Single-crystal to single-crystal transformation from a 1-D chain-like structure to a 2-D coordination polymer on heating

CrystEngComm ◽  
2013 ◽  
Vol 15 (28) ◽  
pp. 5606 ◽  
Author(s):  
Xu-Jia Hong ◽  
Ming-Fang Wang ◽  
Hong-Guang Jin ◽  
Qing-Guang Zhan ◽  
Yi-Ting Liu ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Single Crystal ◽  
Crystal Transformation

Single-Crystal-to-Single-Crystal Transformation of Hydrogen-Bonded Triple-Stranded Ladder Coordination Polymer via Photodimerization Reaction

2019 ◽  
Vol 58 (15) ◽  
pp. 10167-10173 ◽  
Author(s):  
Hasan Ali Al-Mohsin ◽  
Ammar AlMousa ◽  
Sulayman A. Oladepo ◽  
Almaz S. Jalilov ◽  
Mohammed Fettouhi ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Single Crystal ◽  
Crystal Transformation ◽  
Hydrogen Bonded

Expanding uranyl dicyanoaurate coordination polymers into the second and third dimensions

2020 ◽  
Vol 98 (7) ◽  
pp. 365-372
Author(s):  
Matthew L. Brown ◽  
Daniel B. Leznoff
Keyword(s):  
Coordination Polymer ◽  
Single Crystal ◽  
Coordination Polymers ◽  
Solvothermal Synthesis ◽  
Linear Chain ◽  
Three Dimensional ◽  
Synthesis And Characterization ◽  
Crystal Transformation ◽  
System A

The solvothermal synthesis and characterization of a three-dimensional, interpenetrated uranyl dicyanoaurate coordination polymer, K2(UO2)2(UO2)2(Au(CN)2)2(O)2(NO3)4, from UO2(NO3)2·6H2O and KAu(CN)2 is described. The structure contains a three-dimensional (3D) lattice of planar tetranuclear uranyl–oxo–nitrate clusters connected by dicyanoaurate linkers, with the rotation of the clusters providing the increased dimensionality. The material undergoes a reversible single-crystal to single-crystal transformation on exposure to water vapour, which is taken up in the channels of the 3D system. A second uranyl dicyanoaurate coordination polymer of the form [UO2(DMSO)3(H2O)(Au(CN)2)][Au(CN)2] was structurally characterized as a linear chain of dicyanoaurate units connected by gold–gold bonds with pendant uranyl–water–DMSO adducts that are hydrogen bonded into a two-dimensional sheet. Both materials exhibit emission arising from both the uranyl moiety and the gold(I) centre and represent the first multidimensional uranyl–dicyanoaurate coordination polymers.

Solvochromic and photodimerization behaviour of 1D coordination polymer via single-crystal-to-single-crystal transformation

2011 ◽  
Vol 47 (33) ◽  
pp. 9384 ◽  
Author(s):  
Yong-Cong Ou ◽  
Wen-Ting Liu ◽  
Jin-Yan Li ◽  
Gong-Guo Zhang ◽  
Jing Wang ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Single Crystal ◽  
Crystal Transformation ◽  
1D Coordination Polymer

Two scandium-based coordination polymers: rapid ultrasound-assisted synthesis, crystal transformation, and catalytic properties

CrystEngComm ◽  
2021 ◽  
Author(s):  
Rui Liu ◽  
Yansong Jiang ◽  
Yiran Gong ◽  
Yu Fu ◽  
Jieyu Shen ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Single Crystal ◽  
Coordination Polymers ◽  
Catalytic Properties ◽  
Ultrasound Waves ◽  
Catalytic Activities ◽  
Crystal Transformation ◽  
Ultrasound Assisted

Assisted by ultrasound waves, a Sc-based coordination polymer CP 1 was synthesized successfully. With 1 as the precursor, another stable CP 2 can be obtained by single-crystal to single-crystal transformation and 2 exhibited good catalytic activities.

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