium coordination polymer [Ca(HL-MA)]n(H3L-MA = L-malic acid) has been solvothermally synthesized. The structure of the newly synthesized complex has been determined by single-crystal X-ray diffraction analysis and further characterized by elemental analysis, reflectance UV-Vis & IR spectra, powder X-ray diffraction (PXRD), and thermogravimetric analysis (TGA). The single crystal structure analysis showed that the complex forms three-dimensional framework. The new Ca(II) complex has displayed very high thermal stability which was inferred from TGA and PXRD results. As far as the optical property of the new complex is concerned, the complex emitted its own characteristic sensitized luminescence.

A three-dimensional cadmium(II) coordination polymer: poly[[[μ-4,4′-(propane-1,3-diyl)dipyridine-κ2N:N](μ-3,3′-thiodipropionato-κ3O,O′:O)cadmium(II)] monohydrate]

2014 ◽  
Vol 70 (7) ◽  
pp. 712-714
Author(s):  
Xiao-Min Hao ◽  
Gang Chen ◽  
Chang-Sheng Gu ◽  
Ji-Wei Liu
Keyword(s):  
Coordination Polymer ◽  
Three Dimensional ◽  
Octahedral Coordination ◽  
Two Dimensional ◽  
One Dimensional ◽  
Distorted Octahedral Coordination ◽  
Dimensional Network ◽  
Distorted Octahedral

In the title coordination polymer, {[Cd(C6H8O4S)(C13H14N2)]·H2O}n, the CdIIatom displays a distorted octahedral coordination, formed by three carboxylate O atoms and one S atom from three different 3,3′-thiodipropionate ligands, and two N atoms from two different 4,4′-(propane-1,3-diyl)dipyridine ligands. The CdIIcentres are bridged through carboxylate O atoms of 3,3′-thiodipropionate ligands and through N atoms of 4,4′-(propane-1,3-diyl)dipyridine ligands to form two different one-dimensional chains, which intersect to form a two-dimensional layer. These two-dimensional layers are linked by S atoms of 3,3′-thiodipropionate ligands from adjacent layers to form a three-dimensional network.

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