Plasma etching as a diagnostic technique in silicon surface studies

1977 ◽  
Vol 12 (5) ◽  
pp. 1019-1027 ◽  
Author(s):  
D. P. Griffiths ◽  
S. H. Bradley
1986 ◽  
Vol 68 ◽  
Author(s):  
Patrice Geraghty ◽  
W. Lee Smith

AbstractA method is presented to nondestructively monitor damage in silicon caused by reactive-ion or plasma etching on actual product wafers or test wafers immediately following the etch step.Data is taken on product wafers by scanning the 1-micron laser probe spot across and along the bottom of RIE-etched trenches.The onset of silicon damage brings a marked increase to the thermal wave (TW) signal: as the RIE bias voltage was increased from -60 volts to -250 volts, the TW signal increased monotonically by 1230%.The effects of other RIE process parameters on the damage level were also measured.This study allowed the RIE process variables to be adjusted to minimize damage to the silicon surface.


1991 ◽  
Vol 30 (Part 1, No. 5) ◽  
pp. 1045-1049 ◽  
Author(s):  
Gen Washidzu ◽  
Tohru Hara ◽  
Jun Hiyoshi ◽  
Masami Sasaki ◽  
Yasuhiro Suzuki ◽  
...  

1973 ◽  
Vol 17 (3-4) ◽  
pp. 245-252 ◽  
Author(s):  
W. F. Van Der Weg ◽  
W. H. Kool ◽  
H. E. Roosendaal ◽  
F. W. Saris

NANO ◽  
2017 ◽  
Vol 12 (08) ◽  
pp. 1750099
Author(s):  
Junho Yoon ◽  
Jeongyun Lee ◽  
Won Jong Yoo

During plasma etching for fin patterning in the three-dimensional (3D) FinFET structure, the exposure of the Si surface to plasma with reactive ions can induce physical damages, resulting in the degradation of electrical properties of the device. In this study, we evaluated the damage with a measurable value by simulation and surface damage analyses using HR-TEM and RBS. As a result, the degree of the damaged layer was strongly dependent on the energy of the ions bombarding the Si substrate during plasma etching. The damage was quantified with the interface defect density measured by the charge pumping method. Plasma etching with high ion energy showed approximately one order of magnitude higher defect density than that with low ion energy and/or wet etching with no ion bombardment. We introduced Si soft treatment (with very low ion energy) to remove the damaged layer. The Si soft treatment was very effective to remove the damage on a highly damaged silicon surface. However, the Si soft treatment itself increased the number of defects for a low damage silicon surface.


1994 ◽  
Vol 339 ◽  
Author(s):  
J. M. Lannon ◽  
J. S. Gold ◽  
C. D. Stinespring

ABSTRACTStudies of diamond heteroepitaxy on silicon indicate that C-C surface species act as nucleation precursors. We have investigated the conversion of the Si(100) 2×1 surface to SiC using C2H4 to obtain an understanding of how C-C species may be formed and to determine the effect of an O-adlayer on enhancing or selecting the reaction channel which leads to these species. Under appropriate conditions, the interaction between C2H4 and the clean silicon surface yields both SiC and C-C species. The presence of an O-adlayer significantly reduces the activity of silicon and enhances the formation of sp2 and sp3 C-C species. These results provide key insights into diamond nucleation conditions in conventional growth processes.


1988 ◽  
Vol 128 ◽  
Author(s):  
K. Shenai ◽  
N. Lewis ◽  
C. A. Smith ◽  
B. J. Baliga

ABSTRACTWe report on the results obtained from a study conducted to understand the effect of reactive ion etching (RIE) of oxide films on the dopant diffusion in ion-implanted silicon. Thermally grown oxide films on silicon were plasma etched in a CHF3/CO2 plasma. The residual silicon surface damage created during plasma etching was removed by employing a low ion-bombardment, two-step surface plasma cleaning process. The samples with oxide films etched in a wet chemical etchant provided the control for evaluating the effect of the RIE process. The samples were implanted with boron and boron was activated under various conditions to form p-n junctions to obtain a range of boron doping profiles and junction depths. Some boron doped samples were implanted with arsenic to form a heavily doped n+ region at the silicon surface. The resulting doping profiles were analysed using spreading resistance profiling (SRP), four-point probe measurements, and secondary ion-mass spectrometry (SIMS) to understand the activation, diffusion, and precipitation of various dopants. Detailed transmission electron microscopy (TEM) analysis was used to study the microstructural effects. It was observed that plasma etching of the oxide films prior to the formation of boron diffused surface regions in silicon resulted in significant changes in boron diffusion. For low boron implant doses, plasma etched silicon surfaces resulted in retarded boron diffusion. For high boron implant doses, plasma etched silicon surfaces lead to enhanced boron diffusion.


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