Towards the Safe and Simple Production of Hydrocinnamic Acid by High‐Performance Palladium on Charcoal Nanocatalyst and Modeling the Nanocatalyst Fabrication Method

2020 ◽  
Vol 5 (7) ◽  
pp. 2354-2364 ◽  
Author(s):  
Sajjad Mousavi ◽  
Behzad Nazari ◽  
Mohammad H. Keshavarz ◽  
Abdol‐Khalegh Bordbar
Coatings ◽  
2020 ◽  
Vol 10 (7) ◽  
pp. 675 ◽  
Author(s):  
Fei Cheng ◽  
Yunxin Fan ◽  
Lu Zhang ◽  
Xiaojiao Jiao ◽  
Guoqiao Lai ◽  
...  

UV–curable polyacrylate is widely used in free–radical type UV–cure coating systems, the disadvantages of which including poor thermal stability and UV resistance can be overcome through chemical modification by silicone. However, it is a remarkable fact that the strategies for fabrication UV–cured silicone modified polyacrylates are somewhat complicated and the price of the products may be much expensive than pure UV–cured polyacrylates. In this work, an easy fabrication method to prepare inexpensive UV–cured transparent silicone modified polyacrylate coatings with good adhesion and UV resistance performance was developed from copolymers of acylates and thiol silicone resin by UV initiated thiol–ene click reaction without UV initiator. The striking results with a high application value should be emphasized that when the amount of thiol silicone resin is only one wt.% of the copolymer of acrylates, the UV–cured coatings obtained exhibit fairly good performance. These coatings prepared exhibit transparency higher than 96% (800 nm), adhesion property to glass slides can reach grade 0, pencil hardness can reach 6H, water absorption is less than 0.16%. In particular, it is observed obviously that the silicone modified polyacrylate coatings exhibit better UV resistance performance than the coating prepared with only copolymers of acrylates initiated by UV initiator 1173. It is proved that it is actually an easy fabrication method to prepare inexpensive UV–cured transparent silicone modified polyacrylate coatings with high performance by UV initiated thiol–ene click reaction of copolymers of acylates and thiol silicone resin.


1994 ◽  
Vol 18 (S_1_PMRC_94_1) ◽  
pp. S1_327-330
Author(s):  
Koji UCHIDA ◽  
Isao WATANABE ◽  
Horoaki MURAOKA ◽  
Yoshihisa NAKAMURA

2014 ◽  
Vol 894 ◽  
pp. 8-12
Author(s):  
Myeong Jin Kim ◽  
Ki Ho Kim ◽  
Myeong Yeol Yoo ◽  
Joo Heon Kim

Two types of graphene/MnO2 composites were synthesized by different reaction procedures. R-GO/MnO2 was synthesized as follows: first, nanoneedle MnO2 was formed on the GO sheets using various functional groups (GO/MnO2). In the second stage, GO/MnO2 was reduced to graphene/MnO2 (R-GO/MnO2) via the dipping method. rGO/MnO2 was synthesized using a different reaction order: first, graphene oxide was reduced to graphene and nanoneedle MnO2 was formed on graphene sheets. Characterization indicated that the nanoneedle MnO2 structures in the R-GO/MnO2 composite were homogeneously dispersed on graphene sheets, whereas MnO2 in the rGO/MnO2 composite formed aggregates due to absence of functional groups. The R-GO/MnO2 electrode exhibited a specific capacitance as high as 327.5 Fg-1at 10 mVs-1, which was higher than that of the rGO/MnO2 electrode (229.9 Fg-1). It is anticipated that the formation of nanoneedle MnO2 on the GO surface following the reduction procedure could be a promising fabrication method for supercapacitor electrodes.


Author(s):  
Xinmiao Chen ◽  
Lei Lu ◽  
Dawei Gu ◽  
Xiaoyan Zhang ◽  
Yu He ◽  
...  

The printable HTM-free (HTM=hole transport materials) mesoporous carbon-based perovskite solar cell (C-PSC) is one of the most promising technologies, because of its simple production process, lost-cost and excellent stability. In...


Materials ◽  
2020 ◽  
Vol 13 (15) ◽  
pp. 3252
Author(s):  
Gaoming Li ◽  
Jingwen Zhang ◽  
Yaoting Hu ◽  
Yongning He

High-performance UV detectors are of great significance for various applications. Plasmonic structures enable great improvement of the performance of detectors. However, to push the plasmonic enhancement to photo response into the deep-UV region presents some challenges. In this work, we found that the optical properties of the supporting layer play important roles in achieving the optimal plasmonic enhancement. Therefore, we fully considered the dependence of the optical constants of the MgZnO supporting layer, which is a promising material to realize deep-UV photodetectors, on microstructure and crystalline quality, which are related to the fabrication method. Based on the optical constants, we designed an Al mesh plasmonic structure and fabricated it with a polystyrene monolayer as a mask. Finally, we demonstrated a three-times enhancement to photo response with UV radiation at 254 nm.


2016 ◽  
Vol 4 (17) ◽  
pp. 6395-6403 ◽  
Author(s):  
Kiho Bae ◽  
Ho-Sung Noh ◽  
Dong Young Jang ◽  
Jongsup Hong ◽  
Hyoungchul Kim ◽  
...  

We proposed a facile and reliable fabrication method by implementing a novel cell platform and thin-film-deposition based protonic ceramic fuel cells.


2021 ◽  
Author(s):  
Shuya Sato ◽  
Setsuko Koura

Yttrium-based superconductors (YBCO) haven’t been widely applied. One reason is because of its high cost. In this study, we replaced the substrate and the fabrication method with lower-cost one, and found the possibility of making high-performance superconducting wires. Specifically, YBCO layer was fabricated by Electrophoretic deposition (EPD). Fabrication by this method needs calcination. The phenomenon that Fe in the substrate diffuses to YBCO layer during calcinating was confirmed. It was caused a decrease in YBCO performance. Therefore, CeO2 as an intermediate layer of substrate and YBCO was fabricated by EPD. It showed the possibility of preventing the spread of Fe. On the other hand, textured CeO2 layer was also fabricated in order to increase the characteristics of superconductor by EPD. And then it was also shown that to obtain a priority orientation is possible by controlling the current value.


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